An Improved Biomimetic Formal Synthesis of Abyssomicin C and atrop‐Abyssomicin C

Biomimetic approaches towards the synthesis of abysssomicin C and atrop‐abyssomicin C are based on a powerful intramolecular Diels–Alder reaction (IMDA) of a butenolide derivative attached to a keto‐triene side chain, where the stereogenic centers and the carbon framework are established in one step...

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Veröffentlicht in:	European journal of organic chemistry 2020-08, Vol.2020 (29), p.4547-4557
Hauptverfasser:	Vidali, Veroniki P., Canko, Aleksander, Peroulias, Angelos D., Georgas, Evangelos T., Bouzas, Emmanuel, Herniman, Julie M., Couladouros, Elias A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Biomimetic synthesis Biomimetics Coupling Cycloaddition Lipase Methylene Natural products Oxidation Polyketides Precursors Spiro compounds Synthesis
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