“Greener” Coupling of Poly(methyl methacrylate) and Poly(methyl acrylate) Chains using Activators Generated by Electron Transfer and Radical Traps

Monobrominated versions of poly(methyl methacrylate) (PMMABr) and poly(methyl acrylate) (PMABr) are prepared by atom transfer radical polymerization and subjected to a variety of chain end‐coupling reactions, with the goal of achieving high extents of coupling with minimal metal content. By using at...

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Veröffentlicht in:	Macromolecular chemistry and physics 2020-07, Vol.221 (13), p.n/a
Hauptverfasser:	Xia, Katherine, Rubaie, Alia, Johnson, Brendan, Tillman, Eric S.
Format:	Artikel
Sprache:	eng
Schlagworte:	Acrylics Ascorbic acid atom transfer radical coupling atom transfer radical polymerization Chemical reactions Copper bromide Copper compounds Coupling Electron transfer poly(methyl acrylate) poly(methyl methyacrylate) Polymethyl acrylates Polymethyl methacrylate Reducing agents
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