Fabrication of metal-dielectric nanocomposites using a table-top ion implanter
A miniature low-voltage vacuum spark is an effective facility for creating composite layers in a dielectric matrix, including metal clusters, which have numerous optical applications. The results of studies of the optical characteristics of alkali-halide crystals (LiF and KCl) irradiated with beams...
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creator | Shipilova, O.I. Gorbunov, S.P. Paperny, V.L. Chernykh, A.A. Dresvyansky, V.P. Martynovich, E.F. Rakevich, A.L. |
description | A miniature low-voltage vacuum spark is an effective facility for creating composite layers in a dielectric matrix, including metal clusters, which have numerous optical applications. The results of studies of the optical characteristics of alkali-halide crystals (LiF and KCl) irradiated with beams of accelerated metal ions, which are emitted by a small-sized, low-voltage (2.5 kV) and low-energy (10 J) vacuum spark and a high-voltage (50 kV) pulsed ion implanter are presented. In both cases, composite layers of metal nanoparticles and/or molecular clusters are formed at submicrometer depth when irradiating these crystals. The low voltage implant method produces similar optical effects as seen in crystals processes at much higher energies. This result shows the possibility of creating a desktop metal ion implanter for various applications.
•An alkali-halide crystal substrate was exposed by a beam of metal ions emitted by a small-sized and low-voltage vacuum spark.•Composite layers of a sub-micrometer depth containing metal particles were obtained.•These layers exhibit luminescent properties, close to those of the layers obtained using a high-voltage ion implanter.•However, a difference was found in the ejection spectra of these layers.•This difference is supposedly due to the difference in the energy spectra of ion beams emitted by these sources. |
doi_str_mv | 10.1016/j.surfcoat.2020.125742 |
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•An alkali-halide crystal substrate was exposed by a beam of metal ions emitted by a small-sized and low-voltage vacuum spark.•Composite layers of a sub-micrometer depth containing metal particles were obtained.•These layers exhibit luminescent properties, close to those of the layers obtained using a high-voltage ion implanter.•However, a difference was found in the ejection spectra of these layers.•This difference is supposedly due to the difference in the energy spectra of ion beams emitted by these sources.</description><identifier>ISSN: 0257-8972</identifier><identifier>EISSN: 1879-3347</identifier><identifier>DOI: 10.1016/j.surfcoat.2020.125742</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Alkali metals ; Alkali-halide crystal ; Composite layers ; Crystals ; Ion beams ; Lithium fluoride ; Low voltage ; Luminescence band ; Metal clusters ; Metal ions ; Metal nanoparticles ; Microscopes ; Molecular clusters ; Nanocomposites ; Nanoparticles ; Optical properties ; Small-sized vacuum spark</subject><ispartof>Surface & coatings technology, 2020-07, Vol.393, p.125742, Article 125742</ispartof><rights>2020 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jul 15, 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c393t-c958197a9b2bfa2f21b5dd1e3c95e38d5ca3dc6ada0f2da7e6369383f3d323d73</citedby><cites>FETCH-LOGICAL-c393t-c958197a9b2bfa2f21b5dd1e3c95e38d5ca3dc6ada0f2da7e6369383f3d323d73</cites><orcidid>0000-0001-7572-7720</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0257897220304114$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids></links><search><creatorcontrib>Shipilova, O.I.</creatorcontrib><creatorcontrib>Gorbunov, S.P.</creatorcontrib><creatorcontrib>Paperny, V.L.</creatorcontrib><creatorcontrib>Chernykh, A.A.</creatorcontrib><creatorcontrib>Dresvyansky, V.P.</creatorcontrib><creatorcontrib>Martynovich, E.F.</creatorcontrib><creatorcontrib>Rakevich, A.L.</creatorcontrib><title>Fabrication of metal-dielectric nanocomposites using a table-top ion implanter</title><title>Surface & coatings technology</title><description>A miniature low-voltage vacuum spark is an effective facility for creating composite layers in a dielectric matrix, including metal clusters, which have numerous optical applications. The results of studies of the optical characteristics of alkali-halide crystals (LiF and KCl) irradiated with beams of accelerated metal ions, which are emitted by a small-sized, low-voltage (2.5 kV) and low-energy (10 J) vacuum spark and a high-voltage (50 kV) pulsed ion implanter are presented. In both cases, composite layers of metal nanoparticles and/or molecular clusters are formed at submicrometer depth when irradiating these crystals. The low voltage implant method produces similar optical effects as seen in crystals processes at much higher energies. This result shows the possibility of creating a desktop metal ion implanter for various applications.
•An alkali-halide crystal substrate was exposed by a beam of metal ions emitted by a small-sized and low-voltage vacuum spark.•Composite layers of a sub-micrometer depth containing metal particles were obtained.•These layers exhibit luminescent properties, close to those of the layers obtained using a high-voltage ion implanter.•However, a difference was found in the ejection spectra of these layers.•This difference is supposedly due to the difference in the energy spectra of ion beams emitted by these sources.</description><subject>Alkali metals</subject><subject>Alkali-halide crystal</subject><subject>Composite layers</subject><subject>Crystals</subject><subject>Ion beams</subject><subject>Lithium fluoride</subject><subject>Low voltage</subject><subject>Luminescence band</subject><subject>Metal clusters</subject><subject>Metal ions</subject><subject>Metal nanoparticles</subject><subject>Microscopes</subject><subject>Molecular clusters</subject><subject>Nanocomposites</subject><subject>Nanoparticles</subject><subject>Optical properties</subject><subject>Small-sized vacuum spark</subject><issn>0257-8972</issn><issn>1879-3347</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkE9LxDAQxYMouK5-BSl47po_bdPclMVVYdGLnkOaTCSlbWqSFfz2ZqmePQ28ee8N80PomuANwaS57TfxEKz2Km0oplmkNa_oCVqRlouSsYqfohXOYtkKTs_RRYw9xphwUa3Qy051wWmVnJ8Kb4sRkhpK42AAnfKimNTktR9nH12CWByimz4KVSTVDVAmPxfHoBvnQU0JwiU6s2qIcPU71-h99_C2fSr3r4_P2_t9qZlgqdSibongSnS0s4paSrraGAIsL4C1ptaKGd0oo7ClRnFoWCNYyywzjDLD2RrdLL1z8J8HiEn2_hCmfFLSqhJVW_Gqya5mcengYwxg5RzcqMK3JFge2cle_rGTR3ZyYZeDd0sQ8g9fDoKM2sGkwbiQuUjj3X8VP6u4fJ8</recordid><startdate>20200715</startdate><enddate>20200715</enddate><creator>Shipilova, O.I.</creator><creator>Gorbunov, S.P.</creator><creator>Paperny, V.L.</creator><creator>Chernykh, A.A.</creator><creator>Dresvyansky, V.P.</creator><creator>Martynovich, E.F.</creator><creator>Rakevich, A.L.</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-7572-7720</orcidid></search><sort><creationdate>20200715</creationdate><title>Fabrication of metal-dielectric nanocomposites using a table-top ion implanter</title><author>Shipilova, O.I. ; Gorbunov, S.P. ; Paperny, V.L. ; Chernykh, A.A. ; Dresvyansky, V.P. ; Martynovich, E.F. ; Rakevich, A.L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c393t-c958197a9b2bfa2f21b5dd1e3c95e38d5ca3dc6ada0f2da7e6369383f3d323d73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alkali metals</topic><topic>Alkali-halide crystal</topic><topic>Composite layers</topic><topic>Crystals</topic><topic>Ion beams</topic><topic>Lithium fluoride</topic><topic>Low voltage</topic><topic>Luminescence band</topic><topic>Metal clusters</topic><topic>Metal ions</topic><topic>Metal nanoparticles</topic><topic>Microscopes</topic><topic>Molecular clusters</topic><topic>Nanocomposites</topic><topic>Nanoparticles</topic><topic>Optical properties</topic><topic>Small-sized vacuum spark</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shipilova, O.I.</creatorcontrib><creatorcontrib>Gorbunov, S.P.</creatorcontrib><creatorcontrib>Paperny, V.L.</creatorcontrib><creatorcontrib>Chernykh, A.A.</creatorcontrib><creatorcontrib>Dresvyansky, V.P.</creatorcontrib><creatorcontrib>Martynovich, E.F.</creatorcontrib><creatorcontrib>Rakevich, A.L.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Surface & coatings technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shipilova, O.I.</au><au>Gorbunov, S.P.</au><au>Paperny, V.L.</au><au>Chernykh, A.A.</au><au>Dresvyansky, V.P.</au><au>Martynovich, E.F.</au><au>Rakevich, A.L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fabrication of metal-dielectric nanocomposites using a table-top ion implanter</atitle><jtitle>Surface & coatings technology</jtitle><date>2020-07-15</date><risdate>2020</risdate><volume>393</volume><spage>125742</spage><pages>125742-</pages><artnum>125742</artnum><issn>0257-8972</issn><eissn>1879-3347</eissn><abstract>A miniature low-voltage vacuum spark is an effective facility for creating composite layers in a dielectric matrix, including metal clusters, which have numerous optical applications. The results of studies of the optical characteristics of alkali-halide crystals (LiF and KCl) irradiated with beams of accelerated metal ions, which are emitted by a small-sized, low-voltage (2.5 kV) and low-energy (10 J) vacuum spark and a high-voltage (50 kV) pulsed ion implanter are presented. In both cases, composite layers of metal nanoparticles and/or molecular clusters are formed at submicrometer depth when irradiating these crystals. The low voltage implant method produces similar optical effects as seen in crystals processes at much higher energies. This result shows the possibility of creating a desktop metal ion implanter for various applications.
•An alkali-halide crystal substrate was exposed by a beam of metal ions emitted by a small-sized and low-voltage vacuum spark.•Composite layers of a sub-micrometer depth containing metal particles were obtained.•These layers exhibit luminescent properties, close to those of the layers obtained using a high-voltage ion implanter.•However, a difference was found in the ejection spectra of these layers.•This difference is supposedly due to the difference in the energy spectra of ion beams emitted by these sources.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.surfcoat.2020.125742</doi><orcidid>https://orcid.org/0000-0001-7572-7720</orcidid></addata></record> |
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subjects | Alkali metals Alkali-halide crystal Composite layers Crystals Ion beams Lithium fluoride Low voltage Luminescence band Metal clusters Metal ions Metal nanoparticles Microscopes Molecular clusters Nanocomposites Nanoparticles Optical properties Small-sized vacuum spark |
title | Fabrication of metal-dielectric nanocomposites using a table-top ion implanter |
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