Greener synthesis of 1,2,3-triazoles using a copper()-exchanged magnetically recoverable β-zeolite as catalyst

Herein, we describe the preparation and thorough characterization of a novel magnetically recoverable copper( i )-exchanged β-zeolite and its use as an efficient catalyst for the synthesis of 1,2,3-triazoles via the one-pot three-component reaction of organic halides, terminal acetylenes, and sodium...

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Veröffentlicht in:New journal of chemistry 2020-09, Vol.44 (35), p.1546-1553
Hauptverfasser: Costa, Elizama R, Andrade, Floyd C. D, de Albuquerque, Danilo Yano, Ferreira, Luanne E. M, Lima, Thiago M, Lima, Carolina G. S, Silva, Domingos S. A, Urquieta-González, Ernesto A, Paixão, Márcio W, Schwab, Ricardo S
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container_end_page 1553
container_issue 35
container_start_page 1546
container_title New journal of chemistry
container_volume 44
creator Costa, Elizama R
Andrade, Floyd C. D
de Albuquerque, Danilo Yano
Ferreira, Luanne E. M
Lima, Thiago M
Lima, Carolina G. S
Silva, Domingos S. A
Urquieta-González, Ernesto A
Paixão, Márcio W
Schwab, Ricardo S
description Herein, we describe the preparation and thorough characterization of a novel magnetically recoverable copper( i )-exchanged β-zeolite and its use as an efficient catalyst for the synthesis of 1,2,3-triazoles via the one-pot three-component reaction of organic halides, terminal acetylenes, and sodium azide in water. The magnetically recoverable β-zeolite could be easily separated from the reaction mixture with the aid of a magnet and reused in several consecutive reactions. Importantly, a series of characterizations studies allowed us to disclose the mechanism for the deactivation of the catalyst, and therefore to propose a method for its reactivation. A novel magnetically recoverable Cu( i )-exchanged β-zeolite catalyst was prepared, characterized and applied for the synthesis of 1,2,3-triazoles via the one-pot three-component reaction.
doi_str_mv 10.1039/d0nj02473b
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Activation
Catalysts
Chemical synthesis
Copper
Deactivation
Halides
Sodium azides
Triazoles
Zeolites
title Greener synthesis of 1,2,3-triazoles using a copper()-exchanged magnetically recoverable β-zeolite as catalyst
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