Compositionally modulated microstructure in nano-layered Ni-P metallic glass composite coating prepared by electrodeposition

Nano-domain metallic glass (or also termed as nanoglass) is a different modality of amorphous solid. Here we present a NiP metallic glass coating with periodic glassy/nanocomposite layered construction by multi-phase pulsed electrodeposition. The multilayered structure was identified by transmission...

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Veröffentlicht in:Surface & coatings technology 2020-05, Vol.389, p.125636, Article 125636
Hauptverfasser: Chen, W.Y., Chen, H.W., Li, W.P., Huang, J.C., Yu, H.S., Duh, J.G., Lan, S., Feng, T.
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container_end_page
container_issue
container_start_page 125636
container_title Surface & coatings technology
container_volume 389
creator Chen, W.Y.
Chen, H.W.
Li, W.P.
Huang, J.C.
Yu, H.S.
Duh, J.G.
Lan, S.
Feng, T.
description Nano-domain metallic glass (or also termed as nanoglass) is a different modality of amorphous solid. Here we present a NiP metallic glass coating with periodic glassy/nanocomposite layered construction by multi-phase pulsed electrodeposition. The multilayered structure was identified by transmission electron microscopy and atom probe tomography. There is a periodic layered structure, ~30 nm intervals with close dependence of elements distribution and crystallinity. The modulus mapping reveals ~95 GPa for loosely glassy interfacial regions and ~115 GPa for metallic glassy core regions. The NiP composite implies superior resistance to corrosion and wear. An interesting insight into architecture control is demonstrated, opening a new design for various nanoglasses coatings with potential industrial applications, such as a strong coating on electrocatalytic electrodes. •NiP nanoglass was prepared by multi-phase pulsed electrodeposition.•The multilayered elemental distribution and crystallinity was identified by TEM and APT.•Interfacial regions and core regions with different moduli were revealed by nanoidentation.
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subjects Amorphous materials
Atomic packing
Coated electrodes
Corrosion resistance
Corrosive wear
Electrodeposition
Glass coatings
Industrial applications
Mapping
Metallic glass
Metallic glasses
Multilayer
Nanocomposites
Nanoglass
Nickel
Wear resistance
title Compositionally modulated microstructure in nano-layered Ni-P metallic glass composite coating prepared by electrodeposition
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