Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature
A cyclometalated rhodium complex has been found to show excellent activity in dehydrogenation of methanol at room temperature. This feature allows for the catalytic transfer hydrogenation of various aldehydes with methanol as both hydrogen source and solvent under very mild conditions. A hydroxy fun...
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| Veröffentlicht in: | Asian journal of organic chemistry 2020-08, Vol.9 (8), p.1174-1178 |
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| container_title | Asian journal of organic chemistry |
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| creator | Chen, Zhenyu Chen, Guanhong Aboo, Ahmed H. Iggo, Jonathan Xiao, Jianliang |
| description | A cyclometalated rhodium complex has been found to show excellent activity in dehydrogenation of methanol at room temperature. This feature allows for the catalytic transfer hydrogenation of various aldehydes with methanol as both hydrogen source and solvent under very mild conditions. A hydroxy functionality on the ligand is shown to be critical for this unusual activity.
Transferring hydrogen out of methanol near room temperature: a rhodium complex has been found to catalyze transfer hydrogenation of a variety of aldehydes at 25–30 °C, made possible by the para‐OH functionality on the ligand. |
| doi_str_mv | 10.1002/ajoc.202000241 |
| format | Article |
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Transferring hydrogen out of methanol near room temperature: a rhodium complex has been found to catalyze transfer hydrogenation of a variety of aldehydes at 25–30 °C, made possible by the para‐OH functionality on the ligand.</description><identifier>ISSN: 2193-5807</identifier><identifier>EISSN: 2193-5815</identifier><identifier>DOI: 10.1002/ajoc.202000241</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Aldehydes ; Dehydrogenation ; Hydrogen storage ; Hydrogenation ; Methanol ; Organic chemistry ; Rhodium ; rhodium complex ; Room temperature ; transfer hydrogenation</subject><ispartof>Asian journal of organic chemistry, 2020-08, Vol.9 (8), p.1174-1178</ispartof><rights>2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2020 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3171-736db73ce60e4de4095fe1ebdc6a15d5d7dd2fe4ae66d808e7aaf52486ad01223</citedby><cites>FETCH-LOGICAL-c3171-736db73ce60e4de4095fe1ebdc6a15d5d7dd2fe4ae66d808e7aaf52486ad01223</cites><orcidid>0000-0003-2010-247X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fajoc.202000241$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fajoc.202000241$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>Chen, Zhenyu</creatorcontrib><creatorcontrib>Chen, Guanhong</creatorcontrib><creatorcontrib>Aboo, Ahmed H.</creatorcontrib><creatorcontrib>Iggo, Jonathan</creatorcontrib><creatorcontrib>Xiao, Jianliang</creatorcontrib><title>Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature</title><title>Asian journal of organic chemistry</title><description>A cyclometalated rhodium complex has been found to show excellent activity in dehydrogenation of methanol at room temperature. This feature allows for the catalytic transfer hydrogenation of various aldehydes with methanol as both hydrogen source and solvent under very mild conditions. A hydroxy functionality on the ligand is shown to be critical for this unusual activity.
Transferring hydrogen out of methanol near room temperature: a rhodium complex has been found to catalyze transfer hydrogenation of a variety of aldehydes at 25–30 °C, made possible by the para‐OH functionality on the ligand.</description><subject>Aldehydes</subject><subject>Dehydrogenation</subject><subject>Hydrogen storage</subject><subject>Hydrogenation</subject><subject>Methanol</subject><subject>Organic chemistry</subject><subject>Rhodium</subject><subject>rhodium complex</subject><subject>Room temperature</subject><subject>transfer hydrogenation</subject><issn>2193-5807</issn><issn>2193-5815</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkM1Lw0AQxRdRsNRePS94Tt2P7G7irRS1SqWg1esyzU5sSpqtuymS_96USj16mhnm9-YNj5BrzsacMXELG1-MBROsH1J-RgaC5zJRGVfnp56ZSzKKcdMzzJici3xAPl6wXUPjawqRzjoX_Cc29M3vQ4F3dBmgiSWG0wbayjfUl3RSO1x3DiNtEAJ99X5Ll7jdYYB2H_CKXJRQRxz91iF5f7hfTmfJfPH4NJ3Mk0JywxMjtVsZWaBmmDpMWa5K5LhyhQaunHLGOVFiCqi1y1iGBqBUIs00OMaFkENyc7y7C_5rj7G1m_71pre0IpUsy6VWvKfGR6oIPsaApd2Faguhs5zZQ3z2EJ89xdcL8qPgu6qx-4e2k-fF9E_7Aw11dEU</recordid><startdate>202008</startdate><enddate>202008</enddate><creator>Chen, Zhenyu</creator><creator>Chen, Guanhong</creator><creator>Aboo, Ahmed H.</creator><creator>Iggo, Jonathan</creator><creator>Xiao, Jianliang</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-2010-247X</orcidid></search><sort><creationdate>202008</creationdate><title>Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature</title><author>Chen, Zhenyu ; Chen, Guanhong ; Aboo, Ahmed H. ; Iggo, Jonathan ; Xiao, Jianliang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3171-736db73ce60e4de4095fe1ebdc6a15d5d7dd2fe4ae66d808e7aaf52486ad01223</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aldehydes</topic><topic>Dehydrogenation</topic><topic>Hydrogen storage</topic><topic>Hydrogenation</topic><topic>Methanol</topic><topic>Organic chemistry</topic><topic>Rhodium</topic><topic>rhodium complex</topic><topic>Room temperature</topic><topic>transfer hydrogenation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Zhenyu</creatorcontrib><creatorcontrib>Chen, Guanhong</creatorcontrib><creatorcontrib>Aboo, Ahmed H.</creatorcontrib><creatorcontrib>Iggo, Jonathan</creatorcontrib><creatorcontrib>Xiao, Jianliang</creatorcontrib><collection>CrossRef</collection><jtitle>Asian journal of organic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Zhenyu</au><au>Chen, Guanhong</au><au>Aboo, Ahmed H.</au><au>Iggo, Jonathan</au><au>Xiao, Jianliang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature</atitle><jtitle>Asian journal of organic chemistry</jtitle><date>2020-08</date><risdate>2020</risdate><volume>9</volume><issue>8</issue><spage>1174</spage><epage>1178</epage><pages>1174-1178</pages><issn>2193-5807</issn><eissn>2193-5815</eissn><abstract>A cyclometalated rhodium complex has been found to show excellent activity in dehydrogenation of methanol at room temperature. This feature allows for the catalytic transfer hydrogenation of various aldehydes with methanol as both hydrogen source and solvent under very mild conditions. A hydroxy functionality on the ligand is shown to be critical for this unusual activity.
Transferring hydrogen out of methanol near room temperature: a rhodium complex has been found to catalyze transfer hydrogenation of a variety of aldehydes at 25–30 °C, made possible by the para‐OH functionality on the ligand.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ajoc.202000241</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0003-2010-247X</orcidid></addata></record> |
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| ispartof | Asian journal of organic chemistry, 2020-08, Vol.9 (8), p.1174-1178 |
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| language | eng |
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| source | Wiley Journals |
| subjects | Aldehydes Dehydrogenation Hydrogen storage Hydrogenation Methanol Organic chemistry Rhodium rhodium complex Room temperature transfer hydrogenation |
| title | Methanol as Hydrogen Source: Transfer Hydrogenation of Aldehydes near Room Temperature |
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