Enantiopure Chiral Phosphines Bearing a Sulfinyl Group and their Application in Catalytic Enantiodivergent Synthesis of Polysubstituted Pyrrolines

In this work, a type of enantiopure chiral phosphines bearing a polar S=O sulfinyl group as the chiral unit in the molecule has been developed, which can be prepared in either enantiomeric form from commercially available materials by a three‐step route. The enantiopure chiral phosphines can catalys...

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Veröffentlicht in:	Advanced synthesis & catalysis 2020-07, Vol.362 (13), p.2760-2766
Hauptverfasser:	Li, Hanyuan, Li, Bojuan, Zeng, Jianwei, Jiang, Changzun, He, Zhengjie
Format:	Artikel
Sprache:	eng
Schlagworte:	[4+1] annulation asymmetric catalysis Carbonates Chemical reactions Chemical synthesis Imines organocatalysis phosphine Phosphines pyrroline
Online-Zugang:	Volltext
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