Synthesis and structure of half-sandwich SmII and YIII cyclopentadienyl halide complexes with the penta(benzyl)cyclopentadienyl ligand

The exchange reactions of equimolar amounts of potassium penta(benzyl)cyclopentadienide Cp Bn 5K (Cp Bn 5 = C 5 (CH 2 Ph) 5 ) and SmI 2 (THF) 2 or YCl 3 afforded the corresponding half-sandwich derivatives [Cp Bn 5Sm(DME)(μ-I)] 2 ( 1 ) and [Cp Bn 5YCl 2 (THF)] 2 [KCl(THF) 2 ] ( 2 ). According to the...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Russian chemical bulletin 2020, Vol.69 (6), p.1085-1091
Hauptverfasser:	Selikhov, A. N., Lyubov, D. M., Mahrova, T. V., Cherkasov, A. V., Fukin, G. K., Trifonov, A. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination compounds Full Articles Inorganic Chemistry Ligands Organic Chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!