Preparation of poly(methyl methacrylate) microspheres via photopolymerization initiated by LED light source
Poly(methyl methacrylate) (PMMA) microspheres were synthesized through visible light–induced photopolymerization of methyl methacrylate (MMA). 2,4,6-Trimethylbenzoyldipenylphosphine oxide (TPO), polyvinylpyrrolidone (PVP), and light-emitting diodes (LEDs) were used as the photoinitiator, stabilizer,...
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| Veröffentlicht in: | Colloid and polymer science 2020-10, Vol.298 (10), p.1285-1291 |
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| container_title | Colloid and polymer science |
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| creator | Xie, Chuanbao Leng, Kangwei Sheng, Jie Wang, Xuemei Li, Qianmin Song, Liang Liu, Lei Sun, Hejing Huang, Xiaowen Wang, Zhongwei Yu, Qing |
| description | Poly(methyl methacrylate) (PMMA) microspheres were synthesized through visible light–induced photopolymerization of methyl methacrylate (MMA). 2,4,6-Trimethylbenzoyldipenylphosphine oxide (TPO), polyvinylpyrrolidone (PVP), and light-emitting diodes (LEDs) were used as the photoinitiator, stabilizer, and light source, respectively. No other additive was involved. The effect of LEDs, TPO, and PVP was discussed. Results showed that PMMA microspheres with the size of 0.5–0.8 μm could be obtained when LED@385 nm was the light source, and the content of TPO and PVP was 2 wt% and 30 wt% of MMA. Moreover, the possible formation pathway of PMMA microspheres was proposed based on the investigation of reaction time and addition method of PVP.
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| doi_str_mv | 10.1007/s00396-020-04694-5 |
| format | Article |
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Graphical abstract</description><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Complex Fluids and Microfluidics</subject><subject>Food Science</subject><subject>Light emitting diodes</subject><subject>Light sources</subject><subject>Microspheres</subject><subject>Nanotechnology and Microengineering</subject><subject>Original Contribution</subject><subject>Photoinitiators</subject><subject>Photopolymerization</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Polymethyl methacrylate</subject><subject>Polyvinylpyrrolidone</subject><subject>Reaction time</subject><subject>Soft and Granular Matter</subject><issn>0303-402X</issn><issn>1435-1536</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kEtLxEAQhAdRcF39A54GvOgh2plXkqPo-oAFPSh4GyZJ72bWbBJnskL89U6M4M2-1OWrKroIOY3hMgZIrjwAz1QEDCIQKhOR3COzWHAZxZKrfTIDDjwSwN4OyZH3GwAQmVIz8v7ssDPO9LZtaLuiXVsP51vsq6Gmo5jCDbXp8YJubeFa31Xo0NNPa2hXtX078lt09mtKsI3tbcBLmg90ubiltV1XPfXtzhV4TA5WpvZ48qtz8nq3eLl5iJZP948318uo4FL1UZlywUDGCgGVSdIYGRZGJMAMk7lhGY-ZKZkIp1AkaZIjl0WuMCtNwUXG5-Rsyu1c-7FD3-tN6G9CpQ4ulnIuUggUm6jxLe9wpTtnt8YNOgY9jqqnUXUYVf-MqmUw8cnkA9ys0f1F_-P6Bvpoe7Y</recordid><startdate>20201001</startdate><enddate>20201001</enddate><creator>Xie, Chuanbao</creator><creator>Leng, Kangwei</creator><creator>Sheng, Jie</creator><creator>Wang, Xuemei</creator><creator>Li, Qianmin</creator><creator>Song, Liang</creator><creator>Liu, Lei</creator><creator>Sun, Hejing</creator><creator>Huang, Xiaowen</creator><creator>Wang, Zhongwei</creator><creator>Yu, Qing</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><orcidid>https://orcid.org/0000-0002-2810-486X</orcidid></search><sort><creationdate>20201001</creationdate><title>Preparation of poly(methyl methacrylate) microspheres via photopolymerization initiated by LED light source</title><author>Xie, Chuanbao ; 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No other additive was involved. The effect of LEDs, TPO, and PVP was discussed. Results showed that PMMA microspheres with the size of 0.5–0.8 μm could be obtained when LED@385 nm was the light source, and the content of TPO and PVP was 2 wt% and 30 wt% of MMA. Moreover, the possible formation pathway of PMMA microspheres was proposed based on the investigation of reaction time and addition method of PVP.
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| subjects | Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Complex Fluids and Microfluidics Food Science Light emitting diodes Light sources Microspheres Nanotechnology and Microengineering Original Contribution Photoinitiators Photopolymerization Physical Chemistry Polymer Sciences Polymethyl methacrylate Polyvinylpyrrolidone Reaction time Soft and Granular Matter |
| title | Preparation of poly(methyl methacrylate) microspheres via photopolymerization initiated by LED light source |
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