Theory, preparation, properties and catalysis application in 2D Graphynes-Based Materials

Carbon has three hybridization forms of sp-, sp2- and sp3-, and the combination of different forms can obtain different kinds of carbon allotropes, such as diamond, carbon nanotubes, fullerene, graphynes (GYs) and graphdiyne (GDY). Among them, the GDY molecule is a single-layer two-dimensional (2D)...

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Veröffentlicht in:arXiv.org 2020-10
Hauptverfasser: Zhang, Ning, Wu, Jiayu, Yu, Taoyuan, Lv, Jiaqi, Liu, He, Xu, Xiping
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description Carbon has three hybridization forms of sp-, sp2- and sp3-, and the combination of different forms can obtain different kinds of carbon allotropes, such as diamond, carbon nanotubes, fullerene, graphynes (GYs) and graphdiyne (GDY). Among them, the GDY molecule is a single-layer two-dimensional (2D) planar structure material with highly -conjugation formed by sp- and sp2- hybridization. GDY has a carbon atom ring composed of benzene ring and acetylene, which makes GDY have a uniformly distributed pore structure. In addition, GDY planar material have some slight wrinkles, which makes GDY have better self-stability than other 2D planar materials. The excellent properties of GDY make it attract the attention of researcher. Therefore, GDY is widely used in chemical catalysis, electronics, communications, clean energy and composite materials. This paper summarizes the recent progress of GDY research, including structure, preparation, properties and application of GDY in the field of catalysts.
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subjects Acetylene
Allotropy
Benzene
Carbon
Carbon nanotubes
Catalysis
Clean energy
Composite materials
Conjugation
Diamonds
Fullerenes
Planar structures
Porosity
Properties (attributes)
title Theory, preparation, properties and catalysis application in 2D Graphynes-Based Materials
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