Metal-ligand cooperativity across two sites of a square planar iron() complex ligated by a tetradentate PNNP ligand

An iron( ii ) complex with a square planar geometry and S = 1 ground state was synthesized using a rigid tetradentate bisphosphine-bisamide [PNNP] 2− ligand. This complex was shown to bind an equivalent of PMe 3 to produce a five-coordinate low spin complex, and to react with two equivalents of bora...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2020-07, Vol.56 (61), p.8611-8614
Hauptverfasser:	Hatzis, Gillian P, Thomas, Christine M
Format:	Artikel
Sprache:	eng
Schlagworte:	Coordination compounds Crystallography Equivalence Iron Ligands Reagents
Online-Zugang:	Volltext
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