Ultraviolet-protecting, flexible and stable photovoltaic-assisted piezoelectric hybrid unit nanogenerator for simultaneously harvesting ultraviolet light and mechanical energies

Owing to the ecological destruction and the energy crisis, harvesting green energy from the environment has become a hot issue in modern times. Here, a facile, flexible and stable hybrid unit nanogenerator (NG) with ultraviolet (UV) protection based on poly(vinylidene fluoride) (PVDF) piezoelectric...

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Veröffentlicht in:Journal of materials science 2020-11, Vol.55 (31), p.15222-15237
Hauptverfasser: Liu, Xi, Li, Jie, Fang, Zhaozhou, Wang, Chen, Shu, Luosheng, Han, Jing
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container_issue 31
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creator Liu, Xi
Li, Jie
Fang, Zhaozhou
Wang, Chen
Shu, Luosheng
Han, Jing
description Owing to the ecological destruction and the energy crisis, harvesting green energy from the environment has become a hot issue in modern times. Here, a facile, flexible and stable hybrid unit nanogenerator (NG) with ultraviolet (UV) protection based on poly(vinylidene fluoride) (PVDF) piezoelectric nanogenerator (PENG) unit and ultraviolet photovoltaic (SC) unit is fabricated. Specially, self-made thiophenyl soluble conjugated polymer (scp)/zinc oxide (ZnO) quantum dots nanocomposite film was prepared by spin-coating in ambient air condition as UV photoelectric and UV-protective thin film. The flexible photovoltaic films were found to exhibit good photovoltaic performance with a dominating fraction of UV absorption. Under external mechanical forces and UV LED illumination, and the open-circuit output voltage and short-circuit current of the device were significantly enhanced by UV LED constant light exposure. To specify this device performance, the effects of different external mechanical forces and UV illumination on the output of hybrid unit are also analyzed, the open-circuit output voltage of the device was significantly influenced by UV illumination. To demonstrate the practical applications of flexible hybrid unit NG, it exhibits high performance with a maximum power density of 0.97 mW/cm 3 . The device is able to charge a 33-μF capacitor to 3.6 V within a short time span (60 s) and drive a red LED for a few seconds. This work explores new prospects for UV-protective energy harvesting which can eventually boost up the self-powered electronic robotics and wearable systems based on renewable energy. Graphic abstract
doi_str_mv 10.1007/s10853-020-05078-4
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Here, a facile, flexible and stable hybrid unit nanogenerator (NG) with ultraviolet (UV) protection based on poly(vinylidene fluoride) (PVDF) piezoelectric nanogenerator (PENG) unit and ultraviolet photovoltaic (SC) unit is fabricated. Specially, self-made thiophenyl soluble conjugated polymer (scp)/zinc oxide (ZnO) quantum dots nanocomposite film was prepared by spin-coating in ambient air condition as UV photoelectric and UV-protective thin film. The flexible photovoltaic films were found to exhibit good photovoltaic performance with a dominating fraction of UV absorption. Under external mechanical forces and UV LED illumination, and the open-circuit output voltage and short-circuit current of the device were significantly enhanced by UV LED constant light exposure. To specify this device performance, the effects of different external mechanical forces and UV illumination on the output of hybrid unit are also analyzed, the open-circuit output voltage of the device was significantly influenced by UV illumination. To demonstrate the practical applications of flexible hybrid unit NG, it exhibits high performance with a maximum power density of 0.97 mW/cm 3 . The device is able to charge a 33-μF capacitor to 3.6 V within a short time span (60 s) and drive a red LED for a few seconds. This work explores new prospects for UV-protective energy harvesting which can eventually boost up the self-powered electronic robotics and wearable systems based on renewable energy. Graphic abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10853-020-05078-4</doi><tpages>16</tpages><orcidid>https://orcid.org/0000-0002-5715-7725</orcidid></addata></record>
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subjects Alternative energy sources
Automation
Characterization and Evaluation of Materials
Chemistry and Materials Science
Circuits
Classical Mechanics
Clean energy
Coatings
Crystallography and Scattering Methods
Dielectric films
Electric generators
Electric potential
Electric power generation
Electric power production
Energy harvesting
Energy Materials
Green technology
Illumination
Light emitting diodes
Manufacturing engineering
Materials Science
Maximum power density
Nanocomposites
Nanogenerators
Photoelectricity
Piezoelectricity
Polymer Sciences
Polyvinylidene fluoride
Polyvinylidene fluorides
Quantum dots
Robotics
Short circuit currents
Solar energy industry
Solid Mechanics
Spin coating
Thin films
Ultraviolet radiation
Vinylidene fluoride
Voltage
Zinc oxide
Zinc oxides
title Ultraviolet-protecting, flexible and stable photovoltaic-assisted piezoelectric hybrid unit nanogenerator for simultaneously harvesting ultraviolet light and mechanical energies
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