Pressure-induced Esterification Reaction between Phosphoric Acid and Methanol
Esterification reaction between phosphoric acid and methanol proceeded markedly at 6 GPa and 25 °C. The yields of monomethyl phosphate and dimethyl phosphate were 17.0% and 0.3%, respectively. The yield of monomethyl phosphate at 6 GPa was at least 34 times higher than that under ambient conditions....
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| Veröffentlicht in: | Chemistry letters 2020-08, Vol.49 (8), p.885-887 |
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| container_title | Chemistry letters |
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| creator | Sun, Yuchen Fujimoto, Chikako Kagi, Hiroyuki |
| description | Esterification reaction between phosphoric acid and methanol proceeded markedly at 6 GPa and 25 °C. The yields of monomethyl phosphate and dimethyl phosphate were 17.0% and 0.3%, respectively. The yield of monomethyl phosphate at 6 GPa was at least 34 times higher than that under ambient conditions. The esterification reaction was accompanied by crystallization of ice VII, a high-pressure form of ice. It is likely that the formation of ice VII was the driving force of the esterification reaction. |
| doi_str_mv | 10.1246/cl.200289 |
| format | Article |
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The yields of monomethyl phosphate and dimethyl phosphate were 17.0% and 0.3%, respectively. The yield of monomethyl phosphate at 6 GPa was at least 34 times higher than that under ambient conditions. The esterification reaction was accompanied by crystallization of ice VII, a high-pressure form of ice. It is likely that the formation of ice VII was the driving force of the esterification reaction.</description><identifier>ISSN: 0366-7022</identifier><identifier>EISSN: 1348-0715</identifier><identifier>DOI: 10.1246/cl.200289</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><subject>Crystallization ; Esterification ; Ice formation ; Methanol ; Phosphoric acid</subject><ispartof>Chemistry letters, 2020-08, Vol.49 (8), p.885-887</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Chemical Society of Japan 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c414t-c623d17757561b37e46a57b85e3f6c6678633dd9a23fbb3cabc8e2cae92344dd3</citedby><cites>FETCH-LOGICAL-c414t-c623d17757561b37e46a57b85e3f6c6678633dd9a23fbb3cabc8e2cae92344dd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Sun, Yuchen</creatorcontrib><creatorcontrib>Fujimoto, Chikako</creatorcontrib><creatorcontrib>Kagi, Hiroyuki</creatorcontrib><title>Pressure-induced Esterification Reaction between Phosphoric Acid and Methanol</title><title>Chemistry letters</title><description>Esterification reaction between phosphoric acid and methanol proceeded markedly at 6 GPa and 25 °C. The yields of monomethyl phosphate and dimethyl phosphate were 17.0% and 0.3%, respectively. The yield of monomethyl phosphate at 6 GPa was at least 34 times higher than that under ambient conditions. The esterification reaction was accompanied by crystallization of ice VII, a high-pressure form of ice. It is likely that the formation of ice VII was the driving force of the esterification reaction.</description><subject>Crystallization</subject><subject>Esterification</subject><subject>Ice formation</subject><subject>Methanol</subject><subject>Phosphoric acid</subject><issn>0366-7022</issn><issn>1348-0715</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNplkEtLw0AUhQdRsFYX_oOAKxep88pMsiylPqDFIroOkzs3ZEqaqTMJ0n9vtAUXru5ZfOcc7iHkltEZ41I9QDvjlPK8OCMTJmSeUs2yczKhQqlUU84vyVWMW0ppXgg-IetNwBiHgKnr7ABok2XsMbjagemd75I3NPArKuy_ELtk0_i4b3xwkMzB2cR0Nllj35jOt9fkojZtxJvTnZKPx-X74jldvT69LOarFCSTfQqKC8u0znSmWCU0SmUyXeUZilqBUjpXQlhbGC7qqhJgKsiRg8GCCymtFVNyd8zdB_85YOzLrR9CN1aWXIpCZJxTNlL3RwqCjzFgXe6D25lwKBktf9YqoS2Pa42sOrEN7sbf2-jBYX_Ymr3p_tL_G78BFQhvdg</recordid><startdate>20200805</startdate><enddate>20200805</enddate><creator>Sun, Yuchen</creator><creator>Fujimoto, Chikako</creator><creator>Kagi, Hiroyuki</creator><general>The Chemical Society of Japan</general><general>Chemical Society of Japan</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20200805</creationdate><title>Pressure-induced Esterification Reaction between Phosphoric Acid and Methanol</title><author>Sun, Yuchen ; Fujimoto, Chikako ; Kagi, Hiroyuki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c414t-c623d17757561b37e46a57b85e3f6c6678633dd9a23fbb3cabc8e2cae92344dd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Crystallization</topic><topic>Esterification</topic><topic>Ice formation</topic><topic>Methanol</topic><topic>Phosphoric acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sun, Yuchen</creatorcontrib><creatorcontrib>Fujimoto, Chikako</creatorcontrib><creatorcontrib>Kagi, Hiroyuki</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sun, Yuchen</au><au>Fujimoto, Chikako</au><au>Kagi, Hiroyuki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Pressure-induced Esterification Reaction between Phosphoric Acid and Methanol</atitle><jtitle>Chemistry letters</jtitle><date>2020-08-05</date><risdate>2020</risdate><volume>49</volume><issue>8</issue><spage>885</spage><epage>887</epage><pages>885-887</pages><issn>0366-7022</issn><eissn>1348-0715</eissn><abstract>Esterification reaction between phosphoric acid and methanol proceeded markedly at 6 GPa and 25 °C. The yields of monomethyl phosphate and dimethyl phosphate were 17.0% and 0.3%, respectively. The yield of monomethyl phosphate at 6 GPa was at least 34 times higher than that under ambient conditions. The esterification reaction was accompanied by crystallization of ice VII, a high-pressure form of ice. It is likely that the formation of ice VII was the driving force of the esterification reaction.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/cl.200289</doi><tpages>3</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0366-7022 |
| ispartof | Chemistry letters, 2020-08, Vol.49 (8), p.885-887 |
| issn | 0366-7022 1348-0715 |
| language | eng |
| recordid | cdi_proquest_journals_2439352201 |
| source | Oxford University Press Journals All Titles (1996-Current) |
| subjects | Crystallization Esterification Ice formation Methanol Phosphoric acid |
| title | Pressure-induced Esterification Reaction between Phosphoric Acid and Methanol |
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