Improving structural, tribological and electrochemical properties of Ti6Al4V alloy with B-doped TiO2 thin films
B-doped TiO2 coatings with different B:Ti molar ratios were produced on Ti6Al4V alloy by a sol-gel dip-coating in order to improve tribological and electrochemical properties of Ti6Al4V. The properties of films were evaluated by XRD, XPS, SEM, surface tension-meter, tribotester and EIS. The highest...
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creator | Çelik, A. Acar, M.T. Yetim, T. Kovacı, H. Yetim, A.F. |
description | B-doped TiO2 coatings with different B:Ti molar ratios were produced on Ti6Al4V alloy by a sol-gel dip-coating in order to improve tribological and electrochemical properties of Ti6Al4V. The properties of films were evaluated by XRD, XPS, SEM, surface tension-meter, tribotester and EIS. The highest roughness and hardness were obtained from B:Ti molar ratio of 2:1 TiO2 thin-film. TiO2 and B-doped TiO2 improved the wear resistance. While the mean CoF of Ti6Al4V was 0.39, TiO2 films reduced CoF significantly. B-doped TiO2 showed higher wear resistance than substrate and TiO2-film. Corrosion resistance was enhanced by TiO2 and the increasing B molar ratio provided improvement. The surface state changed after coatings. While TiO2 film showed hydrophobic behavior, B-doped all films exhibited hydrophilic characteristics.
•The effect of B-doped TiO2 coatings on Ti6Al4V alloy were investigated.•Ti6Al4V samples were coated with TiO2 in different B:Ti molar ratios.•The increasing B ratio increased the hydrophilicity of thin films.•B-doping improved the mechanical, tribological and electrochemical performance of TiO2. |
doi_str_mv | 10.1016/j.triboint.2020.106210 |
format | Article |
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•The effect of B-doped TiO2 coatings on Ti6Al4V alloy were investigated.•Ti6Al4V samples were coated with TiO2 in different B:Ti molar ratios.•The increasing B ratio increased the hydrophilicity of thin films.•B-doping improved the mechanical, tribological and electrochemical performance of TiO2.</description><identifier>ISSN: 0301-679X</identifier><identifier>EISSN: 1879-2464</identifier><identifier>DOI: 10.1016/j.triboint.2020.106210</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>B-doping ; Ceramic coating ; Corrosion ; Corrosion resistance ; Corrosive wear ; Dip coatings ; Electrochemical analysis ; Friction ; Immersion coating ; Properties (attributes) ; Sol-gel processes ; Substrates ; Surface tension ; Thin films ; TiO2 ; Titanium base alloys ; Titanium dioxide ; Tribology ; Wear ; Wear resistance ; X ray photoelectron spectroscopy</subject><ispartof>Tribology international, 2020-06, Vol.146, p.106210, Article 106210</ispartof><rights>2020 Elsevier Ltd</rights><rights>Copyright Elsevier BV Jun 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c340t-e181dbf8d349bf88e50e40169f5beae4dc3e09d92027093409649c531cea98643</citedby><cites>FETCH-LOGICAL-c340t-e181dbf8d349bf88e50e40169f5beae4dc3e09d92027093409649c531cea98643</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.triboint.2020.106210$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Çelik, A.</creatorcontrib><creatorcontrib>Acar, M.T.</creatorcontrib><creatorcontrib>Yetim, T.</creatorcontrib><creatorcontrib>Kovacı, H.</creatorcontrib><creatorcontrib>Yetim, A.F.</creatorcontrib><title>Improving structural, tribological and electrochemical properties of Ti6Al4V alloy with B-doped TiO2 thin films</title><title>Tribology international</title><description>B-doped TiO2 coatings with different B:Ti molar ratios were produced on Ti6Al4V alloy by a sol-gel dip-coating in order to improve tribological and electrochemical properties of Ti6Al4V. The properties of films were evaluated by XRD, XPS, SEM, surface tension-meter, tribotester and EIS. The highest roughness and hardness were obtained from B:Ti molar ratio of 2:1 TiO2 thin-film. TiO2 and B-doped TiO2 improved the wear resistance. While the mean CoF of Ti6Al4V was 0.39, TiO2 films reduced CoF significantly. B-doped TiO2 showed higher wear resistance than substrate and TiO2-film. Corrosion resistance was enhanced by TiO2 and the increasing B molar ratio provided improvement. The surface state changed after coatings. While TiO2 film showed hydrophobic behavior, B-doped all films exhibited hydrophilic characteristics.
•The effect of B-doped TiO2 coatings on Ti6Al4V alloy were investigated.•Ti6Al4V samples were coated with TiO2 in different B:Ti molar ratios.•The increasing B ratio increased the hydrophilicity of thin films.•B-doping improved the mechanical, tribological and electrochemical performance of TiO2.</description><subject>B-doping</subject><subject>Ceramic coating</subject><subject>Corrosion</subject><subject>Corrosion resistance</subject><subject>Corrosive wear</subject><subject>Dip coatings</subject><subject>Electrochemical analysis</subject><subject>Friction</subject><subject>Immersion coating</subject><subject>Properties (attributes)</subject><subject>Sol-gel processes</subject><subject>Substrates</subject><subject>Surface tension</subject><subject>Thin films</subject><subject>TiO2</subject><subject>Titanium base alloys</subject><subject>Titanium dioxide</subject><subject>Tribology</subject><subject>Wear</subject><subject>Wear resistance</subject><subject>X ray photoelectron spectroscopy</subject><issn>0301-679X</issn><issn>1879-2464</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkF9PwjAUxRujiYh-BdPEV4ftVrb1TST-ISHhBY1vzWjvoEu3YlswfHsL02efbnJ7zuk9P4RuKRlRQvOHZhScXlndhVFK0uMyTyk5QwNaFjxJWc7O0YBkhCZ5wT8v0ZX3DSGkYLwYIDtrt87udbfGPridDDtXmXt8SjR2rWVlcNUpDAZkcFZuoD3tomkLLmjw2NZ4qfOJYR-4MsYe8LcOG_yUqKhQ8WmR4rDRHa61af01uqgr4-Hmdw7R-8vzcvqWzBevs-lknsiMkZAALala1aXKGI-jhDEBFsvyeryCCpiSGRCueCxcEB4tPGdcjjMqoeJlzrIhuutz46FfO_BBNHbnuvilSFmUs0iqjKq8V0lnvXdQi63TbeUOghJxhCsa8QdXHOGKHm40PvZGiB32GpzwUkMnQWkXQQll9X8RP3DzhuI</recordid><startdate>202006</startdate><enddate>202006</enddate><creator>Çelik, A.</creator><creator>Acar, M.T.</creator><creator>Yetim, T.</creator><creator>Kovacı, H.</creator><creator>Yetim, A.F.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>202006</creationdate><title>Improving structural, tribological and electrochemical properties of Ti6Al4V alloy with B-doped TiO2 thin films</title><author>Çelik, A. ; Acar, M.T. ; Yetim, T. ; Kovacı, H. ; Yetim, A.F.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c340t-e181dbf8d349bf88e50e40169f5beae4dc3e09d92027093409649c531cea98643</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>B-doping</topic><topic>Ceramic coating</topic><topic>Corrosion</topic><topic>Corrosion resistance</topic><topic>Corrosive wear</topic><topic>Dip coatings</topic><topic>Electrochemical analysis</topic><topic>Friction</topic><topic>Immersion coating</topic><topic>Properties (attributes)</topic><topic>Sol-gel processes</topic><topic>Substrates</topic><topic>Surface tension</topic><topic>Thin films</topic><topic>TiO2</topic><topic>Titanium base alloys</topic><topic>Titanium dioxide</topic><topic>Tribology</topic><topic>Wear</topic><topic>Wear resistance</topic><topic>X ray photoelectron spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Çelik, A.</creatorcontrib><creatorcontrib>Acar, M.T.</creatorcontrib><creatorcontrib>Yetim, T.</creatorcontrib><creatorcontrib>Kovacı, H.</creatorcontrib><creatorcontrib>Yetim, A.F.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Tribology international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Çelik, A.</au><au>Acar, M.T.</au><au>Yetim, T.</au><au>Kovacı, H.</au><au>Yetim, A.F.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improving structural, tribological and electrochemical properties of Ti6Al4V alloy with B-doped TiO2 thin films</atitle><jtitle>Tribology international</jtitle><date>2020-06</date><risdate>2020</risdate><volume>146</volume><spage>106210</spage><pages>106210-</pages><artnum>106210</artnum><issn>0301-679X</issn><eissn>1879-2464</eissn><abstract>B-doped TiO2 coatings with different B:Ti molar ratios were produced on Ti6Al4V alloy by a sol-gel dip-coating in order to improve tribological and electrochemical properties of Ti6Al4V. The properties of films were evaluated by XRD, XPS, SEM, surface tension-meter, tribotester and EIS. The highest roughness and hardness were obtained from B:Ti molar ratio of 2:1 TiO2 thin-film. TiO2 and B-doped TiO2 improved the wear resistance. While the mean CoF of Ti6Al4V was 0.39, TiO2 films reduced CoF significantly. B-doped TiO2 showed higher wear resistance than substrate and TiO2-film. Corrosion resistance was enhanced by TiO2 and the increasing B molar ratio provided improvement. The surface state changed after coatings. While TiO2 film showed hydrophobic behavior, B-doped all films exhibited hydrophilic characteristics.
•The effect of B-doped TiO2 coatings on Ti6Al4V alloy were investigated.•Ti6Al4V samples were coated with TiO2 in different B:Ti molar ratios.•The increasing B ratio increased the hydrophilicity of thin films.•B-doping improved the mechanical, tribological and electrochemical performance of TiO2.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.triboint.2020.106210</doi></addata></record> |
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subjects | B-doping Ceramic coating Corrosion Corrosion resistance Corrosive wear Dip coatings Electrochemical analysis Friction Immersion coating Properties (attributes) Sol-gel processes Substrates Surface tension Thin films TiO2 Titanium base alloys Titanium dioxide Tribology Wear Wear resistance X ray photoelectron spectroscopy |
title | Improving structural, tribological and electrochemical properties of Ti6Al4V alloy with B-doped TiO2 thin films |
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