Chemisorptive Synthesis, Self-Assembly of Complicated 2D and 3D Supramolecular Architectures (Role of Hydrogen Bonds and Secondary Interactions Au···S and S···Cl), and Thermal Behavior of Pseudo-Polymeric Gold(III)–Mercury(II) Dibutyldithiocarbamato-Chlorido Complexes

The interaction of mercury(II) dibutyl dithiocarbamate (BuDtc) with [AuCl 4 ] − anions in 2 M HCl was studied. The heterogeneous reaction of chemisorption binding of gold(III) from the solution leads to heteronuclear Au(III)–Hg(II) pseudo-polymeric complexes of the ionic type: ([Au{S 2 CN(C 4 H 9 )...

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