Preparation and evaluation of composites containing polypropylene and cotton gin trash
Composites of polypropylene (PP) and cotton gin trash (GT) were prepared to enhance the utilization of agro‐based materials in industrial products. GT was modified by two methods: toluene washed only, and toluene washed and treated with maleic anhydride‐grafted polypropylene (MAPP). These GT samples...
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Veröffentlicht in: | Journal of applied polymer science 2020-10, Vol.137 (38), p.n/a |
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creator | Ge, Changfeng Cheng, Huai N. Miri, Massoud J. Hailstone, Richard K. Francis, Johnathan B. Demyttenaere, Shao M. Alharbi, Najat A. |
description | Composites of polypropylene (PP) and cotton gin trash (GT) were prepared to enhance the utilization of agro‐based materials in industrial products. GT was modified by two methods: toluene washed only, and toluene washed and treated with maleic anhydride‐grafted polypropylene (MAPP). These GT samples were extruded with PP, including MAPP and ethylene/vinyl acetate copolymer in various weight ratios (32 composites total). The PP composites displayed tensile strengths close to that of the neat PP, and exhibited higher values of tensile modulus and lower elongation at break than the neat PP. Based on DSC measurements, the PP composites containing 10 wt% GT exhibited two crystalline regimes, while those containing 20 wt% GT were similar in crystallinity to that of the neat PP. The composites were also characterized using SEM, TGA, water absorption tests, and contact angle measurements. These composites represent a more sustainable alternative to neat, fossil fuel‐based PP. |
doi_str_mv | 10.1002/app.49151 |
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GT was modified by two methods: toluene washed only, and toluene washed and treated with maleic anhydride‐grafted polypropylene (MAPP). These GT samples were extruded with PP, including MAPP and ethylene/vinyl acetate copolymer in various weight ratios (32 composites total). The PP composites displayed tensile strengths close to that of the neat PP, and exhibited higher values of tensile modulus and lower elongation at break than the neat PP. Based on DSC measurements, the PP composites containing 10 wt% GT exhibited two crystalline regimes, while those containing 20 wt% GT were similar in crystallinity to that of the neat PP. The composites were also characterized using SEM, TGA, water absorption tests, and contact angle measurements. 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GT was modified by two methods: toluene washed only, and toluene washed and treated with maleic anhydride‐grafted polypropylene (MAPP). These GT samples were extruded with PP, including MAPP and ethylene/vinyl acetate copolymer in various weight ratios (32 composites total). The PP composites displayed tensile strengths close to that of the neat PP, and exhibited higher values of tensile modulus and lower elongation at break than the neat PP. Based on DSC measurements, the PP composites containing 10 wt% GT exhibited two crystalline regimes, while those containing 20 wt% GT were similar in crystallinity to that of the neat PP. The composites were also characterized using SEM, TGA, water absorption tests, and contact angle measurements. These composites represent a more sustainable alternative to neat, fossil fuel‐based PP.</description><subject>biomaterials</subject><subject>By products</subject><subject>Contact angle</subject><subject>Copolymers</subject><subject>Cotton ginning</subject><subject>Cotton gins</subject><subject>Crystal structure</subject><subject>Crystallinity</subject><subject>Elongation</subject><subject>Ethylene vinyl acetates</subject><subject>Extrusion</subject><subject>Fossil fuels</subject><subject>Maleic anhydride</subject><subject>Materials science</subject><subject>mechanical properties</subject><subject>Modulus of elasticity</subject><subject>Polymer matrix composites</subject><subject>Polymers</subject><subject>polyolefins</subject><subject>Polypropylene</subject><subject>synthesis and processing techniques</subject><subject>thermal properties</subject><subject>Toluene</subject><subject>Water absorption</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kD9PwzAQxS0EEqUw8A0iMTGE2o7j1GNV8U-qRAdgtVznUlyltrFdUL49pmFlujvd7909PYSuCb4jGNOZ8v6OCVKTEzQhWDQl43R-iiZ5R8q5EPU5uohxhzEhNeYT9L4O4FVQyThbKNsW8KX6wzi6rtBu7100CWJubVLGGrstvOsHH5wferBwVGmXUlZsjS1SUPHjEp11qo9w9Ven6O3h_nX5VK5eHp-Xi1Wpq4plQ21b0Qq6uqpBtVULXBFFYcMI55QKRQVtWtF0mmE9x7ppSK1V220YUADa8GqKbsa72c7nAWKSO3cINr-UlFHMOOECZ-p2pHRwMQbopA9mr8IgCZa_sckcmzzGltnZyH6bHob_QblYr0fFD9VfcCY</recordid><startdate>20201010</startdate><enddate>20201010</enddate><creator>Ge, Changfeng</creator><creator>Cheng, Huai N.</creator><creator>Miri, Massoud J.</creator><creator>Hailstone, Richard K.</creator><creator>Francis, Johnathan B.</creator><creator>Demyttenaere, Shao M.</creator><creator>Alharbi, Najat A.</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-2401-8910</orcidid></search><sort><creationdate>20201010</creationdate><title>Preparation and evaluation of composites containing polypropylene and cotton gin trash</title><author>Ge, Changfeng ; Cheng, Huai N. ; Miri, Massoud J. ; Hailstone, Richard K. ; Francis, Johnathan B. ; Demyttenaere, Shao M. ; Alharbi, Najat A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3341-8dd323ef535ead3de6a1a2eb4166229a2927d97fc40c80c7715cadfb4e2ee2763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>biomaterials</topic><topic>By products</topic><topic>Contact angle</topic><topic>Copolymers</topic><topic>Cotton ginning</topic><topic>Cotton gins</topic><topic>Crystal structure</topic><topic>Crystallinity</topic><topic>Elongation</topic><topic>Ethylene vinyl acetates</topic><topic>Extrusion</topic><topic>Fossil fuels</topic><topic>Maleic anhydride</topic><topic>Materials science</topic><topic>mechanical properties</topic><topic>Modulus of elasticity</topic><topic>Polymer matrix composites</topic><topic>Polymers</topic><topic>polyolefins</topic><topic>Polypropylene</topic><topic>synthesis and processing techniques</topic><topic>thermal properties</topic><topic>Toluene</topic><topic>Water absorption</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ge, Changfeng</creatorcontrib><creatorcontrib>Cheng, Huai N.</creatorcontrib><creatorcontrib>Miri, Massoud J.</creatorcontrib><creatorcontrib>Hailstone, Richard K.</creatorcontrib><creatorcontrib>Francis, Johnathan B.</creatorcontrib><creatorcontrib>Demyttenaere, Shao M.</creatorcontrib><creatorcontrib>Alharbi, Najat A.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ge, Changfeng</au><au>Cheng, Huai N.</au><au>Miri, Massoud J.</au><au>Hailstone, Richard K.</au><au>Francis, Johnathan B.</au><au>Demyttenaere, Shao M.</au><au>Alharbi, Najat A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and evaluation of composites containing polypropylene and cotton gin trash</atitle><jtitle>Journal of applied polymer science</jtitle><date>2020-10-10</date><risdate>2020</risdate><volume>137</volume><issue>38</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>Composites of polypropylene (PP) and cotton gin trash (GT) were prepared to enhance the utilization of agro‐based materials in industrial products. GT was modified by two methods: toluene washed only, and toluene washed and treated with maleic anhydride‐grafted polypropylene (MAPP). These GT samples were extruded with PP, including MAPP and ethylene/vinyl acetate copolymer in various weight ratios (32 composites total). The PP composites displayed tensile strengths close to that of the neat PP, and exhibited higher values of tensile modulus and lower elongation at break than the neat PP. Based on DSC measurements, the PP composites containing 10 wt% GT exhibited two crystalline regimes, while those containing 20 wt% GT were similar in crystallinity to that of the neat PP. The composites were also characterized using SEM, TGA, water absorption tests, and contact angle measurements. These composites represent a more sustainable alternative to neat, fossil fuel‐based PP.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.49151</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-2401-8910</orcidid></addata></record> |
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subjects | biomaterials By products Contact angle Copolymers Cotton ginning Cotton gins Crystal structure Crystallinity Elongation Ethylene vinyl acetates Extrusion Fossil fuels Maleic anhydride Materials science mechanical properties Modulus of elasticity Polymer matrix composites Polymers polyolefins Polypropylene synthesis and processing techniques thermal properties Toluene Water absorption |
title | Preparation and evaluation of composites containing polypropylene and cotton gin trash |
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