Enhanced catalytic activity of bio-fabricated ZnO NPs prepared by ultrasound-assisted route for the synthesis of tetraketone and benzylidenemalonitrile in hydrotropic aqueous medium
Mushroom-like mesoporous and hexagonal ZnO nanoparticles were synthesized from plant extract and chemical method respectively, by co-precipitation method in aqueous medium. Different morphological forms of ZnO NPs were characterized by XRD, TGA, FESEM, EDX, FTIR, UV–Vis and BET. Neem (Azadirachta in...
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| Veröffentlicht in: | Research on chemical intermediates 2020-10, Vol.46 (10), p.4723-4748 |
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| creator | Attar, Suraj R. Shinde, Bipin Kamble, Santosh B. |
| description | Mushroom-like mesoporous and hexagonal ZnO nanoparticles were synthesized from plant extract and chemical method respectively, by co-precipitation method in aqueous medium. Different morphological forms of ZnO NPs were characterized by XRD, TGA, FESEM, EDX, FTIR, UV–Vis and BET. Neem (Azadirachta indica) leaf extract and ultrasound irradiation have a crucial role in the formation of different morphologies of ZnO NPs. ZnO NPs synthesized from plant extract and hydrotrope show a synergistic effect that leads to efficient synthesis of benzylidenemalonitrile and tetraketone derivatives at room temperature in water. Simple preparation of the catalyst, excellent yields, reusability of catalyst with consistent activity and ease of product isolation are the most significant advantages of this green protocol.
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| doi_str_mv | 10.1007/s11164-020-04233-5 |
| format | Article |
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Graphic abstract</description><subject>Aqueous solutions</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Catalytic activity</subject><subject>Chemical precipitation</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry, Multidisciplinary</subject><subject>Hydrotropes</subject><subject>Inorganic Chemistry</subject><subject>Morphology</subject><subject>Mushrooms</subject><subject>Nanoparticles</subject><subject>Physical Chemistry</subject><subject>Physical Sciences</subject><subject>Room temperature</subject><subject>Science & Technology</subject><subject>Synergistic effect</subject><subject>Ultrasonic imaging</subject><subject>Ultrasound</subject><subject>Zinc oxide</subject><issn>0922-6168</issn><issn>1568-5675</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>AOWDO</sourceid><recordid>eNqNkcuO1DAQRSMEEs3AD7CyxBIZ_Igd9xK1hoc0mmEBGzaR7VRoD2k72M6g8F_8H9UEwQ6xKst17nW5btM85ewFZ6x7WTjnuqVMMMpaISVV95odV9pQpTt1v9mxvRBUc20eNo9KuWWMK2PYrvlxGY82ehiIt9VOaw2eWF_DXagrSSNxIdHRuhywjdCneEOu3xcyZ5htxgu3kmWq2Za0xIHaUkI5czktFciYMqlHIGWNWLB1dqyA-BeoKQKxER0gfl-nMECEk51SDDWHCUiI5LgOOdWc5vNMXxdISyEnGMJyetw8GO1U4MnvetF8fH354fCWXt28eXd4dUW9VLrSFhx3Ro6t165zo7BKayk6BsZ4AKsk852RRu5dO3I_uL1pcYOetyC8tMzJi-bZ5jvnhAOU2t-mJUd8shetNB0TxrRIiY3yOZWSYeznHE42rz1n_TmefounR_P-Vzy9QpHZRN_ApbH4AJjCHyFjTKm91kbgifFDqLaGFA-45YrS5_8vRVpudEEifob89w__GO8nxe-49w</recordid><startdate>20201001</startdate><enddate>20201001</enddate><creator>Attar, Suraj R.</creator><creator>Shinde, Bipin</creator><creator>Kamble, Santosh B.</creator><general>Springer Netherlands</general><general>Springer Nature</general><general>Springer Nature B.V</general><scope>AOWDO</scope><scope>BLEPL</scope><scope>DTL</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-1596-9696</orcidid><orcidid>https://orcid.org/0000-0002-9605-7321</orcidid><orcidid>https://orcid.org/0000-0002-4668-1628</orcidid></search><sort><creationdate>20201001</creationdate><title>Enhanced catalytic activity of bio-fabricated ZnO NPs prepared by ultrasound-assisted route for the synthesis of tetraketone and benzylidenemalonitrile in hydrotropic aqueous medium</title><author>Attar, Suraj R. ; Shinde, Bipin ; Kamble, Santosh B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-4eb1b83f4c6b7bf2a5663270e88ceea530c783839b4f1cdb984020c14e2c3a0b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aqueous solutions</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Catalytic activity</topic><topic>Chemical precipitation</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry, Multidisciplinary</topic><topic>Hydrotropes</topic><topic>Inorganic Chemistry</topic><topic>Morphology</topic><topic>Mushrooms</topic><topic>Nanoparticles</topic><topic>Physical Chemistry</topic><topic>Physical Sciences</topic><topic>Room temperature</topic><topic>Science & Technology</topic><topic>Synergistic effect</topic><topic>Ultrasonic imaging</topic><topic>Ultrasound</topic><topic>Zinc oxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Attar, Suraj R.</creatorcontrib><creatorcontrib>Shinde, Bipin</creatorcontrib><creatorcontrib>Kamble, Santosh B.</creatorcontrib><collection>Web of Science - Science Citation Index Expanded - 2020</collection><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>CrossRef</collection><jtitle>Research on chemical intermediates</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Attar, Suraj R.</au><au>Shinde, Bipin</au><au>Kamble, Santosh B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced catalytic activity of bio-fabricated ZnO NPs prepared by ultrasound-assisted route for the synthesis of tetraketone and benzylidenemalonitrile in hydrotropic aqueous medium</atitle><jtitle>Research on chemical intermediates</jtitle><stitle>Res Chem Intermed</stitle><stitle>RES CHEM INTERMEDIAT</stitle><date>2020-10-01</date><risdate>2020</risdate><volume>46</volume><issue>10</issue><spage>4723</spage><epage>4748</epage><pages>4723-4748</pages><issn>0922-6168</issn><eissn>1568-5675</eissn><abstract>Mushroom-like mesoporous and hexagonal ZnO nanoparticles were synthesized from plant extract and chemical method respectively, by co-precipitation method in aqueous medium. Different morphological forms of ZnO NPs were characterized by XRD, TGA, FESEM, EDX, FTIR, UV–Vis and BET. Neem (Azadirachta indica) leaf extract and ultrasound irradiation have a crucial role in the formation of different morphologies of ZnO NPs. ZnO NPs synthesized from plant extract and hydrotrope show a synergistic effect that leads to efficient synthesis of benzylidenemalonitrile and tetraketone derivatives at room temperature in water. Simple preparation of the catalyst, excellent yields, reusability of catalyst with consistent activity and ease of product isolation are the most significant advantages of this green protocol.
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| source | SpringerNature Journals; Web of Science - Science Citation Index Expanded - 2020<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /> |
| subjects | Aqueous solutions Catalysis Catalysts Catalytic activity Chemical precipitation Chemical synthesis Chemistry Chemistry and Materials Science Chemistry, Multidisciplinary Hydrotropes Inorganic Chemistry Morphology Mushrooms Nanoparticles Physical Chemistry Physical Sciences Room temperature Science & Technology Synergistic effect Ultrasonic imaging Ultrasound Zinc oxide |
| title | Enhanced catalytic activity of bio-fabricated ZnO NPs prepared by ultrasound-assisted route for the synthesis of tetraketone and benzylidenemalonitrile in hydrotropic aqueous medium |
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