Low-Temperature Nitrocarburizing of Austenitic Stainless Steel for Combat Corrosion in H2S Environments

The time-dependent experiment was performed to investigate the corrosion behavior of low-temperature liquid nitrocarburized (LNC) 304 austenitic stainless steel in wet H 2 S environments. Characteristics of H 2 S corrosion products, as well as localized corrosion behavior, were investigated using X-...

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Veröffentlicht in:Metallurgical and materials transactions. A, Physical metallurgy and materials science Physical metallurgy and materials science, 2020-08, Vol.51 (8), p.4242-4256
Hauptverfasser: Li, Longyi, Wang, Jun, Tang, Zhenghua, Yan, Jing, Fan, Hongyuan, Zeng, Bo, Li, Xiaoying, Dong, Hanshan
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container_title Metallurgical and materials transactions. A, Physical metallurgy and materials science
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creator Li, Longyi
Wang, Jun
Tang, Zhenghua
Yan, Jing
Fan, Hongyuan
Zeng, Bo
Li, Xiaoying
Dong, Hanshan
description The time-dependent experiment was performed to investigate the corrosion behavior of low-temperature liquid nitrocarburized (LNC) 304 austenitic stainless steel in wet H 2 S environments. Characteristics of H 2 S corrosion products, as well as localized corrosion behavior, were investigated using X-ray diffraction (XRD), scanning electron microscopy, X-ray photoelectron spectroscopy (XPS), and optical profilometry. The results revealed that the untreated steels, of which the H 2 S corrosion product layer on the untreated surface thickened but displayed a layered defect structure as the corrosion proceeded, had a higher weight loss than the LNC. Energy-dispersive spectroscopy (EDS) served to reveal the relationship between corrosion behavior and the content of sulfur, chromium, and other elements, and the valences of these elements were illustrated by XPS. The surface morphology after removing corrosion products showed that the presence of nitrocarburized S phase could prevent general corrosion and inhibit pit propagation.
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Characteristics of H 2 S corrosion products, as well as localized corrosion behavior, were investigated using X-ray diffraction (XRD), scanning electron microscopy, X-ray photoelectron spectroscopy (XPS), and optical profilometry. The results revealed that the untreated steels, of which the H 2 S corrosion product layer on the untreated surface thickened but displayed a layered defect structure as the corrosion proceeded, had a higher weight loss than the LNC. Energy-dispersive spectroscopy (EDS) served to reveal the relationship between corrosion behavior and the content of sulfur, chromium, and other elements, and the valences of these elements were illustrated by XPS. 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A, Physical metallurgy and materials science</title><addtitle>Metall Mater Trans A</addtitle><addtitle>METALL MATER TRANS A</addtitle><description>The time-dependent experiment was performed to investigate the corrosion behavior of low-temperature liquid nitrocarburized (LNC) 304 austenitic stainless steel in wet H 2 S environments. Characteristics of H 2 S corrosion products, as well as localized corrosion behavior, were investigated using X-ray diffraction (XRD), scanning electron microscopy, X-ray photoelectron spectroscopy (XPS), and optical profilometry. The results revealed that the untreated steels, of which the H 2 S corrosion product layer on the untreated surface thickened but displayed a layered defect structure as the corrosion proceeded, had a higher weight loss than the LNC. Energy-dispersive spectroscopy (EDS) served to reveal the relationship between corrosion behavior and the content of sulfur, chromium, and other elements, and the valences of these elements were illustrated by XPS. 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A, Physical metallurgy and materials science</jtitle><stitle>Metall Mater Trans A</stitle><stitle>METALL MATER TRANS A</stitle><date>2020-08-01</date><risdate>2020</risdate><volume>51</volume><issue>8</issue><spage>4242</spage><epage>4256</epage><pages>4242-4256</pages><issn>1073-5623</issn><eissn>1543-1940</eissn><abstract>The time-dependent experiment was performed to investigate the corrosion behavior of low-temperature liquid nitrocarburized (LNC) 304 austenitic stainless steel in wet H 2 S environments. Characteristics of H 2 S corrosion products, as well as localized corrosion behavior, were investigated using X-ray diffraction (XRD), scanning electron microscopy, X-ray photoelectron spectroscopy (XPS), and optical profilometry. The results revealed that the untreated steels, of which the H 2 S corrosion product layer on the untreated surface thickened but displayed a layered defect structure as the corrosion proceeded, had a higher weight loss than the LNC. Energy-dispersive spectroscopy (EDS) served to reveal the relationship between corrosion behavior and the content of sulfur, chromium, and other elements, and the valences of these elements were illustrated by XPS. The surface morphology after removing corrosion products showed that the presence of nitrocarburized S phase could prevent general corrosion and inhibit pit propagation.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11661-020-05802-4</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-1244-0364</orcidid></addata></record>
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subjects Austenitic stainless steels
Carbonitriding
Characterization and Evaluation of Materials
Chemistry and Materials Science
Chromium
Corrosion
Corrosion environments
Corrosion products
Hydrogen sulfide
Localized corrosion
Low temperature
Materials Science
Materials Science, Multidisciplinary
Metallic Materials
Metallurgy & Metallurgical Engineering
Morphology
Nanotechnology
Photoelectrons
Science & Technology
Spectrum analysis
Stainless steel
Structural Materials
Surfaces and Interfaces
Technology
Thin Films
Time dependence
Uniform attack (corrosion)
Weight loss
X ray photoelectron spectroscopy
title Low-Temperature Nitrocarburizing of Austenitic Stainless Steel for Combat Corrosion in H2S Environments
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