Pd/C Catalyzed selective hydrogenation of nitrobenzene to cyclohexanone oxime in the presence of NH2OH·HCl: Influence of the operative variables and insights on the reaction mechanism

Consecutive, parallel reactions and equilibria affecting the selectivity in cyclohexanone oxime. [Display omitted] •Nitrobenzene hydrogenation catalyzed by Pd/C in the presence of NH2OH HCl forms Aniline and cyclohexanone oxime.•The best solvent are ethers followed by dichloromethane and dimethylcar...

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Veröffentlicht in:	Applied catalysis. A, General General, 2020-05, Vol.598, p.117570, Article 117570
Hauptverfasser:	Pietrobon, L., Ronchin, L., Sadraoui, C., Pontello, R., Tosetto, C., Vavasori, A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Ammonium chloride Aniline Aniline hydrogenation Catalysts Cyclohexanone Cyclohexanone oxime Ethers Hydrogenation NH2OH hydrogenation Nitrobenzene Nitrobenzene hydrogenation Palladium Pd catalysts Reaction intermediates Reaction mechanisms Selectivity Solvents Substrates
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