In-situ synthesis of TiC/graphene/Ti6Al4V composite coating by laser cladding

•The graphene reacted with Ti, and the TiC phase precipitated during laser cladding.•The formation mechanism of TiC phase has been revealed.•The interface of graphene/Ti6Al4V composite coating is well bonded by in-situ reactive. Graphene reinforced Ti6Al4V composite coating was prepared by laser cla...

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Veröffentlicht in:Materials letters 2020-07, Vol.270, p.127711, Article 127711
Hauptverfasser: Zhang, Lizheng, Zhao, Zhanyong, Bai, Peikang, Du, Wenbo, Li, Yuxin, Yang, Xiao, Wang, Qin
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container_end_page
container_issue
container_start_page 127711
container_title Materials letters
container_volume 270
creator Zhang, Lizheng
Zhao, Zhanyong
Bai, Peikang
Du, Wenbo
Li, Yuxin
Yang, Xiao
Wang, Qin
description •The graphene reacted with Ti, and the TiC phase precipitated during laser cladding.•The formation mechanism of TiC phase has been revealed.•The interface of graphene/Ti6Al4V composite coating is well bonded by in-situ reactive. Graphene reinforced Ti6Al4V composite coating was prepared by laser cladding, and the microstructure of the composite coating was studied. The results show that in-situ synthesis between graphene and Ti occurred during the laser cladding process, and the feathery TiC was formed. The TiC is homogeneously distributed between α′ acicular martensite. When the carbon content is 0.5%, it is the hypoeutectic composition. During the solidification process, the β-Ti was formed firstly. With further cooling of the alloy, the eutectic reaction occurred in the remaining liquid phase, and the β-Ti and TiC were formed. Then β-Ti was transformed to α′ acicular martensite. There are still some graphene in the graphene/Ti6Al4V composite coating, which is well combined with Ti6Al4V matrix.
doi_str_mv 10.1016/j.matlet.2020.127711
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Graphene reinforced Ti6Al4V composite coating was prepared by laser cladding, and the microstructure of the composite coating was studied. The results show that in-situ synthesis between graphene and Ti occurred during the laser cladding process, and the feathery TiC was formed. The TiC is homogeneously distributed between α′ acicular martensite. When the carbon content is 0.5%, it is the hypoeutectic composition. During the solidification process, the β-Ti was formed firstly. With further cooling of the alloy, the eutectic reaction occurred in the remaining liquid phase, and the β-Ti and TiC were formed. Then β-Ti was transformed to α′ acicular martensite. 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Graphene reinforced Ti6Al4V composite coating was prepared by laser cladding, and the microstructure of the composite coating was studied. The results show that in-situ synthesis between graphene and Ti occurred during the laser cladding process, and the feathery TiC was formed. The TiC is homogeneously distributed between α′ acicular martensite. When the carbon content is 0.5%, it is the hypoeutectic composition. During the solidification process, the β-Ti was formed firstly. With further cooling of the alloy, the eutectic reaction occurred in the remaining liquid phase, and the β-Ti and TiC were formed. Then β-Ti was transformed to α′ acicular martensite. There are still some graphene in the graphene/Ti6Al4V composite coating, which is well combined with Ti6Al4V matrix.</abstract><cop>Amsterdam</cop><pub>Elsevier B.V</pub><doi>10.1016/j.matlet.2020.127711</doi></addata></record>
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subjects Carbon content
Coating
Eutectic alloys
Eutectic reactions
Graphene
Laser beam cladding
Laser processing
Lasers
Liquid phases
Martensite
Materials science
Metals and alloys
Microstructure
Solidification
Synthesis
TiC
Titanium base alloys
Titanium carbide
title In-situ synthesis of TiC/graphene/Ti6Al4V composite coating by laser cladding
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