Structure and Magnetic Properties of Mixed-Ligand Complexes of 3d Metal Hexafluoroacetylacetonates with 3,5- and 3,6-Di-Tert-Butyl-O-Benzoquinones

The reaction of metal hexafluoroacetylacetonates M(hfac) 2 , where M = Fe, Mn, and Co, with 3,6-di- tert -butyl- o -benzoquinone (3,6-Q) in the inert atmosphere of a dry box is found to yield mixed-ligand complexes [ M (hfac) 2 (3,6-Q)]. When the synthesis is performed under ambient conditions or th...

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