Tailoring polymer dispersity by mixing chain transfer agents in PET-RAFT polymerization

Here we report a simple and versatile batch methodology to tailor polymer dispersity utilizing PET-RAFT polymerization. By mixing two chain transfer agents (CTAs) possessing different transfer constants (a higher and a lower transfer constant CTA) in different ratios, control over the dispersity ( =...

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Veröffentlicht in:	Polymer chemistry 2020-08, Vol.11 (31), p.4968-4972
Hauptverfasser:	Parkatzidis, Kostas, Truong, Nghia P, Antonopoulou, Maria Nefeli, Whitfield, Richard, Konkolewicz, Dominik, Anastasaki, Athina
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylates Addition polymerization Block copolymers Chain transfer Chemical synthesis Deoxygenation Dispersion Light irradiation Molecular weight distribution NMR Nuclear magnetic resonance Polyethylene terephthalate Polymer chemistry Polymerization
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