A highly selective green supported liquid membrane by using a hydrophobic deep eutectic solvent for carrier-less transport of silver ions
A new supported liquid membrane (SLM) was designed by using a suitable deep eutectic solvent (DES) as the hydrophobic liquid membrane phase for the selective and facilitated carrier-less transport of Ag + ions. The deep eutectic solvent was composed of a 4/1 molar ratio of l -menthol/salicylic acid...
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| Veröffentlicht in: | Analytical methods 2020-10, Vol.12 (38), p.4682-469 |
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| creator | Shahrezaei, Fatemeh Shamsipur, Mojtaba Gholivand, Mohammad Bagher Zohrabi, Parvin Babajani, Nasrin Abri, Abdolreza Zonouz, Adeleh Moshtaghi Shekaari, Hemayat |
| description | A new supported liquid membrane (SLM) was designed by using a suitable deep eutectic solvent (DES) as the hydrophobic liquid membrane phase for the selective and facilitated carrier-less transport of Ag
+
ions. The deep eutectic solvent was composed of a 4/1 molar ratio of
l
-menthol/salicylic acid and was impregnated into a microporous polypropylene membrane to prepare a novel carrier-less SLM system. The highly selective facilitated transport of silver ions was accomplished by using sodium thiosulfate as a highly selective stripping agent for Ag
+
ions in the aqueous strip phase (SP). Some important factors, including the concentration of picric acid in the feed phase (FP), pH of the two aqueous phases, stirring rate, transport time, and nature and concentration of the stripping agent were also investigated and optimized. In the presence of 2.8 × 10
−2
mol L
−1
picrate ions as an appropriate ion pairing agent in the FP and 0.025 mol L
−1
thiosulfate as a convenient metal ion acceptor in the SP, the amount of Ag
+
ion transport found to occur almost quantitatively after 60 min is 90%. Compared with other SLM systems reported in the literature, the designed DES-SLM system exhibited suitable permeability and higher selectivity for Ag
+
ion transport from aqueous solutions containing Fe
2+
, Mn
2+
, Cu
2+
, Ni
2+
, Pb
2+
, and Cd
2+
as competing metal ions.
A new supported liquid membrane (SLM) was designed by using a suitable deep eutectic solvent (DES) as the hydrophobic liquid membrane phase for the selective and facilitated carrier-less transport of Ag
+
ions. |
| doi_str_mv | 10.1039/d0ay01266a |
| format | Article |
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+
ions. The deep eutectic solvent was composed of a 4/1 molar ratio of
l
-menthol/salicylic acid and was impregnated into a microporous polypropylene membrane to prepare a novel carrier-less SLM system. The highly selective facilitated transport of silver ions was accomplished by using sodium thiosulfate as a highly selective stripping agent for Ag
+
ions in the aqueous strip phase (SP). Some important factors, including the concentration of picric acid in the feed phase (FP), pH of the two aqueous phases, stirring rate, transport time, and nature and concentration of the stripping agent were also investigated and optimized. In the presence of 2.8 × 10
−2
mol L
−1
picrate ions as an appropriate ion pairing agent in the FP and 0.025 mol L
−1
thiosulfate as a convenient metal ion acceptor in the SP, the amount of Ag
+
ion transport found to occur almost quantitatively after 60 min is 90%. Compared with other SLM systems reported in the literature, the designed DES-SLM system exhibited suitable permeability and higher selectivity for Ag
+
ion transport from aqueous solutions containing Fe
2+
, Mn
2+
, Cu
2+
, Ni
2+
, Pb
2+
, and Cd
2+
as competing metal ions.
A new supported liquid membrane (SLM) was designed by using a suitable deep eutectic solvent (DES) as the hydrophobic liquid membrane phase for the selective and facilitated carrier-less transport of Ag
+
ions.</description><identifier>ISSN: 1759-9660</identifier><identifier>EISSN: 1759-9679</identifier><identifier>DOI: 10.1039/d0ay01266a</identifier><identifier>PMID: 32914799</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Aqueous solutions ; Cadmium ; Copper ; Hydrophobicity ; Ion transport ; Ions ; Iron ; L-Menthol ; Lead ; Liquid membranes ; Manganese ; Membranes ; Menthol ; Metal ions ; Nickel ; Permeability ; Picric acid ; Polypropylene ; Salicylic acid ; Selectivity ; Silver ; Sodium thiosulfate ; Solvents ; Stripping ; Thiosulfate ; Thiosulfates</subject><ispartof>Analytical methods, 2020-10, Vol.12 (38), p.4682-469</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c400t-cc31906a6cf160c7a1c1460f2420a5b97ac35204caf7869ace381e21f2ea5ef43</citedby><cites>FETCH-LOGICAL-c400t-cc31906a6cf160c7a1c1460f2420a5b97ac35204caf7869ace381e21f2ea5ef43</cites><orcidid>0000-0001-6560-4815 ; 0000-0002-5134-6330</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/32914799$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Shahrezaei, Fatemeh</creatorcontrib><creatorcontrib>Shamsipur, Mojtaba</creatorcontrib><creatorcontrib>Gholivand, Mohammad Bagher</creatorcontrib><creatorcontrib>Zohrabi, Parvin</creatorcontrib><creatorcontrib>Babajani, Nasrin</creatorcontrib><creatorcontrib>Abri, Abdolreza</creatorcontrib><creatorcontrib>Zonouz, Adeleh Moshtaghi</creatorcontrib><creatorcontrib>Shekaari, Hemayat</creatorcontrib><title>A highly selective green supported liquid membrane by using a hydrophobic deep eutectic solvent for carrier-less transport of silver ions</title><title>Analytical methods</title><addtitle>Anal Methods</addtitle><description>A new supported liquid membrane (SLM) was designed by using a suitable deep eutectic solvent (DES) as the hydrophobic liquid membrane phase for the selective and facilitated carrier-less transport of Ag
+
ions. The deep eutectic solvent was composed of a 4/1 molar ratio of
l
-menthol/salicylic acid and was impregnated into a microporous polypropylene membrane to prepare a novel carrier-less SLM system. The highly selective facilitated transport of silver ions was accomplished by using sodium thiosulfate as a highly selective stripping agent for Ag
+
ions in the aqueous strip phase (SP). Some important factors, including the concentration of picric acid in the feed phase (FP), pH of the two aqueous phases, stirring rate, transport time, and nature and concentration of the stripping agent were also investigated and optimized. In the presence of 2.8 × 10
−2
mol L
−1
picrate ions as an appropriate ion pairing agent in the FP and 0.025 mol L
−1
thiosulfate as a convenient metal ion acceptor in the SP, the amount of Ag
+
ion transport found to occur almost quantitatively after 60 min is 90%. Compared with other SLM systems reported in the literature, the designed DES-SLM system exhibited suitable permeability and higher selectivity for Ag
+
ion transport from aqueous solutions containing Fe
2+
, Mn
2+
, Cu
2+
, Ni
2+
, Pb
2+
, and Cd
2+
as competing metal ions.
A new supported liquid membrane (SLM) was designed by using a suitable deep eutectic solvent (DES) as the hydrophobic liquid membrane phase for the selective and facilitated carrier-less transport of Ag
+
ions.</description><subject>Aqueous solutions</subject><subject>Cadmium</subject><subject>Copper</subject><subject>Hydrophobicity</subject><subject>Ion transport</subject><subject>Ions</subject><subject>Iron</subject><subject>L-Menthol</subject><subject>Lead</subject><subject>Liquid membranes</subject><subject>Manganese</subject><subject>Membranes</subject><subject>Menthol</subject><subject>Metal ions</subject><subject>Nickel</subject><subject>Permeability</subject><subject>Picric acid</subject><subject>Polypropylene</subject><subject>Salicylic acid</subject><subject>Selectivity</subject><subject>Silver</subject><subject>Sodium thiosulfate</subject><subject>Solvents</subject><subject>Stripping</subject><subject>Thiosulfate</subject><subject>Thiosulfates</subject><issn>1759-9660</issn><issn>1759-9679</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kU1r3DAQhkVpaJJtL723TMilFNxKtiyvjkv6FQjk0h56MrI82lWwLUdjB_wT-q-r7aZb6CEnDbwPD6N5GXst-AfBC_2x5WbhIlfKPGNnoip1plWlnx9nxU_ZOdEd50oXSrxgp0Wuhay0PmO_NrDz2123AGGHdvIPCNuIOADN4xjihC10_n72LfTYN9EMCM0CM_lhCwZ2SxvDuAuNt9AijoDztLdYoNA94DCBCxGsidFjzDokgik5aG-G4IB8oiL4MNBLduJMR_jq8V2xH18-f7_6lt3cfr2-2txkVnI-ZdYWQnNllHVCcVsZYYVU3OUy56ZsdGVsUeZcWuOqtdLGYrEWmAuXoynRyWLF3h28Ywz3M9JU954sdl36WpipzqVM4nWRbrVil_-hd2GOQ9puT2lZirJUiXp_oGwMRBFdPUbfm7jUgtf7gupPfPPzT0GbBL99VM5Nj-0R_dtIAt4cgEj2mP5rOOUXT-X12LriN3s-osM</recordid><startdate>20201008</startdate><enddate>20201008</enddate><creator>Shahrezaei, Fatemeh</creator><creator>Shamsipur, Mojtaba</creator><creator>Gholivand, Mohammad Bagher</creator><creator>Zohrabi, Parvin</creator><creator>Babajani, Nasrin</creator><creator>Abri, Abdolreza</creator><creator>Zonouz, Adeleh Moshtaghi</creator><creator>Shekaari, Hemayat</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SE</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>FR3</scope><scope>H8G</scope><scope>JG9</scope><scope>L7M</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-6560-4815</orcidid><orcidid>https://orcid.org/0000-0002-5134-6330</orcidid></search><sort><creationdate>20201008</creationdate><title>A highly selective green supported liquid membrane by using a hydrophobic deep eutectic solvent for carrier-less transport of silver ions</title><author>Shahrezaei, Fatemeh ; Shamsipur, Mojtaba ; Gholivand, Mohammad Bagher ; Zohrabi, Parvin ; Babajani, Nasrin ; Abri, Abdolreza ; Zonouz, Adeleh Moshtaghi ; Shekaari, Hemayat</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c400t-cc31906a6cf160c7a1c1460f2420a5b97ac35204caf7869ace381e21f2ea5ef43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aqueous solutions</topic><topic>Cadmium</topic><topic>Copper</topic><topic>Hydrophobicity</topic><topic>Ion transport</topic><topic>Ions</topic><topic>Iron</topic><topic>L-Menthol</topic><topic>Lead</topic><topic>Liquid membranes</topic><topic>Manganese</topic><topic>Membranes</topic><topic>Menthol</topic><topic>Metal ions</topic><topic>Nickel</topic><topic>Permeability</topic><topic>Picric acid</topic><topic>Polypropylene</topic><topic>Salicylic acid</topic><topic>Selectivity</topic><topic>Silver</topic><topic>Sodium thiosulfate</topic><topic>Solvents</topic><topic>Stripping</topic><topic>Thiosulfate</topic><topic>Thiosulfates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Shahrezaei, Fatemeh</creatorcontrib><creatorcontrib>Shamsipur, Mojtaba</creatorcontrib><creatorcontrib>Gholivand, Mohammad Bagher</creatorcontrib><creatorcontrib>Zohrabi, Parvin</creatorcontrib><creatorcontrib>Babajani, Nasrin</creatorcontrib><creatorcontrib>Abri, Abdolreza</creatorcontrib><creatorcontrib>Zonouz, Adeleh Moshtaghi</creatorcontrib><creatorcontrib>Shekaari, Hemayat</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Analytical methods</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Shahrezaei, Fatemeh</au><au>Shamsipur, Mojtaba</au><au>Gholivand, Mohammad Bagher</au><au>Zohrabi, Parvin</au><au>Babajani, Nasrin</au><au>Abri, Abdolreza</au><au>Zonouz, Adeleh Moshtaghi</au><au>Shekaari, Hemayat</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A highly selective green supported liquid membrane by using a hydrophobic deep eutectic solvent for carrier-less transport of silver ions</atitle><jtitle>Analytical methods</jtitle><addtitle>Anal Methods</addtitle><date>2020-10-08</date><risdate>2020</risdate><volume>12</volume><issue>38</issue><spage>4682</spage><epage>469</epage><pages>4682-469</pages><issn>1759-9660</issn><eissn>1759-9679</eissn><abstract>A new supported liquid membrane (SLM) was designed by using a suitable deep eutectic solvent (DES) as the hydrophobic liquid membrane phase for the selective and facilitated carrier-less transport of Ag
+
ions. The deep eutectic solvent was composed of a 4/1 molar ratio of
l
-menthol/salicylic acid and was impregnated into a microporous polypropylene membrane to prepare a novel carrier-less SLM system. The highly selective facilitated transport of silver ions was accomplished by using sodium thiosulfate as a highly selective stripping agent for Ag
+
ions in the aqueous strip phase (SP). Some important factors, including the concentration of picric acid in the feed phase (FP), pH of the two aqueous phases, stirring rate, transport time, and nature and concentration of the stripping agent were also investigated and optimized. In the presence of 2.8 × 10
−2
mol L
−1
picrate ions as an appropriate ion pairing agent in the FP and 0.025 mol L
−1
thiosulfate as a convenient metal ion acceptor in the SP, the amount of Ag
+
ion transport found to occur almost quantitatively after 60 min is 90%. Compared with other SLM systems reported in the literature, the designed DES-SLM system exhibited suitable permeability and higher selectivity for Ag
+
ion transport from aqueous solutions containing Fe
2+
, Mn
2+
, Cu
2+
, Ni
2+
, Pb
2+
, and Cd
2+
as competing metal ions.
A new supported liquid membrane (SLM) was designed by using a suitable deep eutectic solvent (DES) as the hydrophobic liquid membrane phase for the selective and facilitated carrier-less transport of Ag
+
ions.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>32914799</pmid><doi>10.1039/d0ay01266a</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-6560-4815</orcidid><orcidid>https://orcid.org/0000-0002-5134-6330</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1759-9660 |
| ispartof | Analytical methods, 2020-10, Vol.12 (38), p.4682-469 |
| issn | 1759-9660 1759-9679 |
| language | eng |
| recordid | cdi_proquest_journals_2449451556 |
| source | Royal Society Of Chemistry Journals |
| subjects | Aqueous solutions Cadmium Copper Hydrophobicity Ion transport Ions Iron L-Menthol Lead Liquid membranes Manganese Membranes Menthol Metal ions Nickel Permeability Picric acid Polypropylene Salicylic acid Selectivity Silver Sodium thiosulfate Solvents Stripping Thiosulfate Thiosulfates |
| title | A highly selective green supported liquid membrane by using a hydrophobic deep eutectic solvent for carrier-less transport of silver ions |
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