Trapping of Difluorocarbene by Frustrated Lewis Pairs
Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho‐position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to release difluorocarbene at elevated temperatures. Difluorocarbene is reversibly trapped by intramolecu...
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| Veröffentlicht in: | Angewandte Chemie 2020-07, Vol.132 (30), p.12528-12531 |
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| container_title | Angewandte Chemie |
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| creator | Smirnov, Vladimir O. Volodin, Alexander D. Korlyukov, Alexander A. Dilman, Alexander D. |
| description | Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho‐position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to release difluorocarbene at elevated temperatures.
Difluorocarbene is reversibly trapped by intramolecular frustrated Lewis pairs. The reaction proceeds stepwise via interaction of the carbene with the phosphorus atom followed by formation of the carbon–boron bond. |
| doi_str_mv | 10.1002/ange.202001354 |
| format | Article |
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Difluorocarbene is reversibly trapped by intramolecular frustrated Lewis pairs. The reaction proceeds stepwise via interaction of the carbene with the phosphorus atom followed by formation of the carbon–boron bond.</description><subject>Adducts</subject><subject>Chemistry</subject><subject>difluorocarbene</subject><subject>frustrated Lewis pairs</subject><subject>High temperature</subject><subject>intermediates</subject><subject>organofluorine</subject><subject>phosphinoboranes</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNqFkE1LAzEURYMoWKtb1wOup768fMxkWWpbhaIu6jqkmaRMqTNj0qHMvzeloktXDx7n3AuXkHsKEwqAj6bZugkCAlAm-AUZUYE0Z4UoLskIgPO8RK6uyU2MOwCQWKgREetguq5utlnrs6fa7_s2tNaEjWtcthmyRejjIZiDq7KVO9Yxezd1iLfkypt9dHc_d0w-FvP17DlfvS1fZtNVblHS1OdLV5WUl1JKVakKUKCxUlnvBUPOrBeesfQRErkRRkhZIEfFnS24U5KNycM5twvtV-_iQe_aPjSpUicugRKRJWpypmxoYwzO6y7UnyYMmoI-TaNP0-jfaZKgzsKx3rvhH1pPX5fzP_cbGlpl5A</recordid><startdate>20200720</startdate><enddate>20200720</enddate><creator>Smirnov, Vladimir O.</creator><creator>Volodin, Alexander D.</creator><creator>Korlyukov, Alexander A.</creator><creator>Dilman, Alexander D.</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-8048-7223</orcidid><orcidid>https://orcid.org/0000-0003-0844-6050</orcidid></search><sort><creationdate>20200720</creationdate><title>Trapping of Difluorocarbene by Frustrated Lewis Pairs</title><author>Smirnov, Vladimir O. ; Volodin, Alexander D. ; Korlyukov, Alexander A. ; Dilman, Alexander D.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2614-8f8ed81486669d9d0252ac69cff53243cf5f33ac65624a5a566724294ec74e963</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Adducts</topic><topic>Chemistry</topic><topic>difluorocarbene</topic><topic>frustrated Lewis pairs</topic><topic>High temperature</topic><topic>intermediates</topic><topic>organofluorine</topic><topic>phosphinoboranes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Smirnov, Vladimir O.</creatorcontrib><creatorcontrib>Volodin, Alexander D.</creatorcontrib><creatorcontrib>Korlyukov, Alexander A.</creatorcontrib><creatorcontrib>Dilman, Alexander D.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Smirnov, Vladimir O.</au><au>Volodin, Alexander D.</au><au>Korlyukov, Alexander A.</au><au>Dilman, Alexander D.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Trapping of Difluorocarbene by Frustrated Lewis Pairs</atitle><jtitle>Angewandte Chemie</jtitle><date>2020-07-20</date><risdate>2020</risdate><volume>132</volume><issue>30</issue><spage>12528</spage><epage>12531</epage><pages>12528-12531</pages><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>Frustrated Lewis pairs consisting of diphenylphosphino and boryl groups located at the ortho‐position can trap difluorocarbene affording stable zwitterionic adducts. The reaction can be reversed to release difluorocarbene at elevated temperatures.
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| subjects | Adducts Chemistry difluorocarbene frustrated Lewis pairs High temperature intermediates organofluorine phosphinoboranes |
| title | Trapping of Difluorocarbene by Frustrated Lewis Pairs |
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