Recovery of Precious Metals (Au, Ag, Pt, and Pd) from Urban Mining Through Copper Smelting

With the aim of investigating deportments of precious metals in pyrometallurgical processing of waste electrical and electronic equipment, the distributions of selected precious metals (gold, silver, platinum, and palladium) between copper matte and three different silica-saturated slags (pure FeO x...

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Veröffentlicht in:Metallurgical and materials transactions. B, Process metallurgy and materials processing science Process metallurgy and materials processing science, 2020-08, Vol.51 (4), p.1495-1508
Hauptverfasser: Chen, Min, Avarmaa, Katri, Klemettinen, Lassi, O’Brien, Hugh, Sukhomlinov, Dmitry, Shi, Junjie, Taskinen, Pekka, Jokilaakso, Ari
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container_title Metallurgical and materials transactions. B, Process metallurgy and materials processing science
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creator Chen, Min
Avarmaa, Katri
Klemettinen, Lassi
O’Brien, Hugh
Sukhomlinov, Dmitry
Shi, Junjie
Taskinen, Pekka
Jokilaakso, Ari
description With the aim of investigating deportments of precious metals in pyrometallurgical processing of waste electrical and electronic equipment, the distributions of selected precious metals (gold, silver, platinum, and palladium) between copper matte and three different silica-saturated slags (pure FeO x -SiO 2 , FeO x -SiO 2 -Al 2 O 3 , and FeO x -SiO 2 -Al 2 O 3 -CaO slag) were investigated at 1300 °C in controlled flowing CO-CO 2 -SO 2 -Ar gas atmosphere by a high-temperature isothermal equilibration technique. The phase compositions were analyzed by Electron Probe X-ray Microanalysis and Laser Ablation-High Resolution Inductively Coupled Plasma-Mass Spectrometry. It was shown that the distribution coefficients of gold, platinum, and palladium between matte and slag ( L m/s (Me) = [Me] in matte /(Me) in slag ) were very high and increased with increasing matte grade. The distributions to the matte phase were increased by adding basic oxides alumina and lime into the acidic silicate slags. The experimentally measured distribution coefficients L m/s (Me) followed the order of platinum > palladium > gold > silver. The present experimental results can be used for upgrading thermodynamic databases for the complex recycling processes through nonferrous smelting.
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B, Process metallurgy and materials processing science</jtitle><stitle>Metall Mater Trans B</stitle><date>2020-08-01</date><risdate>2020</risdate><volume>51</volume><issue>4</issue><spage>1495</spage><epage>1508</epage><pages>1495-1508</pages><issn>1073-5615</issn><eissn>1543-1916</eissn><abstract>With the aim of investigating deportments of precious metals in pyrometallurgical processing of waste electrical and electronic equipment, the distributions of selected precious metals (gold, silver, platinum, and palladium) between copper matte and three different silica-saturated slags (pure FeO x -SiO 2 , FeO x -SiO 2 -Al 2 O 3 , and FeO x -SiO 2 -Al 2 O 3 -CaO slag) were investigated at 1300 °C in controlled flowing CO-CO 2 -SO 2 -Ar gas atmosphere by a high-temperature isothermal equilibration technique. The phase compositions were analyzed by Electron Probe X-ray Microanalysis and Laser Ablation-High Resolution Inductively Coupled Plasma-Mass Spectrometry. 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subjects Acidic oxides
Aluminum oxide
Basic oxides
Carbon dioxide
Characterization and Evaluation of Materials
Chemistry and Materials Science
Copper
Copper mattes
Electron probes
Electronic equipment
Electronic waste
Gold
High temperature
Inductively coupled plasma mass spectrometry
Laser ablation
Mass spectrometry
Materials recovery
Materials Science
Metallic Materials
Metallurgy
Nanotechnology
Noble metals
Palladium
Platinum
Silicon dioxide
Silver
Slag
Smelting
Structural Materials
Sulfur dioxide
Surfaces and Interfaces
Thin Films
title Recovery of Precious Metals (Au, Ag, Pt, and Pd) from Urban Mining Through Copper Smelting
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