Iron–cobalt-catalyzed heterotrimerization of alkynes and nitriles to polyfunctionalized pyridines

Based on the reactivity of half-sandwich complexes [Cp*Fe(NCMe) 3 ]PF 6 and Cp*Co(1,2-Ph 2 PC 6 H 4 NH), (Cp* = Me 5 C 5 − ), the iron( ii )–cobalt( ii ) co-catalysis of the cycloaddition of alkynes to nitriles under mild reaction conditions has been studied. This method enables the synthesis of pol...

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Veröffentlicht in:	Organic Chemistry Frontiers 2020-08, Vol.7 (16), p.2196-2201
Hauptverfasser:	Xie, Yufang, Wu, Chengjuan, Jia, Changhao, Tung, Chen-Ho, Wang, Wenguang
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Catalysis Cobalt Crystallography Cycloaddition Iron Nitriles NMR Nuclear magnetic resonance Organic chemistry Pyridines
Online-Zugang:	Volltext
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