Microwave-Assisted Copper Slag-Catalyzed Green S-Arylation of Arenethiols with Arylboronic Acids

Diaryl sulfides have been synthesized in moderate to excellent yield by S -arylation of arenethiols with arylboronic acids using copper slag as a catalyst. Copper slag is a by-product obtained from smelting and refining of copper. Conventional heating method has been compared with the microwave-assi...

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Veröffentlicht in:Russian journal of organic chemistry 2020-07, Vol.56 (7), p.1300-1303
Hauptverfasser: Sarkate, A. P., Gavane, D. S., Kale, B. D., Karnik, K. S., Narula, I. S., Khandare, A. L., Rajhans, A. P., Jambhorkar, V. S.
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container_issue 7
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container_title Russian journal of organic chemistry
container_volume 56
creator Sarkate, A. P.
Gavane, D. S.
Kale, B. D.
Karnik, K. S.
Narula, I. S.
Khandare, A. L.
Rajhans, A. P.
Jambhorkar, V. S.
description Diaryl sulfides have been synthesized in moderate to excellent yield by S -arylation of arenethiols with arylboronic acids using copper slag as a catalyst. Copper slag is a by-product obtained from smelting and refining of copper. Conventional heating method has been compared with the microwave-assisted technique. The proposed microwave-assisted synthesis provides excellent yields of diaryl sulfides in a short time (10 min) and is ligand-free, green, and cost-effective.
doi_str_mv 10.1134/S107042802007026X
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subjects Chemistry
Chemistry and Materials Science
Copper
Organic Chemistry
Slag
Smelting
Sulfides
title Microwave-Assisted Copper Slag-Catalyzed Green S-Arylation of Arenethiols with Arylboronic Acids
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