Dispersed Nickel-Based Catalyst for Enhanced Oil Recovery (EOR) Under Limited Hydrogen Conditions
Heavy crude oil enhanced into a lighter oil by hydrocracking process with nickel nanoparticles (Ni NPs) as catalysts. Ni NPs were synthesized by colloidal method (chemical reduction of metal salts). The reduction of nickel nitrate hexahydrate ((Ni(NO 3 ) 2 ·6H 2 O) was done using sodium borohydride...
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| Veröffentlicht in: | Topics in catalysis 2020-08, Vol.63 (5-6), p.504-510 |
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| creator | Morelos-Santos, O. Reyes de la Torre, A. I. Melo-Banda, J. A. Mendoza-Martínez, A. M. Schacht-Hernández, P. Portales-Martínez, B. Soto-Escalante, I. Domínguez-Esquivel, J. M. José-Yacamán, M. |
| description | Heavy crude oil enhanced into a lighter oil by hydrocracking process with nickel nanoparticles (Ni NPs) as catalysts. Ni NPs were synthesized by colloidal method (chemical reduction of metal salts). The reduction of nickel nitrate hexahydrate ((Ni(NO
3
)
2
·6H
2
O) was done using sodium borohydride (NaBH
4
) as a reducing agent in presence of polyvinylpyrrolidone which worked as a protective and stabilizing agent; ethanol was used as a solvent. The properties of the nanoparticles were investigated by FT-IR, TEM, XRD, and HRTEM. These techniques confirmed the formation of Ni NPs with an average size of 10 nm and a tetragonal structure. The experiments were carried out in a batch reactor at 45 Kg
f
cm
−2
(initial H
2
pressure), 380 °C, stirring speed of 500 rpm and reaction time of 1 h. In all cases, the increase in the concentration of Ni nanoparticles improved the physical and chemical properties of heavy crude oil, even in limited hydrogen conditions; these properties were measured in terms of viscosity, SARA analysis, sulfur and nitrogen removal, and chromatographic analysis of gaseous products. The asphaltenes conversion was of 26.31% and moderate sulfur removal was achieved, these results are promising for EOR application.
Graphic Abstract |
| doi_str_mv | 10.1007/s11244-020-01227-w |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2434255749</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2434255749</sourcerecordid><originalsourceid>FETCH-LOGICAL-c356t-2c2f125db3f1640e23a88c05f483f5bfd1918176d90f80a04dc4f6831f3bc4e43</originalsourceid><addsrcrecordid>eNp9kMtKAzEUhgdRsFZfwNWAG11Ek5NkLkut1QrFQrHrkOZSp04zNZla5u1NHcGdq3Ph-8-BL0kuCb4lGOd3gRBgDGHACBOAHO2PkgHhOaASQ3EcewyAOIfiNDkLYY0xkLwsB4l8rMLW-GB0-lqpD1OjB3kYRrKVdRfa1DY-Hbt36VTczqo6nRvVfBnfpdfj2fwmXThtfDqtNlUbgUmnfbMyLh01Tldt1bhwnpxYWQdz8VuHyeJp_DaaoOns-WV0P0WK8qxFoMAS4HpJLckYNkBlUSjMLSuo5UurSUkKkme6xLbAEjOtmM0KSixdKmYYHSZX_d2tbz53JrRi3ey8iy8FMMqA85yVkYKeUr4JwRsrtr7aSN8JgsVBpehViqhS_KgU-xiifShE2K2M_zv9T-obxC92Pg</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2434255749</pqid></control><display><type>article</type><title>Dispersed Nickel-Based Catalyst for Enhanced Oil Recovery (EOR) Under Limited Hydrogen Conditions</title><source>Springer Nature - Complete Springer Journals</source><creator>Morelos-Santos, O. ; Reyes de la Torre, A. I. ; Melo-Banda, J. A. ; Mendoza-Martínez, A. M. ; Schacht-Hernández, P. ; Portales-Martínez, B. ; Soto-Escalante, I. ; Domínguez-Esquivel, J. M. ; José-Yacamán, M.</creator><creatorcontrib>Morelos-Santos, O. ; Reyes de la Torre, A. I. ; Melo-Banda, J. A. ; Mendoza-Martínez, A. M. ; Schacht-Hernández, P. ; Portales-Martínez, B. ; Soto-Escalante, I. ; Domínguez-Esquivel, J. M. ; José-Yacamán, M.</creatorcontrib><description>Heavy crude oil enhanced into a lighter oil by hydrocracking process with nickel nanoparticles (Ni NPs) as catalysts. Ni NPs were synthesized by colloidal method (chemical reduction of metal salts). The reduction of nickel nitrate hexahydrate ((Ni(NO
3
)
2
·6H
2
O) was done using sodium borohydride (NaBH
4
) as a reducing agent in presence of polyvinylpyrrolidone which worked as a protective and stabilizing agent; ethanol was used as a solvent. The properties of the nanoparticles were investigated by FT-IR, TEM, XRD, and HRTEM. These techniques confirmed the formation of Ni NPs with an average size of 10 nm and a tetragonal structure. The experiments were carried out in a batch reactor at 45 Kg
f
cm
−2
(initial H
2
pressure), 380 °C, stirring speed of 500 rpm and reaction time of 1 h. In all cases, the increase in the concentration of Ni nanoparticles improved the physical and chemical properties of heavy crude oil, even in limited hydrogen conditions; these properties were measured in terms of viscosity, SARA analysis, sulfur and nitrogen removal, and chromatographic analysis of gaseous products. The asphaltenes conversion was of 26.31% and moderate sulfur removal was achieved, these results are promising for EOR application.
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3
)
2
·6H
2
O) was done using sodium borohydride (NaBH
4
) as a reducing agent in presence of polyvinylpyrrolidone which worked as a protective and stabilizing agent; ethanol was used as a solvent. The properties of the nanoparticles were investigated by FT-IR, TEM, XRD, and HRTEM. These techniques confirmed the formation of Ni NPs with an average size of 10 nm and a tetragonal structure. The experiments were carried out in a batch reactor at 45 Kg
f
cm
−2
(initial H
2
pressure), 380 °C, stirring speed of 500 rpm and reaction time of 1 h. In all cases, the increase in the concentration of Ni nanoparticles improved the physical and chemical properties of heavy crude oil, even in limited hydrogen conditions; these properties were measured in terms of viscosity, SARA analysis, sulfur and nitrogen removal, and chromatographic analysis of gaseous products. The asphaltenes conversion was of 26.31% and moderate sulfur removal was achieved, these results are promising for EOR application.
Graphic Abstract</description><subject>Asphaltenes</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical properties</subject><subject>Chemical reduction</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Colloid chemistry</subject><subject>Crude oil</subject><subject>Enhanced oil recovery</subject><subject>Ethanol</subject><subject>Heavy petroleum</subject><subject>Hydrocracking</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Nanoparticles</subject><subject>Nickel</subject><subject>Nitrates</subject><subject>Nitrogen removal</subject><subject>Original Paper</subject><subject>Pharmacy</subject><subject>Physical Chemistry</subject><subject>Polyvinylpyrrolidone</subject><subject>Reaction time</subject><subject>Reducing agents</subject><subject>Stabilizers (agents)</subject><subject>Sulfur</subject><subject>Sulfur removal</subject><issn>1022-5528</issn><issn>1572-9028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kMtKAzEUhgdRsFZfwNWAG11Ek5NkLkut1QrFQrHrkOZSp04zNZla5u1NHcGdq3Ph-8-BL0kuCb4lGOd3gRBgDGHACBOAHO2PkgHhOaASQ3EcewyAOIfiNDkLYY0xkLwsB4l8rMLW-GB0-lqpD1OjB3kYRrKVdRfa1DY-Hbt36VTczqo6nRvVfBnfpdfj2fwmXThtfDqtNlUbgUmnfbMyLh01Tldt1bhwnpxYWQdz8VuHyeJp_DaaoOns-WV0P0WK8qxFoMAS4HpJLckYNkBlUSjMLSuo5UurSUkKkme6xLbAEjOtmM0KSixdKmYYHSZX_d2tbz53JrRi3ey8iy8FMMqA85yVkYKeUr4JwRsrtr7aSN8JgsVBpehViqhS_KgU-xiifShE2K2M_zv9T-obxC92Pg</recordid><startdate>20200801</startdate><enddate>20200801</enddate><creator>Morelos-Santos, O.</creator><creator>Reyes de la Torre, A. I.</creator><creator>Melo-Banda, J. A.</creator><creator>Mendoza-Martínez, A. M.</creator><creator>Schacht-Hernández, P.</creator><creator>Portales-Martínez, B.</creator><creator>Soto-Escalante, I.</creator><creator>Domínguez-Esquivel, J. M.</creator><creator>José-Yacamán, M.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-5593-1326</orcidid></search><sort><creationdate>20200801</creationdate><title>Dispersed Nickel-Based Catalyst for Enhanced Oil Recovery (EOR) Under Limited Hydrogen Conditions</title><author>Morelos-Santos, O. ; Reyes de la Torre, A. I. ; Melo-Banda, J. A. ; Mendoza-Martínez, A. M. ; Schacht-Hernández, P. ; Portales-Martínez, B. ; Soto-Escalante, I. ; Domínguez-Esquivel, J. M. ; José-Yacamán, M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c356t-2c2f125db3f1640e23a88c05f483f5bfd1918176d90f80a04dc4f6831f3bc4e43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Asphaltenes</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical properties</topic><topic>Chemical reduction</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Colloid chemistry</topic><topic>Crude oil</topic><topic>Enhanced oil recovery</topic><topic>Ethanol</topic><topic>Heavy petroleum</topic><topic>Hydrocracking</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Nanoparticles</topic><topic>Nickel</topic><topic>Nitrates</topic><topic>Nitrogen removal</topic><topic>Original Paper</topic><topic>Pharmacy</topic><topic>Physical Chemistry</topic><topic>Polyvinylpyrrolidone</topic><topic>Reaction time</topic><topic>Reducing agents</topic><topic>Stabilizers (agents)</topic><topic>Sulfur</topic><topic>Sulfur removal</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Morelos-Santos, O.</creatorcontrib><creatorcontrib>Reyes de la Torre, A. I.</creatorcontrib><creatorcontrib>Melo-Banda, J. A.</creatorcontrib><creatorcontrib>Mendoza-Martínez, A. M.</creatorcontrib><creatorcontrib>Schacht-Hernández, P.</creatorcontrib><creatorcontrib>Portales-Martínez, B.</creatorcontrib><creatorcontrib>Soto-Escalante, I.</creatorcontrib><creatorcontrib>Domínguez-Esquivel, J. M.</creatorcontrib><creatorcontrib>José-Yacamán, M.</creatorcontrib><collection>CrossRef</collection><jtitle>Topics in catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Morelos-Santos, O.</au><au>Reyes de la Torre, A. I.</au><au>Melo-Banda, J. A.</au><au>Mendoza-Martínez, A. M.</au><au>Schacht-Hernández, P.</au><au>Portales-Martínez, B.</au><au>Soto-Escalante, I.</au><au>Domínguez-Esquivel, J. M.</au><au>José-Yacamán, M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dispersed Nickel-Based Catalyst for Enhanced Oil Recovery (EOR) Under Limited Hydrogen Conditions</atitle><jtitle>Topics in catalysis</jtitle><stitle>Top Catal</stitle><date>2020-08-01</date><risdate>2020</risdate><volume>63</volume><issue>5-6</issue><spage>504</spage><epage>510</epage><pages>504-510</pages><issn>1022-5528</issn><eissn>1572-9028</eissn><abstract>Heavy crude oil enhanced into a lighter oil by hydrocracking process with nickel nanoparticles (Ni NPs) as catalysts. Ni NPs were synthesized by colloidal method (chemical reduction of metal salts). The reduction of nickel nitrate hexahydrate ((Ni(NO
3
)
2
·6H
2
O) was done using sodium borohydride (NaBH
4
) as a reducing agent in presence of polyvinylpyrrolidone which worked as a protective and stabilizing agent; ethanol was used as a solvent. The properties of the nanoparticles were investigated by FT-IR, TEM, XRD, and HRTEM. These techniques confirmed the formation of Ni NPs with an average size of 10 nm and a tetragonal structure. The experiments were carried out in a batch reactor at 45 Kg
f
cm
−2
(initial H
2
pressure), 380 °C, stirring speed of 500 rpm and reaction time of 1 h. In all cases, the increase in the concentration of Ni nanoparticles improved the physical and chemical properties of heavy crude oil, even in limited hydrogen conditions; these properties were measured in terms of viscosity, SARA analysis, sulfur and nitrogen removal, and chromatographic analysis of gaseous products. The asphaltenes conversion was of 26.31% and moderate sulfur removal was achieved, these results are promising for EOR application.
Graphic Abstract</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11244-020-01227-w</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-5593-1326</orcidid></addata></record> |
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| issn | 1022-5528 1572-9028 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Asphaltenes Catalysis Catalysts Characterization and Evaluation of Materials Chemical properties Chemical reduction Chemical synthesis Chemistry Chemistry and Materials Science Chromatography Colloid chemistry Crude oil Enhanced oil recovery Ethanol Heavy petroleum Hydrocracking Industrial Chemistry/Chemical Engineering Nanoparticles Nickel Nitrates Nitrogen removal Original Paper Pharmacy Physical Chemistry Polyvinylpyrrolidone Reaction time Reducing agents Stabilizers (agents) Sulfur Sulfur removal |
| title | Dispersed Nickel-Based Catalyst for Enhanced Oil Recovery (EOR) Under Limited Hydrogen Conditions |
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