Thermally Reversible Diels–Alder Bond‐Containing Acrylate Networks Showing Improved Lifetime

Photopolymerization of (meth)acrylates into highly crosslinked networks is in general accompanied by volumetric shrinkage, often leading to premature material failure. In this work, thermoreversible Diels–Alder groups are investigated to explore their effect on material lifetime. A difunctional acry...

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Veröffentlicht in:	Macromolecular chemistry and physics 2020-10, Vol.221 (19), p.n/a
Hauptverfasser:	Maassen, Eveline E. L., Anastasio, Rosaria, Breemen, Lambèrt C. A., Sijbesma, Rint P., Heuts, Johan P. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylates Crosslinking Diels–Alder Materials failure Mechanical properties Photopolymerization thermoresponsive polymers Yield stress
Online-Zugang:	Volltext
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