Star-shaped trithiophene and hexathiophene functionalized truxenes: synthesis, electropolymerization, and electrochromism
The porous structure produced by star-shaped molecules via electrochemical polymerization provides a number of transport channels, which will be beneficial for ions migration and improving electrochemical and electrochromic performance. Two novel star-shaped trithiophene and hexathiophene functional...
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| Veröffentlicht in: | Reactive & functional polymers 2020-09, Vol.154, p.104674, Article 104674 |
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| creator | Lin, Kaiwen Jian, Nannan Zhang, Xiaobin Zhang, Yushan Ming, Shouli Zhen, Shijie Jiang, Qinglin Wang, Liangying Wang, Yuehui Xu, Jingkun |
| description | The porous structure produced by star-shaped molecules via electrochemical polymerization provides a number of transport channels, which will be beneficial for ions migration and improving electrochemical and electrochromic performance. Two novel star-shaped trithiophene and hexathiophene functionalized truxenes, Tr-3Th and Tr-6Th, were successfully synthesized. The corresponding porous polymers PTr-3Th and PTr-6Th, prepared by the electrochemical polymerization of the Tr-3Th and Tr-6Th, have provided compatible ion transport channels, which performed high electrochemical stability (maintain 99% electrochemical activity after 5000 cycles). PTr-3Th revealed colour change from light gray-green to dark gray-green upon oxidation, meanwhile, PTr-6Th presented the colour variations from light yellow to green. The result provides a new insight into the design of electrochromic polymers with good stability.
Microporous polymers PTr-3Th and PTr-6Th, prepared by the electrochemical polymerization of monomers Tr-3Th and Tr-6Th, have provided compatible ion transport channels, which resulted into their high electrochemical stability (maintain 99% electrochemical activity after 5000 cycles). PTr-3Th revealed colour change from light gray-green to dark gray-green upon oxidation, meanwhile, PTr-6Th presented the colour variations from light yellow to green. [Display omitted]
•Two novel star-shaped trithiophene and hexathiophene functionalized truxenes, Tr-3Th and Tr-6Th were synthesized.•Porous PTr-3Th and PTr-6Th exhibited high electrochemical stability due to compatible ion transport channels.•PTr-6Th presented the obvious colour variations from light yellow to green. |
| doi_str_mv | 10.1016/j.reactfunctpolym.2020.104674 |
| format | Article |
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Microporous polymers PTr-3Th and PTr-6Th, prepared by the electrochemical polymerization of monomers Tr-3Th and Tr-6Th, have provided compatible ion transport channels, which resulted into their high electrochemical stability (maintain 99% electrochemical activity after 5000 cycles). PTr-3Th revealed colour change from light gray-green to dark gray-green upon oxidation, meanwhile, PTr-6Th presented the colour variations from light yellow to green. [Display omitted]
•Two novel star-shaped trithiophene and hexathiophene functionalized truxenes, Tr-3Th and Tr-6Th were synthesized.•Porous PTr-3Th and PTr-6Th exhibited high electrochemical stability due to compatible ion transport channels.•PTr-6Th presented the obvious colour variations from light yellow to green.</description><identifier>ISSN: 1381-5148</identifier><identifier>EISSN: 1873-166X</identifier><identifier>DOI: 10.1016/j.reactfunctpolym.2020.104674</identifier><language>eng</language><publisher>Amsterdam: Elsevier B.V</publisher><subject>Channels ; Chemical synthesis ; Color ; Electrochromism ; Electropolymerization ; Ion transport ; Molecular structure ; Oxidation ; Polymerization ; Polymers ; Porous electrochromic polymer ; Stability ; Star-shaped ; Synthesis ; Truxene</subject><ispartof>Reactive & functional polymers, 2020-09, Vol.154, p.104674, Article 104674</ispartof><rights>2020 Elsevier B.V.</rights><rights>Copyright Elsevier BV Sep 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-206dc3475526fdcb88e0d33761aa08e691c9f87937e896feab24de8b93bac0f43</citedby><cites>FETCH-LOGICAL-c361t-206dc3475526fdcb88e0d33761aa08e691c9f87937e896feab24de8b93bac0f43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.reactfunctpolym.2020.104674$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3549,27923,27924,45994</link.rule.ids></links><search><creatorcontrib>Lin, Kaiwen</creatorcontrib><creatorcontrib>Jian, Nannan</creatorcontrib><creatorcontrib>Zhang, Xiaobin</creatorcontrib><creatorcontrib>Zhang, Yushan</creatorcontrib><creatorcontrib>Ming, Shouli</creatorcontrib><creatorcontrib>Zhen, Shijie</creatorcontrib><creatorcontrib>Jiang, Qinglin</creatorcontrib><creatorcontrib>Wang, Liangying</creatorcontrib><creatorcontrib>Wang, Yuehui</creatorcontrib><creatorcontrib>Xu, Jingkun</creatorcontrib><title>Star-shaped trithiophene and hexathiophene functionalized truxenes: synthesis, electropolymerization, and electrochromism</title><title>Reactive & functional polymers</title><description>The porous structure produced by star-shaped molecules via electrochemical polymerization provides a number of transport channels, which will be beneficial for ions migration and improving electrochemical and electrochromic performance. Two novel star-shaped trithiophene and hexathiophene functionalized truxenes, Tr-3Th and Tr-6Th, were successfully synthesized. The corresponding porous polymers PTr-3Th and PTr-6Th, prepared by the electrochemical polymerization of the Tr-3Th and Tr-6Th, have provided compatible ion transport channels, which performed high electrochemical stability (maintain 99% electrochemical activity after 5000 cycles). PTr-3Th revealed colour change from light gray-green to dark gray-green upon oxidation, meanwhile, PTr-6Th presented the colour variations from light yellow to green. The result provides a new insight into the design of electrochromic polymers with good stability.
Microporous polymers PTr-3Th and PTr-6Th, prepared by the electrochemical polymerization of monomers Tr-3Th and Tr-6Th, have provided compatible ion transport channels, which resulted into their high electrochemical stability (maintain 99% electrochemical activity after 5000 cycles). PTr-3Th revealed colour change from light gray-green to dark gray-green upon oxidation, meanwhile, PTr-6Th presented the colour variations from light yellow to green. [Display omitted]
•Two novel star-shaped trithiophene and hexathiophene functionalized truxenes, Tr-3Th and Tr-6Th were synthesized.•Porous PTr-3Th and PTr-6Th exhibited high electrochemical stability due to compatible ion transport channels.•PTr-6Th presented the obvious colour variations from light yellow to green.</description><subject>Channels</subject><subject>Chemical synthesis</subject><subject>Color</subject><subject>Electrochromism</subject><subject>Electropolymerization</subject><subject>Ion transport</subject><subject>Molecular structure</subject><subject>Oxidation</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Porous electrochromic polymer</subject><subject>Stability</subject><subject>Star-shaped</subject><subject>Synthesis</subject><subject>Truxene</subject><issn>1381-5148</issn><issn>1873-166X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqNUF1LwzAULaLgnP6Hgvi2zqTp0lTwQYZOYeCDCr6FNL2lKW1Tk0y2_XrTbiD45NO93PORnBMENxjNMcL0tp4bENKVm066Xje7dh6jeMASmiYnwQSzlESY0s9TvxOGowVO2HlwYW2NEE49Mgl2b06YyFaihyJ0RrlK6b6CDkLRFWEFW_F7GR9SuhON2o_szdaf7V1od52rwCo7C6EB6YwevwNG7cUgmI1mR0hWRrfKtpfBWSkaC1fHOQ0-nh7fl8_R-nX1snxYR5JQ7KIY0UKSJF0sYloWMmcMUEFISrEQiAHNsMxKlmYkBZbREkQeJwWwPCO5kKhMyDS4Pvj2Rn9twDpe643xISyPE--bJojGnnV_YEmjrTVQ8t6oVpgdx4gPbfOa_2mbD23zQ9tevzrowUf5VmC4lQo6CYUyPjYvtPqn0w_seZcS</recordid><startdate>202009</startdate><enddate>202009</enddate><creator>Lin, Kaiwen</creator><creator>Jian, Nannan</creator><creator>Zhang, Xiaobin</creator><creator>Zhang, Yushan</creator><creator>Ming, Shouli</creator><creator>Zhen, Shijie</creator><creator>Jiang, Qinglin</creator><creator>Wang, Liangying</creator><creator>Wang, Yuehui</creator><creator>Xu, Jingkun</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>202009</creationdate><title>Star-shaped trithiophene and hexathiophene functionalized truxenes: synthesis, electropolymerization, and electrochromism</title><author>Lin, Kaiwen ; Jian, Nannan ; Zhang, Xiaobin ; Zhang, Yushan ; Ming, Shouli ; Zhen, Shijie ; Jiang, Qinglin ; Wang, Liangying ; Wang, Yuehui ; Xu, Jingkun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-206dc3475526fdcb88e0d33761aa08e691c9f87937e896feab24de8b93bac0f43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Channels</topic><topic>Chemical synthesis</topic><topic>Color</topic><topic>Electrochromism</topic><topic>Electropolymerization</topic><topic>Ion transport</topic><topic>Molecular structure</topic><topic>Oxidation</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Porous electrochromic polymer</topic><topic>Stability</topic><topic>Star-shaped</topic><topic>Synthesis</topic><topic>Truxene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Lin, Kaiwen</creatorcontrib><creatorcontrib>Jian, Nannan</creatorcontrib><creatorcontrib>Zhang, Xiaobin</creatorcontrib><creatorcontrib>Zhang, Yushan</creatorcontrib><creatorcontrib>Ming, Shouli</creatorcontrib><creatorcontrib>Zhen, Shijie</creatorcontrib><creatorcontrib>Jiang, Qinglin</creatorcontrib><creatorcontrib>Wang, Liangying</creatorcontrib><creatorcontrib>Wang, Yuehui</creatorcontrib><creatorcontrib>Xu, Jingkun</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Reactive & functional polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Lin, Kaiwen</au><au>Jian, Nannan</au><au>Zhang, Xiaobin</au><au>Zhang, Yushan</au><au>Ming, Shouli</au><au>Zhen, Shijie</au><au>Jiang, Qinglin</au><au>Wang, Liangying</au><au>Wang, Yuehui</au><au>Xu, Jingkun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Star-shaped trithiophene and hexathiophene functionalized truxenes: synthesis, electropolymerization, and electrochromism</atitle><jtitle>Reactive & functional polymers</jtitle><date>2020-09</date><risdate>2020</risdate><volume>154</volume><spage>104674</spage><pages>104674-</pages><artnum>104674</artnum><issn>1381-5148</issn><eissn>1873-166X</eissn><abstract>The porous structure produced by star-shaped molecules via electrochemical polymerization provides a number of transport channels, which will be beneficial for ions migration and improving electrochemical and electrochromic performance. Two novel star-shaped trithiophene and hexathiophene functionalized truxenes, Tr-3Th and Tr-6Th, were successfully synthesized. The corresponding porous polymers PTr-3Th and PTr-6Th, prepared by the electrochemical polymerization of the Tr-3Th and Tr-6Th, have provided compatible ion transport channels, which performed high electrochemical stability (maintain 99% electrochemical activity after 5000 cycles). PTr-3Th revealed colour change from light gray-green to dark gray-green upon oxidation, meanwhile, PTr-6Th presented the colour variations from light yellow to green. The result provides a new insight into the design of electrochromic polymers with good stability.
Microporous polymers PTr-3Th and PTr-6Th, prepared by the electrochemical polymerization of monomers Tr-3Th and Tr-6Th, have provided compatible ion transport channels, which resulted into their high electrochemical stability (maintain 99% electrochemical activity after 5000 cycles). PTr-3Th revealed colour change from light gray-green to dark gray-green upon oxidation, meanwhile, PTr-6Th presented the colour variations from light yellow to green. [Display omitted]
•Two novel star-shaped trithiophene and hexathiophene functionalized truxenes, Tr-3Th and Tr-6Th were synthesized.•Porous PTr-3Th and PTr-6Th exhibited high electrochemical stability due to compatible ion transport channels.•PTr-6Th presented the obvious colour variations from light yellow to green.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.reactfunctpolym.2020.104674</doi></addata></record> |
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| subjects | Channels Chemical synthesis Color Electrochromism Electropolymerization Ion transport Molecular structure Oxidation Polymerization Polymers Porous electrochromic polymer Stability Star-shaped Synthesis Truxene |
| title | Star-shaped trithiophene and hexathiophene functionalized truxenes: synthesis, electropolymerization, and electrochromism |
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