One-dimensional cyanide-bridged Fe(III)–Mn(II) magnetic complexes with different configurations derived from a new pentacyanoiron(III) building block
Two cyanide-bridged heterometallic Fe III –Mn II complexes with formula {[Mn(bipy)(H 2 O)] 2 [Fe(2-CH 3 im)(CN) 5 ] 2 } n · n CH 3 OH·4 n H 2 O ( 2 ) (bipy = 2,2′-bipyridine) and {[Mn(MAC)][Fe(2-CH 3 im)(CN) 5 ]} n · n DMF·3 n H 2 O ( 3 ) (MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octa...
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| Veröffentlicht in: | Transition metal chemistry (Weinheim) 2020-09, Vol.45 (6), p.373-380 |
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| container_title | Transition metal chemistry (Weinheim) |
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| creator | Hao, Xiaoyun Dou, Yong Cao, Tong Qin, Lan Zhou, Zhen Yang, Lu Li, Dacheng Liu, Qingyun Li, Yueyun Zhang, Daopeng |
| description | Two cyanide-bridged heterometallic Fe
III
–Mn
II
complexes with formula {[Mn(bipy)(H
2
O)]
2
[Fe(2-CH
3
im)(CN)
5
]
2
}
n
·
n
CH
3
OH·4
n
H
2
O (
2
) (bipy = 2,2′-bipyridine) and {[Mn(MAC)][Fe(2-CH
3
im)(CN)
5
]}
n
·
n
DMF·3
n
H
2
O (
3
) (MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene) have been successfully synthesized by assembling a newly designed pentacyanoiron(III) precursor [PPh
4
]
2
[Fe(CN)
5
(2-CH
3
im)]·2CH
3
OH (
1
) and two Mn(II) compounds containing bulky ancillary organic ligands as segments, and characterized by elemental analysis, infrared (IR) spectroscopy, and X-ray structure determination. X-ray diffraction analysis revealed one-dimensional (1D) ladder-like double or linear single infinite-chain structures for complex
2
and
3
, respectively, indicating the obvious steric influence of the auxiliary ligand(s) on the structural type. Experimental and theoretical investigations on the magnetic properties of the complexes showed the antiferromagnetic coupling between the cyanide-bridged low-spin Fe(III) ion and high-spin Mn(II) ion. |
| doi_str_mv | 10.1007/s11243-020-00389-6 |
| format | Article |
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III
–Mn
II
complexes with formula {[Mn(bipy)(H
2
O)]
2
[Fe(2-CH
3
im)(CN)
5
]
2
}
n
·
n
CH
3
OH·4
n
H
2
O (
2
) (bipy = 2,2′-bipyridine) and {[Mn(MAC)][Fe(2-CH
3
im)(CN)
5
]}
n
·
n
DMF·3
n
H
2
O (
3
) (MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene) have been successfully synthesized by assembling a newly designed pentacyanoiron(III) precursor [PPh
4
]
2
[Fe(CN)
5
(2-CH
3
im)]·2CH
3
OH (
1
) and two Mn(II) compounds containing bulky ancillary organic ligands as segments, and characterized by elemental analysis, infrared (IR) spectroscopy, and X-ray structure determination. X-ray diffraction analysis revealed one-dimensional (1D) ladder-like double or linear single infinite-chain structures for complex
2
and
3
, respectively, indicating the obvious steric influence of the auxiliary ligand(s) on the structural type. Experimental and theoretical investigations on the magnetic properties of the complexes showed the antiferromagnetic coupling between the cyanide-bridged low-spin Fe(III) ion and high-spin Mn(II) ion.</description><identifier>ISSN: 0340-4285</identifier><identifier>EISSN: 1572-901X</identifier><identifier>DOI: 10.1007/s11243-020-00389-6</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Antiferromagnetism ; Catalysis ; Chemical analysis ; Chemistry ; Chemistry and Materials Science ; Dimensional analysis ; Infrared analysis ; Infrared spectroscopy ; Inorganic Chemistry ; Ligands ; Magnetic properties ; Manganese ; Organometallic Chemistry ; Physical Chemistry</subject><ispartof>Transition metal chemistry (Weinheim), 2020-09, Vol.45 (6), p.373-380</ispartof><rights>Springer Nature Switzerland AG 2020</rights><rights>Springer Nature Switzerland AG 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-4e17289603bcee7528304559fae6ebb5db8eee5213f4cc0eebda3a32ecc48f383</citedby><cites>FETCH-LOGICAL-c319t-4e17289603bcee7528304559fae6ebb5db8eee5213f4cc0eebda3a32ecc48f383</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11243-020-00389-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11243-020-00389-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Hao, Xiaoyun</creatorcontrib><creatorcontrib>Dou, Yong</creatorcontrib><creatorcontrib>Cao, Tong</creatorcontrib><creatorcontrib>Qin, Lan</creatorcontrib><creatorcontrib>Zhou, Zhen</creatorcontrib><creatorcontrib>Yang, Lu</creatorcontrib><creatorcontrib>Li, Dacheng</creatorcontrib><creatorcontrib>Liu, Qingyun</creatorcontrib><creatorcontrib>Li, Yueyun</creatorcontrib><creatorcontrib>Zhang, Daopeng</creatorcontrib><title>One-dimensional cyanide-bridged Fe(III)–Mn(II) magnetic complexes with different configurations derived from a new pentacyanoiron(III) building block</title><title>Transition metal chemistry (Weinheim)</title><addtitle>Transit Met Chem</addtitle><description>Two cyanide-bridged heterometallic Fe
III
–Mn
II
complexes with formula {[Mn(bipy)(H
2
O)]
2
[Fe(2-CH
3
im)(CN)
5
]
2
}
n
·
n
CH
3
OH·4
n
H
2
O (
2
) (bipy = 2,2′-bipyridine) and {[Mn(MAC)][Fe(2-CH
3
im)(CN)
5
]}
n
·
n
DMF·3
n
H
2
O (
3
) (MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene) have been successfully synthesized by assembling a newly designed pentacyanoiron(III) precursor [PPh
4
]
2
[Fe(CN)
5
(2-CH
3
im)]·2CH
3
OH (
1
) and two Mn(II) compounds containing bulky ancillary organic ligands as segments, and characterized by elemental analysis, infrared (IR) spectroscopy, and X-ray structure determination. X-ray diffraction analysis revealed one-dimensional (1D) ladder-like double or linear single infinite-chain structures for complex
2
and
3
, respectively, indicating the obvious steric influence of the auxiliary ligand(s) on the structural type. Experimental and theoretical investigations on the magnetic properties of the complexes showed the antiferromagnetic coupling between the cyanide-bridged low-spin Fe(III) ion and high-spin Mn(II) ion.</description><subject>Antiferromagnetism</subject><subject>Catalysis</subject><subject>Chemical analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dimensional analysis</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Magnetic properties</subject><subject>Manganese</subject><subject>Organometallic Chemistry</subject><subject>Physical Chemistry</subject><issn>0340-4285</issn><issn>1572-901X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kb1OHDEUha0okbIhvACVpTRQmPhvdjwlQoGsBKIJEp3lsa8nJjP2xp7lp8s7UOT9eBK8LFK6VPdK95zvSucgdMDoMaO0_VoY41IQyimhVKiOLN-hBWtaTjrKbt6jBRWSEslV8xF9KuWWUtrwVi7Q36sIxIUJYgkpmhHbRxODA9Ln4AZw-AwOV6vV0fOfp8tYtyM8mSHCHCy2aVqP8AAF34f5J3bBe8gQ53qIPgybbOaKLNhBDneV5HOasMER7vG6ysz2Uwo5xdcHuN-E0YU44H5M9tdn9MGbscD-29xD12fffpx-JxdX56vTkwtiBetmIoG1XHVLKnoL0DZcCSqbpvMGltD3jesVADScCS-tpQC9M8IIDtZK5YUSe-jLjrvO6fcGyqxv0ybXIIqugapOKcmXVcV3KptTKRm8XucwmfyoGdXbAvSuAF0L0K8F6K1J7EyliuMA-R_6P64X3u2MSg</recordid><startdate>20200901</startdate><enddate>20200901</enddate><creator>Hao, Xiaoyun</creator><creator>Dou, Yong</creator><creator>Cao, Tong</creator><creator>Qin, Lan</creator><creator>Zhou, Zhen</creator><creator>Yang, Lu</creator><creator>Li, Dacheng</creator><creator>Liu, Qingyun</creator><creator>Li, Yueyun</creator><creator>Zhang, Daopeng</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20200901</creationdate><title>One-dimensional cyanide-bridged Fe(III)–Mn(II) magnetic complexes with different configurations derived from a new pentacyanoiron(III) building block</title><author>Hao, Xiaoyun ; Dou, Yong ; Cao, Tong ; Qin, Lan ; Zhou, Zhen ; Yang, Lu ; Li, Dacheng ; Liu, Qingyun ; Li, Yueyun ; Zhang, Daopeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-4e17289603bcee7528304559fae6ebb5db8eee5213f4cc0eebda3a32ecc48f383</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Antiferromagnetism</topic><topic>Catalysis</topic><topic>Chemical analysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dimensional analysis</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Magnetic properties</topic><topic>Manganese</topic><topic>Organometallic Chemistry</topic><topic>Physical Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hao, Xiaoyun</creatorcontrib><creatorcontrib>Dou, Yong</creatorcontrib><creatorcontrib>Cao, Tong</creatorcontrib><creatorcontrib>Qin, Lan</creatorcontrib><creatorcontrib>Zhou, Zhen</creatorcontrib><creatorcontrib>Yang, Lu</creatorcontrib><creatorcontrib>Li, Dacheng</creatorcontrib><creatorcontrib>Liu, Qingyun</creatorcontrib><creatorcontrib>Li, Yueyun</creatorcontrib><creatorcontrib>Zhang, Daopeng</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Transition metal chemistry (Weinheim)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hao, Xiaoyun</au><au>Dou, Yong</au><au>Cao, Tong</au><au>Qin, Lan</au><au>Zhou, Zhen</au><au>Yang, Lu</au><au>Li, Dacheng</au><au>Liu, Qingyun</au><au>Li, Yueyun</au><au>Zhang, Daopeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>One-dimensional cyanide-bridged Fe(III)–Mn(II) magnetic complexes with different configurations derived from a new pentacyanoiron(III) building block</atitle><jtitle>Transition metal chemistry (Weinheim)</jtitle><stitle>Transit Met Chem</stitle><date>2020-09-01</date><risdate>2020</risdate><volume>45</volume><issue>6</issue><spage>373</spage><epage>380</epage><pages>373-380</pages><issn>0340-4285</issn><eissn>1572-901X</eissn><abstract>Two cyanide-bridged heterometallic Fe
III
–Mn
II
complexes with formula {[Mn(bipy)(H
2
O)]
2
[Fe(2-CH
3
im)(CN)
5
]
2
}
n
·
n
CH
3
OH·4
n
H
2
O (
2
) (bipy = 2,2′-bipyridine) and {[Mn(MAC)][Fe(2-CH
3
im)(CN)
5
]}
n
·
n
DMF·3
n
H
2
O (
3
) (MAC = 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-[12.3.1]octadeca-1(18),2,12,14,16-pentaene) have been successfully synthesized by assembling a newly designed pentacyanoiron(III) precursor [PPh
4
]
2
[Fe(CN)
5
(2-CH
3
im)]·2CH
3
OH (
1
) and two Mn(II) compounds containing bulky ancillary organic ligands as segments, and characterized by elemental analysis, infrared (IR) spectroscopy, and X-ray structure determination. X-ray diffraction analysis revealed one-dimensional (1D) ladder-like double or linear single infinite-chain structures for complex
2
and
3
, respectively, indicating the obvious steric influence of the auxiliary ligand(s) on the structural type. Experimental and theoretical investigations on the magnetic properties of the complexes showed the antiferromagnetic coupling between the cyanide-bridged low-spin Fe(III) ion and high-spin Mn(II) ion.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11243-020-00389-6</doi><tpages>8</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0340-4285 |
| ispartof | Transition metal chemistry (Weinheim), 2020-09, Vol.45 (6), p.373-380 |
| issn | 0340-4285 1572-901X |
| language | eng |
| recordid | cdi_proquest_journals_2438988426 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Antiferromagnetism Catalysis Chemical analysis Chemistry Chemistry and Materials Science Dimensional analysis Infrared analysis Infrared spectroscopy Inorganic Chemistry Ligands Magnetic properties Manganese Organometallic Chemistry Physical Chemistry |
| title | One-dimensional cyanide-bridged Fe(III)–Mn(II) magnetic complexes with different configurations derived from a new pentacyanoiron(III) building block |
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