Hypervalent iodine in the structure of N-heterocycles: synthesis, structure, and application in organic synthesis

The review is devoted to one of the most substantial trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ 3 - and λ 5 -iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attentio...

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Veröffentlicht in:Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2020-07, Vol.56 (7), p.854-866
Hauptverfasser: Vlasenko, Yulia А., Yusubov, Mekhman S., Shafir, Alexandr, Postnikov, Pavel S.
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container_issue 7
container_start_page 854
container_title Chemistry of heterocyclic compounds (New York, N.Y. 1965)
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creator Vlasenko, Yulia А.
Yusubov, Mekhman S.
Shafir, Alexandr
Postnikov, Pavel S.
description The review is devoted to one of the most substantial trends in the chemistry of hypervalent iodine – synthesis, structure, and properties of heterocyclic and pseudoheterocyclic systems based on λ 3 - and λ 5 -iodanes. Among the variety of cyclic reagents based on hypervalent iodine, special attention has recently been paid to iodanes having close contact between I and N atoms. The review is addressing the synthetic approaches, structural features, and application of these reagents. The review includes more than 100 literature sources, mainly covering publications from 1990 to 2020 and key research from earlier years.
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subjects Chemical synthesis
Chemistry
Chemistry and Materials Science
Iodine
Organic Chemistry
Pharmacy
Reagents
title Hypervalent iodine in the structure of N-heterocycles: synthesis, structure, and application in organic synthesis
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