Activity Coefficients of the Components of the Binary Systems Consisting of Benzene, Diphenyl, and n-Alkanes
Theoretical calculations are compared to data from an experimental study of the position of eutectics in two-component systems consisting of benzene, diphenyl, and n -alkanes with 12 to 17 carbon atoms. Data on diphenyl– n -alkane ( n = 12–17) and benzene– n -alkane ( n = 12–17) systems are given fo...
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| Veröffentlicht in: | Russian Journal of Physical Chemistry A 2020-09, Vol.94 (9), p.1822-1826 |
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| container_issue | 9 |
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| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 94 |
| creator | Yakovlev, I. G. Garkushin, I. K. Kolyado, A. V. |
| description | Theoretical calculations are compared to data from an experimental study of the position of eutectics in two-component systems consisting of benzene, diphenyl, and
n
-alkanes with 12 to 17 carbon atoms. Data on diphenyl–
n
-alkane (
n
= 12–17) and benzene–
n
-alkane (
n
= 12–17) systems are given for the composition of eutectics, their melting points, and activity coefficients of each component. The theoretical study is based on the Schröder–Le Chatelier approach and the original UNIFAC system; the experimental study is performed via DTA. Deviations of the experimental data from ones calculated for the studied systems are presented. The change in the activity coefficients of benzene and
n
-hexadecane is illustrated graphically according to UNIFAC and the experimental data. |
| doi_str_mv | 10.1134/S0036024420090320 |
| format | Article |
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n
-alkanes with 12 to 17 carbon atoms. Data on diphenyl–
n
-alkane (
n
= 12–17) and benzene–
n
-alkane (
n
= 12–17) systems are given for the composition of eutectics, their melting points, and activity coefficients of each component. The theoretical study is based on the Schröder–Le Chatelier approach and the original UNIFAC system; the experimental study is performed via DTA. Deviations of the experimental data from ones calculated for the studied systems are presented. The change in the activity coefficients of benzene and
n
-hexadecane is illustrated graphically according to UNIFAC and the experimental data.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024420090320</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Activity coefficients ; Alkanes ; Benzene ; Binary systems ; Chemistry ; Chemistry and Materials Science ; Eutectic composition ; Hexadecane ; Hydrocarbons ; Mathematical analysis ; Melting points ; Physical Chemistry ; Physical Chemistry of Solutions</subject><ispartof>Russian Journal of Physical Chemistry A, 2020-09, Vol.94 (9), p.1822-1826</ispartof><rights>Pleiades Publishing, Ltd. 2020</rights><rights>Pleiades Publishing, Ltd. 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c1830-31b88fcdba339c1d6361d459b7ff33cd668a1c57d8c25f47958510add2ef832b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0036024420090320$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0036024420090320$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51298</link.rule.ids></links><search><creatorcontrib>Yakovlev, I. G.</creatorcontrib><creatorcontrib>Garkushin, I. K.</creatorcontrib><creatorcontrib>Kolyado, A. V.</creatorcontrib><title>Activity Coefficients of the Components of the Binary Systems Consisting of Benzene, Diphenyl, and n-Alkanes</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>Theoretical calculations are compared to data from an experimental study of the position of eutectics in two-component systems consisting of benzene, diphenyl, and
n
-alkanes with 12 to 17 carbon atoms. Data on diphenyl–
n
-alkane (
n
= 12–17) and benzene–
n
-alkane (
n
= 12–17) systems are given for the composition of eutectics, their melting points, and activity coefficients of each component. The theoretical study is based on the Schröder–Le Chatelier approach and the original UNIFAC system; the experimental study is performed via DTA. Deviations of the experimental data from ones calculated for the studied systems are presented. The change in the activity coefficients of benzene and
n
-hexadecane is illustrated graphically according to UNIFAC and the experimental data.</description><subject>Activity coefficients</subject><subject>Alkanes</subject><subject>Benzene</subject><subject>Binary systems</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Eutectic composition</subject><subject>Hexadecane</subject><subject>Hydrocarbons</subject><subject>Mathematical analysis</subject><subject>Melting points</subject><subject>Physical Chemistry</subject><subject>Physical Chemistry of Solutions</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kN1LwzAUxYMoOKd_gG8BX1fNbdI2fdzm_ICBD1PwrbT52DK7tDaZUP96UyYoiE8Xzv2dc7kHoUsg1wCU3awIoSmJGYsJyQmNyREaQUIh4il9PUajYR0N-1N05tyWEMYYsBGqp8KbD-N7PG-U1kYYZb3DjcZ-o4K2axv7W5kZW3Y9XvXOq50LgHXGeWPXAzBT9lNZNcG3pt0o29cTXFqJbTSt30qr3Dk60WXt1MX3HKOXu8Xz_CFaPt0_zqfLSACnJKJQca6FrEpKcwEypSlIluRVpjWlQqYpL0EkmeQiTjTL8oQnQEopY6U5jSs6RleH3LZr3vfK-WLb7DsbThahAcI4pBkECg6U6BrnOqWLtjO78F0BpBhKLf6UGjzxweMCa9eq-0n-3_QF7Vx4YQ</recordid><startdate>20200901</startdate><enddate>20200901</enddate><creator>Yakovlev, I. G.</creator><creator>Garkushin, I. K.</creator><creator>Kolyado, A. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200901</creationdate><title>Activity Coefficients of the Components of the Binary Systems Consisting of Benzene, Diphenyl, and n-Alkanes</title><author>Yakovlev, I. G. ; Garkushin, I. K. ; Kolyado, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1830-31b88fcdba339c1d6361d459b7ff33cd668a1c57d8c25f47958510add2ef832b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Activity coefficients</topic><topic>Alkanes</topic><topic>Benzene</topic><topic>Binary systems</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Eutectic composition</topic><topic>Hexadecane</topic><topic>Hydrocarbons</topic><topic>Mathematical analysis</topic><topic>Melting points</topic><topic>Physical Chemistry</topic><topic>Physical Chemistry of Solutions</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yakovlev, I. G.</creatorcontrib><creatorcontrib>Garkushin, I. K.</creatorcontrib><creatorcontrib>Kolyado, A. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yakovlev, I. G.</au><au>Garkushin, I. K.</au><au>Kolyado, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Activity Coefficients of the Components of the Binary Systems Consisting of Benzene, Diphenyl, and n-Alkanes</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2020-09-01</date><risdate>2020</risdate><volume>94</volume><issue>9</issue><spage>1822</spage><epage>1826</epage><pages>1822-1826</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>Theoretical calculations are compared to data from an experimental study of the position of eutectics in two-component systems consisting of benzene, diphenyl, and
n
-alkanes with 12 to 17 carbon atoms. Data on diphenyl–
n
-alkane (
n
= 12–17) and benzene–
n
-alkane (
n
= 12–17) systems are given for the composition of eutectics, their melting points, and activity coefficients of each component. The theoretical study is based on the Schröder–Le Chatelier approach and the original UNIFAC system; the experimental study is performed via DTA. Deviations of the experimental data from ones calculated for the studied systems are presented. The change in the activity coefficients of benzene and
n
-hexadecane is illustrated graphically according to UNIFAC and the experimental data.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024420090320</doi><tpages>5</tpages></addata></record> |
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| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Activity coefficients Alkanes Benzene Binary systems Chemistry Chemistry and Materials Science Eutectic composition Hexadecane Hydrocarbons Mathematical analysis Melting points Physical Chemistry Physical Chemistry of Solutions |
| title | Activity Coefficients of the Components of the Binary Systems Consisting of Benzene, Diphenyl, and n-Alkanes |
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