Terbium-fluorido cluster: an energy cage for photoluminescence
We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb 6 (μ 3 -F) 8 (piv) 10 (Hpiv) 4 DMF]· x DMF· y H 2 O 1 . Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to...
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| Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2020-08, Vol.56 (64), p.913-9133 |
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| container_issue | 64 |
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| container_title | Chemical communications (Cambridge, England) |
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| creator | Ling, Bo-Kai Li, Junhao Zhai, Yuan-Qi Hsu, Hung-Kai Chan, Yi-Tsu Chen, Wei-Peng Han, Tian Zheng, Yan-Zhen |
| description | We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb
6
(μ
3
-F)
8
(piv)
10
(Hpiv)
4
DMF]·
x
DMF·
y
H
2
O
1
. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.
This work demonstrates that encapsulating terbium ions into a fluorido-bridged cage by organic ligands significantly enhances the luminescence quantum yield of such sub-nanosized materials. |
| doi_str_mv | 10.1039/d0cc02898c |
| format | Article |
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6
(μ
3
-F)
8
(piv)
10
(Hpiv)
4
DMF]·
x
DMF·
y
H
2
O
1
. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.
This work demonstrates that encapsulating terbium ions into a fluorido-bridged cage by organic ligands significantly enhances the luminescence quantum yield of such sub-nanosized materials.</description><identifier>ISSN: 1359-7345</identifier><identifier>EISSN: 1364-548X</identifier><identifier>DOI: 10.1039/d0cc02898c</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Clusters ; Computer simulation ; Crystallography ; Fluorescence ; Photoluminescence ; Terbium</subject><ispartof>Chemical communications (Cambridge, England), 2020-08, Vol.56 (64), p.913-9133</ispartof><rights>Copyright Royal Society of Chemistry 2020</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-7df0853f5c18c4178a8156a2c1f018c27f34983ebfd3da07afe10b6b6e9005f63</citedby><cites>FETCH-LOGICAL-c406t-7df0853f5c18c4178a8156a2c1f018c27f34983ebfd3da07afe10b6b6e9005f63</cites><orcidid>0000-0001-9658-2188 ; 0000-0001-9844-7860 ; 0000-0002-8732-0810 ; 0000-0002-8753-7999 ; 0000-0003-4056-097X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Ling, Bo-Kai</creatorcontrib><creatorcontrib>Li, Junhao</creatorcontrib><creatorcontrib>Zhai, Yuan-Qi</creatorcontrib><creatorcontrib>Hsu, Hung-Kai</creatorcontrib><creatorcontrib>Chan, Yi-Tsu</creatorcontrib><creatorcontrib>Chen, Wei-Peng</creatorcontrib><creatorcontrib>Han, Tian</creatorcontrib><creatorcontrib>Zheng, Yan-Zhen</creatorcontrib><title>Terbium-fluorido cluster: an energy cage for photoluminescence</title><title>Chemical communications (Cambridge, England)</title><description>We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb
6
(μ
3
-F)
8
(piv)
10
(Hpiv)
4
DMF]·
x
DMF·
y
H
2
O
1
. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.
This work demonstrates that encapsulating terbium ions into a fluorido-bridged cage by organic ligands significantly enhances the luminescence quantum yield of such sub-nanosized materials.</description><subject>Clusters</subject><subject>Computer simulation</subject><subject>Crystallography</subject><subject>Fluorescence</subject><subject>Photoluminescence</subject><subject>Terbium</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp90E1LxDAQBuAgCq6rF-9CxYsI1clXk3oQpH7CgpcVvJU0TdYubbMm7WH_vVlXFDyYy4SZh2F4ETrGcImB5lc1aA1E5lLvoAmmGUs5k2-7mz_PU0EZ30cHISwhPszlBN3Mja-asUttOzrf1C7R7RgG468T1SemN36xTrRamMQ6n6ze3eDasWt6E7TptTlEe1a1wRx91yl6fbifF0_p7OXxubidpZpBNqSitiA5tVxjqRkWUknMM0U0thA7RFjKcklNZWtaKxDKGgxVVmUmB-A2o1N0vt278u5jNGEouyZe0LaqN24MJWGEAAjBZKRnf-jSjb6P10VFCZWMCBzVxVZp70LwxpYr33TKr0sM5SbK8g6K4ivKIuKTLfZB_7jfqOP89L95uaot_QQmw3qT</recordid><startdate>20200811</startdate><enddate>20200811</enddate><creator>Ling, Bo-Kai</creator><creator>Li, Junhao</creator><creator>Zhai, Yuan-Qi</creator><creator>Hsu, Hung-Kai</creator><creator>Chan, Yi-Tsu</creator><creator>Chen, Wei-Peng</creator><creator>Han, Tian</creator><creator>Zheng, Yan-Zhen</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0001-9658-2188</orcidid><orcidid>https://orcid.org/0000-0001-9844-7860</orcidid><orcidid>https://orcid.org/0000-0002-8732-0810</orcidid><orcidid>https://orcid.org/0000-0002-8753-7999</orcidid><orcidid>https://orcid.org/0000-0003-4056-097X</orcidid></search><sort><creationdate>20200811</creationdate><title>Terbium-fluorido cluster: an energy cage for photoluminescence</title><author>Ling, Bo-Kai ; Li, Junhao ; Zhai, Yuan-Qi ; Hsu, Hung-Kai ; Chan, Yi-Tsu ; Chen, Wei-Peng ; Han, Tian ; Zheng, Yan-Zhen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-7df0853f5c18c4178a8156a2c1f018c27f34983ebfd3da07afe10b6b6e9005f63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Clusters</topic><topic>Computer simulation</topic><topic>Crystallography</topic><topic>Fluorescence</topic><topic>Photoluminescence</topic><topic>Terbium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ling, Bo-Kai</creatorcontrib><creatorcontrib>Li, Junhao</creatorcontrib><creatorcontrib>Zhai, Yuan-Qi</creatorcontrib><creatorcontrib>Hsu, Hung-Kai</creatorcontrib><creatorcontrib>Chan, Yi-Tsu</creatorcontrib><creatorcontrib>Chen, Wei-Peng</creatorcontrib><creatorcontrib>Han, Tian</creatorcontrib><creatorcontrib>Zheng, Yan-Zhen</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ling, Bo-Kai</au><au>Li, Junhao</au><au>Zhai, Yuan-Qi</au><au>Hsu, Hung-Kai</au><au>Chan, Yi-Tsu</au><au>Chen, Wei-Peng</au><au>Han, Tian</au><au>Zheng, Yan-Zhen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Terbium-fluorido cluster: an energy cage for photoluminescence</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2020-08-11</date><risdate>2020</risdate><volume>56</volume><issue>64</issue><spage>913</spage><epage>9133</epage><pages>913-9133</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>We report here that energy migration during luminescence can be extremely minimized by caging the fluorescent centers in a molecular cluster of [Tb
6
(μ
3
-F)
8
(piv)
10
(Hpiv)
4
DMF]·
x
DMF·
y
H
2
O
1
. Experimental and theoretical simulations reveal that bonding terbium with fluoride is the key to reducing the non-radiative multi-phonon relaxation processes, which is disparate to the common hydroxy-based lanthanide clusters.
This work demonstrates that encapsulating terbium ions into a fluorido-bridged cage by organic ligands significantly enhances the luminescence quantum yield of such sub-nanosized materials.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d0cc02898c</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0001-9658-2188</orcidid><orcidid>https://orcid.org/0000-0001-9844-7860</orcidid><orcidid>https://orcid.org/0000-0002-8732-0810</orcidid><orcidid>https://orcid.org/0000-0002-8753-7999</orcidid><orcidid>https://orcid.org/0000-0003-4056-097X</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1359-7345 |
| ispartof | Chemical communications (Cambridge, England), 2020-08, Vol.56 (64), p.913-9133 |
| issn | 1359-7345 1364-548X |
| language | eng |
| recordid | cdi_proquest_journals_2432384271 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Clusters Computer simulation Crystallography Fluorescence Photoluminescence Terbium |
| title | Terbium-fluorido cluster: an energy cage for photoluminescence |
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