Synthesis of Non‐Symmetric Ruthenium(II) POCOP Pincer Complexes and Their Bimetallic Derivatives by π‐Coordination of Arenophile Fragments

A series of neutral 16‐electron square pyramidal ruthenium(II) complexes of the general formula [Ru(POCOP)(X)(CO)] (X = Cl, H) have readily been obtained in good yields from [RuCl2(COD)]n and different POCOP pincer ligands based on the naphthoresorcinate backbone. The molecular structure of two of t...

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Veröffentlicht in:	European journal of inorganic chemistry 2020-07, Vol.2020 (28), p.2700-2708
Hauptverfasser:	Roque‐Ramires, Manuel A., Shen, Longzhu, Le Lagadec, Ronan
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Bimetallic complexes Bimetals Carbon monoxide Coordination Hydride ligands Inorganic chemistry Ligands Molecular structure Non‐symmetric POCOP pincer ligands Planar chirality Ruthenium Ruthenium compounds
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