Temperature effect on aqueous NH4CN polymerization: Relationship between kinetic behaviour and structural properties

[Display omitted] •Temperature has a significant effect on the nature of NH4CN polymers.•Autocatalytic or nth order kinetic is conditioned by temperature for NH4CN polymerization.•The kinetic behaviour of the NH4CN polymerization presents diffusion limitations.•A reliable value for the activation en...

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Veröffentlicht in:	European polymer journal 2020-06, Vol.132, p.109719, Article 109719
Hauptverfasser:	Mas, Itziar, de la Fuente, José L., Ruiz-Bermejo, Marta
Format:	Artikel
Sprache:	eng
Schlagworte:	Astrobiology Autocatalysis Chemical analysis Empirical analysis HCN polymers Infrared analysis Kamal model Kinetic Kinetics Materials science NMR Nuclear magnetic resonance Polymerization Polymers Precipitation polymerization Reaction kinetics Spectroscopy Structural analysis Temperature Temperature effects
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