Analyzing the coloration of sodium borate glasses caused by sulfur species
Herein, coloration in sodium borate glasses containing sulfur were investigated and sulfur species in the glasses were determined using ultraviolet–visible (UV–vis), Raman, and fluorescence spectroscopy. Sample coloration varied from blue to brown and depended on alkali content and glass matrix comp...
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Veröffentlicht in: | Journal of the Ceramic Society of Japan 2020/09/01, Vol.128(9), pp.648-652 |
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creator | ASAHI, Taro KISHIDA, Riho NAKAYAMA, Susumu WADA, Noriyuki |
description | Herein, coloration in sodium borate glasses containing sulfur were investigated and sulfur species in the glasses were determined using ultraviolet–visible (UV–vis), Raman, and fluorescence spectroscopy. Sample coloration varied from blue to brown and depended on alkali content and glass matrix composition. Using UV–vis spectroscopy, several absorption bands were detected at 280, 380, and 580 nm. It was anticipated that the sulfur species, such as S2, S2−, and S3−, will be formed in the glass samples and will influence sample coloration. Raman spectroscopy suggested that the absorption band at approximately 580 nm was due to the S3− anion species, whereas fluorescence spectroscopy suggested that the absorption band at approximately 380 nm was due to S2− anion species. The ratio of these sulfur anion species varied with matrix glass compositions and had a strong effect on the sample coloration. Herein, the origin of these color centers is discussed from the viewpoint of the redox of the melt and borate glass network. |
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Sample coloration varied from blue to brown and depended on alkali content and glass matrix composition. Using UV–vis spectroscopy, several absorption bands were detected at 280, 380, and 580 nm. It was anticipated that the sulfur species, such as S2, S2−, and S3−, will be formed in the glass samples and will influence sample coloration. Raman spectroscopy suggested that the absorption band at approximately 580 nm was due to the S3− anion species, whereas fluorescence spectroscopy suggested that the absorption band at approximately 380 nm was due to S2− anion species. The ratio of these sulfur anion species varied with matrix glass compositions and had a strong effect on the sample coloration. Herein, the origin of these color centers is discussed from the viewpoint of the redox of the melt and borate glass network.</description><identifier>ISSN: 1882-0743</identifier><identifier>EISSN: 1348-6535</identifier><identifier>DOI: 10.2109/jcersj2.20111</identifier><language>eng</language><publisher>Tokyo: The Ceramic Society of Japan</publisher><subject>Absorption spectra ; Anions ; Borate glass ; Color centers ; Composition ; Fluorescence ; Glass ; Raman spectroscopy ; Sodium borates ; Spectrum analysis ; Sulfur ; UV–vis spectroscopy</subject><ispartof>Journal of the Ceramic Society of Japan, 2020/09/01, Vol.128(9), pp.648-652</ispartof><rights>2020 The Ceramic Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2020</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c489t-d5cb092d0e290c5dd0ac314e1405cdc33d3122cd5e1fb06b0de8fb8963432a793</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,1883,27924,27925</link.rule.ids></links><search><creatorcontrib>ASAHI, Taro</creatorcontrib><creatorcontrib>KISHIDA, Riho</creatorcontrib><creatorcontrib>NAKAYAMA, Susumu</creatorcontrib><creatorcontrib>WADA, Noriyuki</creatorcontrib><title>Analyzing the coloration of sodium borate glasses caused by sulfur species</title><title>Journal of the Ceramic Society of Japan</title><addtitle>J. Ceram. Soc. Japan</addtitle><description>Herein, coloration in sodium borate glasses containing sulfur were investigated and sulfur species in the glasses were determined using ultraviolet–visible (UV–vis), Raman, and fluorescence spectroscopy. Sample coloration varied from blue to brown and depended on alkali content and glass matrix composition. Using UV–vis spectroscopy, several absorption bands were detected at 280, 380, and 580 nm. It was anticipated that the sulfur species, such as S2, S2−, and S3−, will be formed in the glass samples and will influence sample coloration. Raman spectroscopy suggested that the absorption band at approximately 580 nm was due to the S3− anion species, whereas fluorescence spectroscopy suggested that the absorption band at approximately 380 nm was due to S2− anion species. The ratio of these sulfur anion species varied with matrix glass compositions and had a strong effect on the sample coloration. Herein, the origin of these color centers is discussed from the viewpoint of the redox of the melt and borate glass network.</description><subject>Absorption spectra</subject><subject>Anions</subject><subject>Borate glass</subject><subject>Color centers</subject><subject>Composition</subject><subject>Fluorescence</subject><subject>Glass</subject><subject>Raman spectroscopy</subject><subject>Sodium borates</subject><subject>Spectrum analysis</subject><subject>Sulfur</subject><subject>UV–vis spectroscopy</subject><issn>1882-0743</issn><issn>1348-6535</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNo9kM1PwzAMxSMEEmNw5B6Jc0c-2i45TtNgoElc4Bylibu16poRt4fx19N10y62Zf_8pPcIeeZsJjjTr7WDiLWYCcY5vyETLlOV5JnMbodZKZGweSrvyQNizVguUqkm5HPR2ub4V7Vb2u2AutCEaLsqtDSUFIOv-j0tTiug28YiAlJnewRPiyPFvin7SPEArgJ8JHelbRCeLn1Kft5W38t1svl6_1guNolLle4Sn7mCaeEZCM1c5j2zTvIUeMoy552UXnIhnM-AlwXLC-ZBlYXSuUylsHMtp-TlrHuI4bcH7Ewd-jjYQDN40lIpOVLJmXIxIEYozSFWexuPhjNzistc4jJjXAO_OvM1dnYLV9rGrnINXGkulNFjHf-ud7ez0UAr_wET0nfX</recordid><startdate>20200901</startdate><enddate>20200901</enddate><creator>ASAHI, Taro</creator><creator>KISHIDA, Riho</creator><creator>NAKAYAMA, Susumu</creator><creator>WADA, Noriyuki</creator><general>The Ceramic Society of Japan</general><general>Japan Science and Technology Agency</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20200901</creationdate><title>Analyzing the coloration of sodium borate glasses caused by sulfur species</title><author>ASAHI, Taro ; KISHIDA, Riho ; NAKAYAMA, Susumu ; WADA, Noriyuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c489t-d5cb092d0e290c5dd0ac314e1405cdc33d3122cd5e1fb06b0de8fb8963432a793</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Absorption spectra</topic><topic>Anions</topic><topic>Borate glass</topic><topic>Color centers</topic><topic>Composition</topic><topic>Fluorescence</topic><topic>Glass</topic><topic>Raman spectroscopy</topic><topic>Sodium borates</topic><topic>Spectrum analysis</topic><topic>Sulfur</topic><topic>UV–vis spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>ASAHI, Taro</creatorcontrib><creatorcontrib>KISHIDA, Riho</creatorcontrib><creatorcontrib>NAKAYAMA, Susumu</creatorcontrib><creatorcontrib>WADA, Noriyuki</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of the Ceramic Society of Japan</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>ASAHI, Taro</au><au>KISHIDA, Riho</au><au>NAKAYAMA, Susumu</au><au>WADA, Noriyuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Analyzing the coloration of sodium borate glasses caused by sulfur species</atitle><jtitle>Journal of the Ceramic Society of Japan</jtitle><addtitle>J. Ceram. Soc. Japan</addtitle><date>2020-09-01</date><risdate>2020</risdate><volume>128</volume><issue>9</issue><spage>648</spage><epage>652</epage><pages>648-652</pages><issn>1882-0743</issn><eissn>1348-6535</eissn><abstract>Herein, coloration in sodium borate glasses containing sulfur were investigated and sulfur species in the glasses were determined using ultraviolet–visible (UV–vis), Raman, and fluorescence spectroscopy. Sample coloration varied from blue to brown and depended on alkali content and glass matrix composition. Using UV–vis spectroscopy, several absorption bands were detected at 280, 380, and 580 nm. It was anticipated that the sulfur species, such as S2, S2−, and S3−, will be formed in the glass samples and will influence sample coloration. Raman spectroscopy suggested that the absorption band at approximately 580 nm was due to the S3− anion species, whereas fluorescence spectroscopy suggested that the absorption band at approximately 380 nm was due to S2− anion species. The ratio of these sulfur anion species varied with matrix glass compositions and had a strong effect on the sample coloration. Herein, the origin of these color centers is discussed from the viewpoint of the redox of the melt and borate glass network.</abstract><cop>Tokyo</cop><pub>The Ceramic Society of Japan</pub><doi>10.2109/jcersj2.20111</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Absorption spectra Anions Borate glass Color centers Composition Fluorescence Glass Raman spectroscopy Sodium borates Spectrum analysis Sulfur UV–vis spectroscopy |
title | Analyzing the coloration of sodium borate glasses caused by sulfur species |
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