Site-selective synthesis of 1,3-dioxin-3-ones via a gold(i) catalyzed cascade reaction

A novel gold(i)-catalyzed protocol for the synthesis of 4H-1,3-dioxin-3-ones is presented. The protocol exploits a metal induced cascade sequence involving a [3,3]-sigmatropic rearrangement followed by regioselectiveO-annulation reactions. A wide range of oxygen-based heterocyclic scaffolds (21 exam...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2020-07, Vol.56 (56), p.7734-7737
Hauptverfasser:	An, Juzeng, Pedrazzani, Riccardo, Monari, Magda, Marin-Luna, Marta, Silva Lopez, Carlos, Bandini, Marco
Format:	Artikel
Sprache:	eng
Schlagworte:	Cartesian coordinates Cascade chemical reactions Chemical reactions Chemical synthesis Chemistry Chemistry, Multidisciplinary Crystallography Deuterium Dioxins Gold NMR Nuclear magnetic resonance Physical Sciences Regioselectivity Science & Technology
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!