A Liquid Arylazopyrazole Derivative as Molecular Solar Thermal Fuel with Long-term Thermal Stability

A liquid arylazopyrazole derivative is newly synthesized as molecular solar thermal fuel. It shows efficient trans-to-cis photoisomerization in the neat liquid state, with the cis-isomer having a significantly longer thermal half-life (t1/2 = 3,069 h, at 25 °C). It overcomes the limited thermal stab...

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Veröffentlicht in:	Chemistry letters 2020-06, Vol.49 (6), p.736-740
Hauptverfasser:	Morikawa, Masa-aki, Yang, Hanyu, Ishiba, Keita, Masutani, Kouta, Hui, Joseph K.-H., Kimizuka, Nobuo
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical synthesis Coordination Asymmetry Flux density Fuels Gravimetry Heat storage Solar heating Thermal stability
Online-Zugang:	Volltext
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