Direct synthesis of completely unsymmetrical triarylmethanes via Fe(III) salt‐mediated in situ o‐quinone methides process
An efficient and straightforward synthetic approach to completely unsymmetrical triarylmethanes through the situ‐generated o‐quinone methides from readily available starting materials has been successfully developed. In the presence of an Fe(III) salt, three different aromatic rings, including salic...
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| Veröffentlicht in: | Applied organometallic chemistry 2020-08, Vol.34 (8), p.n/a |
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| container_title | Applied organometallic chemistry |
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| creator | Yang, Qi Wu, Run‐Shi Wu, Ke‐Xin Gu, Ying‐Chun Yu, Ya‐Qin Xu, Da‐Zhen |
| description | An efficient and straightforward synthetic approach to completely unsymmetrical triarylmethanes through the situ‐generated o‐quinone methides from readily available starting materials has been successfully developed. In the presence of an Fe(III) salt, three different aromatic rings, including salicylaldehydes, arylboronic acids, and arenes, were incorporated into one molecule in a single step under the base/ligand‐free conditions. The related reactions show high chemoselectivity and afford a variety of completely unsymmetrical triarylmethane products in good to excellent yields.
An efficient and straightforward synthetic approach to completely unsymmetrical triarylmethanes through the in situ‐generated o‐quinone methides from simple readily available starting materials has been successfully developed. |
| doi_str_mv | 10.1002/aoc.5716 |
| format | Article |
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An efficient and straightforward synthetic approach to completely unsymmetrical triarylmethanes through the in situ‐generated o‐quinone methides from simple readily available starting materials has been successfully developed.</description><identifier>ISSN: 0268-2605</identifier><identifier>EISSN: 1099-0739</identifier><identifier>DOI: 10.1002/aoc.5716</identifier><language>eng</language><publisher>Chichester: Wiley Subscription Services, Inc</publisher><subject>Aromatic compounds ; arylboronic acids ; Chemistry ; iron ; Quinones ; salicylaldehydes ; triarylmethanes</subject><ispartof>Applied organometallic chemistry, 2020-08, Vol.34 (8), p.n/a</ispartof><rights>2020 John Wiley & Sons, Ltd.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3306-e55a2873cfb7cacd3abd4e582ca45603f17800d8bbb97e4bac4684faa8ad65183</citedby><cites>FETCH-LOGICAL-c3306-e55a2873cfb7cacd3abd4e582ca45603f17800d8bbb97e4bac4684faa8ad65183</cites><orcidid>0000-0001-5076-7558</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Faoc.5716$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Faoc.5716$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Yang, Qi</creatorcontrib><creatorcontrib>Wu, Run‐Shi</creatorcontrib><creatorcontrib>Wu, Ke‐Xin</creatorcontrib><creatorcontrib>Gu, Ying‐Chun</creatorcontrib><creatorcontrib>Yu, Ya‐Qin</creatorcontrib><creatorcontrib>Xu, Da‐Zhen</creatorcontrib><title>Direct synthesis of completely unsymmetrical triarylmethanes via Fe(III) salt‐mediated in situ o‐quinone methides process</title><title>Applied organometallic chemistry</title><description>An efficient and straightforward synthetic approach to completely unsymmetrical triarylmethanes through the situ‐generated o‐quinone methides from readily available starting materials has been successfully developed. In the presence of an Fe(III) salt, three different aromatic rings, including salicylaldehydes, arylboronic acids, and arenes, were incorporated into one molecule in a single step under the base/ligand‐free conditions. The related reactions show high chemoselectivity and afford a variety of completely unsymmetrical triarylmethane products in good to excellent yields.
An efficient and straightforward synthetic approach to completely unsymmetrical triarylmethanes through the in situ‐generated o‐quinone methides from simple readily available starting materials has been successfully developed.</description><subject>Aromatic compounds</subject><subject>arylboronic acids</subject><subject>Chemistry</subject><subject>iron</subject><subject>Quinones</subject><subject>salicylaldehydes</subject><subject>triarylmethanes</subject><issn>0268-2605</issn><issn>1099-0739</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kEFOwzAQRS0EEqUgcQRLbMoixXYSJ1lWhUIkpG5gbTnORHWVxK3tgLJA4gickZPgUrasvmb0_nzNR-iakjklhN1Jo-ZpRvkJmlBSFBHJ4uIUTQjjecQ4Sc_RhXNbQkjBaTJBH_fagvLYjb3fgNMOmwYr0-1a8NCOeOjd2HXgrVayxUGkHdswb2QPDr9piVcwK8vyFjvZ-u_Prw5qLT3UWPfYaT9gE5b7QfemB3ww6joYd9YocO4SnTWydXD1p1P0unp4WT5Fz-vHcrl4jlQcEx5BmkqWZ7FqqkxJVceyqhNIc6ZkknISNzTLCanzqqqKDJJKqoTnSSNlLmue0jyeopvj3ZC7H8B5sTWD7UOkYAmjnIUYGqjZkVLWOGehETuru_CwoEQcyhWhXHEoN6DREX3XLYz_cmKxXv7yPw1Zf4w</recordid><startdate>202008</startdate><enddate>202008</enddate><creator>Yang, Qi</creator><creator>Wu, Run‐Shi</creator><creator>Wu, Ke‐Xin</creator><creator>Gu, Ying‐Chun</creator><creator>Yu, Ya‐Qin</creator><creator>Xu, Da‐Zhen</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0001-5076-7558</orcidid></search><sort><creationdate>202008</creationdate><title>Direct synthesis of completely unsymmetrical triarylmethanes via Fe(III) salt‐mediated in situ o‐quinone methides process</title><author>Yang, Qi ; Wu, Run‐Shi ; Wu, Ke‐Xin ; Gu, Ying‐Chun ; Yu, Ya‐Qin ; Xu, Da‐Zhen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3306-e55a2873cfb7cacd3abd4e582ca45603f17800d8bbb97e4bac4684faa8ad65183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Aromatic compounds</topic><topic>arylboronic acids</topic><topic>Chemistry</topic><topic>iron</topic><topic>Quinones</topic><topic>salicylaldehydes</topic><topic>triarylmethanes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Qi</creatorcontrib><creatorcontrib>Wu, Run‐Shi</creatorcontrib><creatorcontrib>Wu, Ke‐Xin</creatorcontrib><creatorcontrib>Gu, Ying‐Chun</creatorcontrib><creatorcontrib>Yu, Ya‐Qin</creatorcontrib><creatorcontrib>Xu, Da‐Zhen</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Applied organometallic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Qi</au><au>Wu, Run‐Shi</au><au>Wu, Ke‐Xin</au><au>Gu, Ying‐Chun</au><au>Yu, Ya‐Qin</au><au>Xu, Da‐Zhen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Direct synthesis of completely unsymmetrical triarylmethanes via Fe(III) salt‐mediated in situ o‐quinone methides process</atitle><jtitle>Applied organometallic chemistry</jtitle><date>2020-08</date><risdate>2020</risdate><volume>34</volume><issue>8</issue><epage>n/a</epage><issn>0268-2605</issn><eissn>1099-0739</eissn><abstract>An efficient and straightforward synthetic approach to completely unsymmetrical triarylmethanes through the situ‐generated o‐quinone methides from readily available starting materials has been successfully developed. In the presence of an Fe(III) salt, three different aromatic rings, including salicylaldehydes, arylboronic acids, and arenes, were incorporated into one molecule in a single step under the base/ligand‐free conditions. The related reactions show high chemoselectivity and afford a variety of completely unsymmetrical triarylmethane products in good to excellent yields.
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Aromatic compounds arylboronic acids Chemistry iron Quinones salicylaldehydes triarylmethanes |
| title | Direct synthesis of completely unsymmetrical triarylmethanes via Fe(III) salt‐mediated in situ o‐quinone methides process |
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