Catalytic assay of Schiff base Co(II), Ni(II), Cu(II) and Zn(II) complexes for N-alkylation of heterocycles with 1,3-dibromopropane
N-alkylation of heterocycles with 1,3-dibromopropane using Schiff base Co(II), Ni(II), Cu(II) and Zn(II) transition metal complexes as a catalyst was studied in 1:1 and 2:1 coupling ratios under mild conditions. It was observed that all the complexes worked as efficient catalyst with product yield 7...
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| Veröffentlicht in: | Journal of chemical sciences (Bangalore, India) India), 2020-12, Vol.132 (1), Article 92 |
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| container_title | Journal of chemical sciences (Bangalore, India) |
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| creator | Hegade, Sujit Jadhav, Yuvraj Chavan, Sanjay Mulik, Ganpatrao Gaikwad, Gautam |
| description | N-alkylation of heterocycles with 1,3-dibromopropane using Schiff base Co(II), Ni(II), Cu(II) and Zn(II) transition metal complexes as a catalyst was studied in 1:1 and 2:1 coupling ratios under mild conditions. It was observed that all the complexes worked as efficient catalyst with product yield 78–92% for coupling ratio 1:1 and product yield 63–78% for coupling ratio 2:1. N-alkylation of heterocycles with 1,3-dibromopropane in 1:1 coupling ratio is easier with higher yields as compared with N-alkylation in 2:1 coupling ratio.
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N-Alkylation of heterocycles with 1,3-dibromopropane |
| doi_str_mv | 10.1007/s12039-020-01791-4 |
| format | Article |
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Graphic abstract
N-Alkylation of heterocycles with 1,3-dibromopropane</description><identifier>ISSN: 0974-3626</identifier><identifier>EISSN: 0973-7103</identifier><identifier>DOI: 10.1007/s12039-020-01791-4</identifier><language>eng</language><publisher>New Delhi: Springer India</publisher><subject>Alkylation ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination compounds ; Copper ; Coupling ; Imines ; Nickel ; Potassium ; Ratios ; Regular Article ; Transition metal compounds ; Zinc</subject><ispartof>Journal of chemical sciences (Bangalore, India), 2020-12, Vol.132 (1), Article 92</ispartof><rights>Indian Academy of Sciences 2020</rights><rights>Indian Academy of Sciences 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-1108d5893225f91c9eaf9e7fa2642fd3cf928a6c450464613b11e792a9efbc7a3</citedby><cites>FETCH-LOGICAL-c319t-1108d5893225f91c9eaf9e7fa2642fd3cf928a6c450464613b11e792a9efbc7a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12039-020-01791-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12039-020-01791-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Hegade, Sujit</creatorcontrib><creatorcontrib>Jadhav, Yuvraj</creatorcontrib><creatorcontrib>Chavan, Sanjay</creatorcontrib><creatorcontrib>Mulik, Ganpatrao</creatorcontrib><creatorcontrib>Gaikwad, Gautam</creatorcontrib><title>Catalytic assay of Schiff base Co(II), Ni(II), Cu(II) and Zn(II) complexes for N-alkylation of heterocycles with 1,3-dibromopropane</title><title>Journal of chemical sciences (Bangalore, India)</title><addtitle>J Chem Sci</addtitle><description>N-alkylation of heterocycles with 1,3-dibromopropane using Schiff base Co(II), Ni(II), Cu(II) and Zn(II) transition metal complexes as a catalyst was studied in 1:1 and 2:1 coupling ratios under mild conditions. It was observed that all the complexes worked as efficient catalyst with product yield 78–92% for coupling ratio 1:1 and product yield 63–78% for coupling ratio 2:1. N-alkylation of heterocycles with 1,3-dibromopropane in 1:1 coupling ratio is easier with higher yields as compared with N-alkylation in 2:1 coupling ratio.
Graphic abstract
N-Alkylation of heterocycles with 1,3-dibromopropane</description><subject>Alkylation</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Coupling</subject><subject>Imines</subject><subject>Nickel</subject><subject>Potassium</subject><subject>Ratios</subject><subject>Regular Article</subject><subject>Transition metal compounds</subject><subject>Zinc</subject><issn>0974-3626</issn><issn>0973-7103</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kLtOwzAARS0EEqXwA0yWWECqwa_E8YgiHpVQGYCFxXIcm6akcbBTQWZ-nLRBYmO6d7gP6QBwSvAlwVhcRUIxkwhTjDARkiC-ByZYCoYEwWx_5zliKU0PwVGMK4xZxgWbgO9cd7ruu8pAHaPuoXfwySwr52Cho4W5P5_PL2ZwUY2ab7YKdVPC12ZnjV-3tf2yETof4ALp-r2vdVf5Zru1tJ0N3vSmHgKfVbeEZMZQWRXBr30bfKsbewwOnK6jPfnVKXi5vXnO79HD4908v35AhhHZIUJwViaZZJQmThIjrXbSCqdpyqkrmXGSZjo1PME85SlhBSFWSKqldYURmk3B2bg7_H5sbOzUym9CM1wqyqlMEiIlG1J0TJngYwzWqTZUax16RbDawlYjbDXAVjvYig8lNpbiEG7ebPib_qf1AzEHf4Q</recordid><startdate>20201201</startdate><enddate>20201201</enddate><creator>Hegade, Sujit</creator><creator>Jadhav, Yuvraj</creator><creator>Chavan, Sanjay</creator><creator>Mulik, Ganpatrao</creator><creator>Gaikwad, Gautam</creator><general>Springer India</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20201201</creationdate><title>Catalytic assay of Schiff base Co(II), Ni(II), Cu(II) and Zn(II) complexes for N-alkylation of heterocycles with 1,3-dibromopropane</title><author>Hegade, Sujit ; Jadhav, Yuvraj ; Chavan, Sanjay ; Mulik, Ganpatrao ; Gaikwad, Gautam</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-1108d5893225f91c9eaf9e7fa2642fd3cf928a6c450464613b11e792a9efbc7a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Alkylation</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Coupling</topic><topic>Imines</topic><topic>Nickel</topic><topic>Potassium</topic><topic>Ratios</topic><topic>Regular Article</topic><topic>Transition metal compounds</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hegade, Sujit</creatorcontrib><creatorcontrib>Jadhav, Yuvraj</creatorcontrib><creatorcontrib>Chavan, Sanjay</creatorcontrib><creatorcontrib>Mulik, Ganpatrao</creatorcontrib><creatorcontrib>Gaikwad, Gautam</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hegade, Sujit</au><au>Jadhav, Yuvraj</au><au>Chavan, Sanjay</au><au>Mulik, Ganpatrao</au><au>Gaikwad, Gautam</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic assay of Schiff base Co(II), Ni(II), Cu(II) and Zn(II) complexes for N-alkylation of heterocycles with 1,3-dibromopropane</atitle><jtitle>Journal of chemical sciences (Bangalore, India)</jtitle><stitle>J Chem Sci</stitle><date>2020-12-01</date><risdate>2020</risdate><volume>132</volume><issue>1</issue><artnum>92</artnum><issn>0974-3626</issn><eissn>0973-7103</eissn><abstract>N-alkylation of heterocycles with 1,3-dibromopropane using Schiff base Co(II), Ni(II), Cu(II) and Zn(II) transition metal complexes as a catalyst was studied in 1:1 and 2:1 coupling ratios under mild conditions. It was observed that all the complexes worked as efficient catalyst with product yield 78–92% for coupling ratio 1:1 and product yield 63–78% for coupling ratio 2:1. N-alkylation of heterocycles with 1,3-dibromopropane in 1:1 coupling ratio is easier with higher yields as compared with N-alkylation in 2:1 coupling ratio.
Graphic abstract
N-Alkylation of heterocycles with 1,3-dibromopropane</abstract><cop>New Delhi</cop><pub>Springer India</pub><doi>10.1007/s12039-020-01791-4</doi></addata></record> |
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| ispartof | Journal of chemical sciences (Bangalore, India), 2020-12, Vol.132 (1), Article 92 |
| issn | 0974-3626 0973-7103 |
| language | eng |
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| source | EZB-FREE-00999 freely available EZB journals; Alma/SFX Local Collection; Free Full-Text Journals in Chemistry; SpringerLink Journals - AutoHoldings |
| subjects | Alkylation Catalysts Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination compounds Copper Coupling Imines Nickel Potassium Ratios Regular Article Transition metal compounds Zinc |
| title | Catalytic assay of Schiff base Co(II), Ni(II), Cu(II) and Zn(II) complexes for N-alkylation of heterocycles with 1,3-dibromopropane |
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