Synthesis and Structure of Heteroleptic Tm Bis(Formamidinate) Complexes

By the interaction of TmCl 3 with KFormDipp (FormDipp = N,N′-bis(2,6-diisopropylphenyl)-formamidinate) [Tm(FormDipp) 2 Cl(THF)] (1) and [KTm(FormDipp) 2 Cl 2 ] 2 (2) complexes are obtained. The reaction of 1 with potassium thiophenolate is studied. Its product is found to be [Tm(FormDipp) 2 (SPh)(TH...

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Veröffentlicht in:	Journal of structural chemistry 2020-04, Vol.61 (4), p.550-558
Hauptverfasser:	Bashirov, D. A., Kolybalov, D. S., Sukhikh, T. S., Konchenko, S. N.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic Atomic/Molecular Structure and Spectra Chemistry Chemistry and Materials Science Crystal structure Crystals Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Single crystals Solid phases Solid State Physics Toluene
Online-Zugang:	Volltext
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