The Power of Iodane‐Guided C−H Coupling: A Group‐Transfer Strategy in Which a Halogen Works for Its Money

Hypervalent organoiodane reagents are ubiquitous in organic synthesis, both as oxidants and as electrophilic group‐transfer agents. In addition to these hallmark applications, a complementary strategy is gaining momentum that exploits the ability of λ3‐iodanes to undergo iodine‐to‐arene group transf...

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Veröffentlicht in:	Angewandte Chemie 2020-09, Vol.132 (38), p.16434-16449
Hauptverfasser:	Chen, Wei W., Cuenca, Ana B., Shafir, Alexandr
Format:	Artikel
Sprache:	eng
Schlagworte:	Allyl compounds Chemical reactions Chemistry Coupling C−H functionalization haloarenes hypervalent iodine iodane-directed coupling Iodine Oxidants Oxidizing agents Phenols Reagents rearrangements Substrates
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