Manipulation of crosslinking in photo-induced phase separated polymers to control morphology and thermo-mechanical properties

Photopolymerization-induced phase separation allows significant control over polymer morphology and properties for hybrid radical/cationic systems. Polymer nano/micro-structure and domain size/continuity of each incompatible phase can be manipulated by using different photopolymerization conditions...

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Veröffentlicht in:	Polymer (Guilford) 2020-08, Vol.202, p.122699, Article 122699
Hauptverfasser:	Hasa, Erion, Stansbury, Jeffrey W., Guymon, C. Allan
Format:	Artikel
Sprache:	eng
Schlagworte:	Cationic polymerization Crosslinking Domains Elongation Enhanced toughness Gelation Glass transition temperature Hybrid radical/cationic systems Hybrid systems Impact strength Mechanical properties Monomers Morphology Nano/micro-phase separation Network gelation Phase separation Photopolymerization Polymers Thermomechanical analysis Thermomechanical properties Toughness Transition temperatures
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