Comparison of the properties of perfluoroalkyl polyoxyethylene ether and alkyl polyoxyethylene ether
Short-chain fluorocarbon surfactants have been widely adopted as substitutes for long-chain fluorocarbon surfactants and hydrocarbon surfactants due to their biodegradability and excellent surface properties. In particular, fluorocarbon surfactants such as short-chain perfluoropolyethers have become...
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| Veröffentlicht in: | Colloid and polymer science 2020-10, Vol.298 (10), p.1389-1399 |
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| creator | Ning, Bo Zhang, Mi Bai, Yanyun Tai, Xiumei Wang, Wanxu Wang, Guoyong |
| description | Short-chain fluorocarbon surfactants have been widely adopted as substitutes for long-chain fluorocarbon surfactants and hydrocarbon surfactants due to their biodegradability and excellent surface properties. In particular, fluorocarbon surfactants such as short-chain perfluoropolyethers have become a research hotspot in recent years. In this study, the short-chain perfluoroalkyl polyoxyethylene ether surfactant CF-310 is systematically compared with the traditional nonionic hydrocarbon surfactant alkyl polyoxyethylene ether AEO-7 in terms of its equilibrium surface tension, dynamic surface tension, wetting properties, and foam properties. The results show that CF-310 has better surface properties, better wettability on low-energy surfaces, and better foam properties than AEO-7. Structural optimization based on density functional theory (DFT) also indicates that the CF-310 fluorocarbon chain has a larger volume and a helical conformation, which are the main factors responsible for the superior surface performance, wettability, and foam performance of CF-310 compared with AEO-7. Excellent performance and biodegradability make this short-chain perfluoroalkyl polyoxyethylene ether surfactant CF-310 a more efficient alternative to AEO-7. This study tested the performance of the CF-310 system in hopes of developing its potential applications in personal and home care and foam applications. |
| doi_str_mv | 10.1007/s00396-020-04732-2 |
| format | Article |
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In particular, fluorocarbon surfactants such as short-chain perfluoropolyethers have become a research hotspot in recent years. In this study, the short-chain perfluoroalkyl polyoxyethylene ether surfactant CF-310 is systematically compared with the traditional nonionic hydrocarbon surfactant alkyl polyoxyethylene ether AEO-7 in terms of its equilibrium surface tension, dynamic surface tension, wetting properties, and foam properties. The results show that CF-310 has better surface properties, better wettability on low-energy surfaces, and better foam properties than AEO-7. Structural optimization based on density functional theory (DFT) also indicates that the CF-310 fluorocarbon chain has a larger volume and a helical conformation, which are the main factors responsible for the superior surface performance, wettability, and foam performance of CF-310 compared with AEO-7. Excellent performance and biodegradability make this short-chain perfluoroalkyl polyoxyethylene ether surfactant CF-310 a more efficient alternative to AEO-7. This study tested the performance of the CF-310 system in hopes of developing its potential applications in personal and home care and foam applications.</description><identifier>ISSN: 0303-402X</identifier><identifier>EISSN: 1435-1536</identifier><identifier>DOI: 10.1007/s00396-020-04732-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Biodegradability ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Complex Fluids and Microfluidics ; Density functional theory ; Food Science ; Hydrocarbons ; Nanotechnology and Microengineering ; Optimization ; Original Contribution ; Perfluoro compounds ; Perfluoroalkyl & polyfluoroalkyl substances ; Perfluorocarbons ; Physical Chemistry ; Polymer Sciences ; Polyoxyethylene ; Properties (attributes) ; Soft and Granular Matter ; Surface properties ; Surface tension ; Surfactants ; Wettability ; Wetting</subject><ispartof>Colloid and polymer science, 2020-10, Vol.298 (10), p.1389-1399</ispartof><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Germany, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c356t-352d0947805848e93bf6a9bf2233517f52bfa26b7f3a84b7a6e600225c834a643</citedby><cites>FETCH-LOGICAL-c356t-352d0947805848e93bf6a9bf2233517f52bfa26b7f3a84b7a6e600225c834a643</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00396-020-04732-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00396-020-04732-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Ning, Bo</creatorcontrib><creatorcontrib>Zhang, Mi</creatorcontrib><creatorcontrib>Bai, Yanyun</creatorcontrib><creatorcontrib>Tai, Xiumei</creatorcontrib><creatorcontrib>Wang, Wanxu</creatorcontrib><creatorcontrib>Wang, Guoyong</creatorcontrib><title>Comparison of the properties of perfluoroalkyl polyoxyethylene ether and alkyl polyoxyethylene ether</title><title>Colloid and polymer science</title><addtitle>Colloid Polym Sci</addtitle><description>Short-chain fluorocarbon surfactants have been widely adopted as substitutes for long-chain fluorocarbon surfactants and hydrocarbon surfactants due to their biodegradability and excellent surface properties. In particular, fluorocarbon surfactants such as short-chain perfluoropolyethers have become a research hotspot in recent years. In this study, the short-chain perfluoroalkyl polyoxyethylene ether surfactant CF-310 is systematically compared with the traditional nonionic hydrocarbon surfactant alkyl polyoxyethylene ether AEO-7 in terms of its equilibrium surface tension, dynamic surface tension, wetting properties, and foam properties. The results show that CF-310 has better surface properties, better wettability on low-energy surfaces, and better foam properties than AEO-7. Structural optimization based on density functional theory (DFT) also indicates that the CF-310 fluorocarbon chain has a larger volume and a helical conformation, which are the main factors responsible for the superior surface performance, wettability, and foam performance of CF-310 compared with AEO-7. Excellent performance and biodegradability make this short-chain perfluoroalkyl polyoxyethylene ether surfactant CF-310 a more efficient alternative to AEO-7. This study tested the performance of the CF-310 system in hopes of developing its potential applications in personal and home care and foam applications.</description><subject>Biodegradability</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Density functional theory</subject><subject>Food Science</subject><subject>Hydrocarbons</subject><subject>Nanotechnology and Microengineering</subject><subject>Optimization</subject><subject>Original Contribution</subject><subject>Perfluoro compounds</subject><subject>Perfluoroalkyl & polyfluoroalkyl substances</subject><subject>Perfluorocarbons</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polyoxyethylene</subject><subject>Properties (attributes)</subject><subject>Soft and Granular Matter</subject><subject>Surface properties</subject><subject>Surface tension</subject><subject>Surfactants</subject><subject>Wettability</subject><subject>Wetting</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kE1LAzEQhoMoWKt_wNOC5-jsTD52j1L8AsGLgreQbRPbut2syRbcf29qBW89zcvM-84wD2OXJVyXAPomAVCtOCBwEJqQ4xGblIIkLyWpYzYBAuIC8P2UnaW0BgBRKzVhi1nY9DauUuiK4Ith6Yo-ht7FYeXSrpOlb7chBtt-jm3Rh3YM36MblmPrOldk4WJhu0VxYH7OTrxtk7v4q1P2dn_3Onvkzy8PT7PbZz4nqQZOEhdQC12BrETlamq8snXjEYlkqb3ExltUjfZkK9Foq5wCQJTzioRVgqbsar83v_C1dWkw67CNXT5pUAisiLTS2YV71zyGlKLzpo-rjY2jKcHsaJo9TZNpml-aBnOI9qGUzd2Hi_-rD6R-AG_7eVA</recordid><startdate>20201001</startdate><enddate>20201001</enddate><creator>Ning, Bo</creator><creator>Zhang, Mi</creator><creator>Bai, Yanyun</creator><creator>Tai, Xiumei</creator><creator>Wang, Wanxu</creator><creator>Wang, Guoyong</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope></search><sort><creationdate>20201001</creationdate><title>Comparison of the properties of perfluoroalkyl polyoxyethylene ether and alkyl polyoxyethylene ether</title><author>Ning, Bo ; Zhang, Mi ; Bai, Yanyun ; Tai, Xiumei ; Wang, Wanxu ; Wang, Guoyong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-352d0947805848e93bf6a9bf2233517f52bfa26b7f3a84b7a6e600225c834a643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Biodegradability</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Complex Fluids and Microfluidics</topic><topic>Density functional theory</topic><topic>Food Science</topic><topic>Hydrocarbons</topic><topic>Nanotechnology and Microengineering</topic><topic>Optimization</topic><topic>Original Contribution</topic><topic>Perfluoro compounds</topic><topic>Perfluoroalkyl & polyfluoroalkyl substances</topic><topic>Perfluorocarbons</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Polyoxyethylene</topic><topic>Properties (attributes)</topic><topic>Soft and Granular Matter</topic><topic>Surface properties</topic><topic>Surface tension</topic><topic>Surfactants</topic><topic>Wettability</topic><topic>Wetting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ning, Bo</creatorcontrib><creatorcontrib>Zhang, Mi</creatorcontrib><creatorcontrib>Bai, Yanyun</creatorcontrib><creatorcontrib>Tai, Xiumei</creatorcontrib><creatorcontrib>Wang, Wanxu</creatorcontrib><creatorcontrib>Wang, Guoyong</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><jtitle>Colloid and polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ning, Bo</au><au>Zhang, Mi</au><au>Bai, Yanyun</au><au>Tai, Xiumei</au><au>Wang, Wanxu</au><au>Wang, Guoyong</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparison of the properties of perfluoroalkyl polyoxyethylene ether and alkyl polyoxyethylene ether</atitle><jtitle>Colloid and polymer science</jtitle><stitle>Colloid Polym Sci</stitle><date>2020-10-01</date><risdate>2020</risdate><volume>298</volume><issue>10</issue><spage>1389</spage><epage>1399</epage><pages>1389-1399</pages><issn>0303-402X</issn><eissn>1435-1536</eissn><abstract>Short-chain fluorocarbon surfactants have been widely adopted as substitutes for long-chain fluorocarbon surfactants and hydrocarbon surfactants due to their biodegradability and excellent surface properties. In particular, fluorocarbon surfactants such as short-chain perfluoropolyethers have become a research hotspot in recent years. In this study, the short-chain perfluoroalkyl polyoxyethylene ether surfactant CF-310 is systematically compared with the traditional nonionic hydrocarbon surfactant alkyl polyoxyethylene ether AEO-7 in terms of its equilibrium surface tension, dynamic surface tension, wetting properties, and foam properties. The results show that CF-310 has better surface properties, better wettability on low-energy surfaces, and better foam properties than AEO-7. Structural optimization based on density functional theory (DFT) also indicates that the CF-310 fluorocarbon chain has a larger volume and a helical conformation, which are the main factors responsible for the superior surface performance, wettability, and foam performance of CF-310 compared with AEO-7. 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| subjects | Biodegradability Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Density functional theory Food Science Hydrocarbons Nanotechnology and Microengineering Optimization Original Contribution Perfluoro compounds Perfluoroalkyl & polyfluoroalkyl substances Perfluorocarbons Physical Chemistry Polymer Sciences Polyoxyethylene Properties (attributes) Soft and Granular Matter Surface properties Surface tension Surfactants Wettability Wetting |
| title | Comparison of the properties of perfluoroalkyl polyoxyethylene ether and alkyl polyoxyethylene ether |
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