Experimental study on the storage and release characteristics of phase change materials with different nanomaterials as addictives

The effect of nanomaterials on the thermal behavior of Decanoic-Caprylic Acid (DA-CA) binary eutectic mixture was investigated experimentally. Different high thermal conductivity nanomaterials, including nano-sized iron oxide (Fe 2 O 3 ), nano-sized copper (Cu), hydroxylated multi-walled carbon nano...

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Veröffentlicht in:Heat and mass transfer 2020-09, Vol.56 (9), p.2769-2777
Hauptverfasser: Zhang, Shihua, Zhang, Xuelai, Xu, Xiaofeng, Zhao, Yi
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container_title Heat and mass transfer
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creator Zhang, Shihua
Zhang, Xuelai
Xu, Xiaofeng
Zhao, Yi
description The effect of nanomaterials on the thermal behavior of Decanoic-Caprylic Acid (DA-CA) binary eutectic mixture was investigated experimentally. Different high thermal conductivity nanomaterials, including nano-sized iron oxide (Fe 2 O 3 ), nano-sized copper (Cu), hydroxylated multi-walled carbon nanotubes (MWCNT-OH), and dispersant Span-60, were added into DA-CA, respectively. The nanomaterial-enhanced phase change materials (NePCMs) were prepared by the ultrasonic oscillation method. The effects of nanomaterials on the cool storage performance of DA-CA were studied from the types and concentrations of nanomaterials. The experimental results showed that as the nanomaterials mass concentration increased, the thermal conductivity increased first and then gradually stabilized. The thermal conductivity trend for the composites added to the nanomaterials was: 0.40 g·L −1 Fe 2 O 3  > 0.10 g·L −1 MWCNT-OH > 0.30 g·L −1 Cu. DA-CA + 0.40 g·L −1 Fe 2 O 3 exhibited the best thermal properties, and its thermal conductivity increased by 36.8%, and the thermal storage time decreased by 38%. After 500 times thermal stability test, the NePCMs still maintained the appropriate phase change temperature and high latent heat. Therefore, this material has potential as part of the cold chain logistics for fruit and vegetable preservation.
doi_str_mv 10.1007/s00231-020-02882-1
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Different high thermal conductivity nanomaterials, including nano-sized iron oxide (Fe 2 O 3 ), nano-sized copper (Cu), hydroxylated multi-walled carbon nanotubes (MWCNT-OH), and dispersant Span-60, were added into DA-CA, respectively. The nanomaterial-enhanced phase change materials (NePCMs) were prepared by the ultrasonic oscillation method. The effects of nanomaterials on the cool storage performance of DA-CA were studied from the types and concentrations of nanomaterials. The experimental results showed that as the nanomaterials mass concentration increased, the thermal conductivity increased first and then gradually stabilized. The thermal conductivity trend for the composites added to the nanomaterials was: 0.40 g·L −1 Fe 2 O 3  &gt; 0.10 g·L −1 MWCNT-OH &gt; 0.30 g·L −1 Cu. DA-CA + 0.40 g·L −1 Fe 2 O 3 exhibited the best thermal properties, and its thermal conductivity increased by 36.8%, and the thermal storage time decreased by 38%. After 500 times thermal stability test, the NePCMs still maintained the appropriate phase change temperature and high latent heat. 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Different high thermal conductivity nanomaterials, including nano-sized iron oxide (Fe 2 O 3 ), nano-sized copper (Cu), hydroxylated multi-walled carbon nanotubes (MWCNT-OH), and dispersant Span-60, were added into DA-CA, respectively. The nanomaterial-enhanced phase change materials (NePCMs) were prepared by the ultrasonic oscillation method. The effects of nanomaterials on the cool storage performance of DA-CA were studied from the types and concentrations of nanomaterials. The experimental results showed that as the nanomaterials mass concentration increased, the thermal conductivity increased first and then gradually stabilized. The thermal conductivity trend for the composites added to the nanomaterials was: 0.40 g·L −1 Fe 2 O 3  &gt; 0.10 g·L −1 MWCNT-OH &gt; 0.30 g·L −1 Cu. DA-CA + 0.40 g·L −1 Fe 2 O 3 exhibited the best thermal properties, and its thermal conductivity increased by 36.8%, and the thermal storage time decreased by 38%. After 500 times thermal stability test, the NePCMs still maintained the appropriate phase change temperature and high latent heat. 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Different high thermal conductivity nanomaterials, including nano-sized iron oxide (Fe 2 O 3 ), nano-sized copper (Cu), hydroxylated multi-walled carbon nanotubes (MWCNT-OH), and dispersant Span-60, were added into DA-CA, respectively. The nanomaterial-enhanced phase change materials (NePCMs) were prepared by the ultrasonic oscillation method. The effects of nanomaterials on the cool storage performance of DA-CA were studied from the types and concentrations of nanomaterials. The experimental results showed that as the nanomaterials mass concentration increased, the thermal conductivity increased first and then gradually stabilized. The thermal conductivity trend for the composites added to the nanomaterials was: 0.40 g·L −1 Fe 2 O 3  &gt; 0.10 g·L −1 MWCNT-OH &gt; 0.30 g·L −1 Cu. DA-CA + 0.40 g·L −1 Fe 2 O 3 exhibited the best thermal properties, and its thermal conductivity increased by 36.8%, and the thermal storage time decreased by 38%. After 500 times thermal stability test, the NePCMs still maintained the appropriate phase change temperature and high latent heat. Therefore, this material has potential as part of the cold chain logistics for fruit and vegetable preservation.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s00231-020-02882-1</doi><tpages>9</tpages></addata></record>
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subjects Copper
Dispersants
Engineering
Engineering Thermodynamics
Heat and Mass Transfer
Heat conductivity
Heat transfer
Industrial Chemistry/Chemical Engineering
Iron oxides
Latent heat
Logistics
Multi wall carbon nanotubes
Nanomaterials
Octanoic acid
Original
Phase change materials
Stability tests
Thermal conductivity
Thermal energy
Thermal stability
Thermal storage
Thermodynamic properties
Thermodynamics
Ultrasonic testing
title Experimental study on the storage and release characteristics of phase change materials with different nanomaterials as addictives
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