Fabrication, structural, optical, electrical, and humidity sensing characteristics of hierarchical NiO nanosheet/nanoball-flower-like structure films

In this work, nickel oxide (NiO) nanosheet/nanoball-flower-like structures (NSBS) were directly grown on a NiO seed-coated glass substrate using a low-temperature immersion method at 75 ºC. The thickness, or density, of the nanoball-flower-like structures differed based on the following samples orde...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2020-07, Vol.31 (14), p.11673-11687
Hauptverfasser: Parimon, N., Mamat, M. H., Shameem Banu, I. B., Vasimalai, N., Ahmad, M. K., Suriani, A. B., Mohamed, A., Rusop, M.
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container_issue 14
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container_title Journal of materials science. Materials in electronics
container_volume 31
creator Parimon, N.
Mamat, M. H.
Shameem Banu, I. B.
Vasimalai, N.
Ahmad, M. K.
Suriani, A. B.
Mohamed, A.
Rusop, M.
description In this work, nickel oxide (NiO) nanosheet/nanoball-flower-like structures (NSBS) were directly grown on a NiO seed-coated glass substrate using a low-temperature immersion method at 75 ºC. The thickness, or density, of the nanoball-flower-like structures differed based on the following samples order: NSBS1 
doi_str_mv 10.1007/s10854-020-03719-7
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H. ; Shameem Banu, I. B. ; Vasimalai, N. ; Ahmad, M. K. ; Suriani, A. B. ; Mohamed, A. ; Rusop, M.</creator><creatorcontrib>Parimon, N. ; Mamat, M. H. ; Shameem Banu, I. B. ; Vasimalai, N. ; Ahmad, M. K. ; Suriani, A. B. ; Mohamed, A. ; Rusop, M.</creatorcontrib><description>In this work, nickel oxide (NiO) nanosheet/nanoball-flower-like structures (NSBS) were directly grown on a NiO seed-coated glass substrate using a low-temperature immersion method at 75 ºC. The thickness, or density, of the nanoball-flower-like structures differed based on the following samples order: NSBS1 &lt; NSBS2 &lt; NSBS3. The synthesised NSBS films were investigated in terms of structural, optical, electrical, and humidity sensing characteristics. The X-ray diffraction (XRD) analysis revealed that the NSBS samples corresponded to the face-centred cubic NiO with five diffraction patterns indexed to the (111), (200), (220), (311), and (222) planes. The interplanar spacing, lattice parameter, unit cell volume, strain, and stress were also determined from the XRD results. The transmittance spectra showed that the NSBS samples had a transparency of more than 30% in the visible region. The optical bandgap values for the NSBS samples were estimated in the range between 3.72 and 3.75 eV, which is directly related to their lattice expansion and defect characteristics. The current–voltage and Hall effect measurement results revealed that the NSBS2 displayed good electrical properties with the resistance, hole concentration, and hole mobility values of 7.84 MΩ, 8.71 × 10 15 hole/cm −3 , and 1.88 × 10 2  cm 2 /V s, respectively. The NSBS samples performed well for humidity sensing with the highest sensitivity value of 169 being obtained for the NSBS2. 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Materials in electronics</jtitle><stitle>J Mater Sci: Mater Electron</stitle><date>2020-07-01</date><risdate>2020</risdate><volume>31</volume><issue>14</issue><spage>11673</spage><epage>11687</epage><pages>11673-11687</pages><issn>0957-4522</issn><eissn>1573-482X</eissn><abstract>In this work, nickel oxide (NiO) nanosheet/nanoball-flower-like structures (NSBS) were directly grown on a NiO seed-coated glass substrate using a low-temperature immersion method at 75 ºC. The thickness, or density, of the nanoball-flower-like structures differed based on the following samples order: NSBS1 &lt; NSBS2 &lt; NSBS3. The synthesised NSBS films were investigated in terms of structural, optical, electrical, and humidity sensing characteristics. The X-ray diffraction (XRD) analysis revealed that the NSBS samples corresponded to the face-centred cubic NiO with five diffraction patterns indexed to the (111), (200), (220), (311), and (222) planes. The interplanar spacing, lattice parameter, unit cell volume, strain, and stress were also determined from the XRD results. The transmittance spectra showed that the NSBS samples had a transparency of more than 30% in the visible region. The optical bandgap values for the NSBS samples were estimated in the range between 3.72 and 3.75 eV, which is directly related to their lattice expansion and defect characteristics. The current–voltage and Hall effect measurement results revealed that the NSBS2 displayed good electrical properties with the resistance, hole concentration, and hole mobility values of 7.84 MΩ, 8.71 × 10 15 hole/cm −3 , and 1.88 × 10 2  cm 2 /V s, respectively. The NSBS samples performed well for humidity sensing with the highest sensitivity value of 169 being obtained for the NSBS2. These humidity sensing results correlated well with their structural, optical, and electrical characteristics.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10854-020-03719-7</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0002-6640-2366</orcidid></addata></record>
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subjects Characterization and Evaluation of Materials
Chemistry and Materials Science
Detection
Diffraction patterns
Electrical properties
Glass substrates
Hall effect
Hole mobility
Humidity
Low temperature
Materials Science
Nanosheets
Nickel oxides
Optical and Electronic Materials
Structural hierarchy
Submerging
Unit cell
X-ray diffraction
title Fabrication, structural, optical, electrical, and humidity sensing characteristics of hierarchical NiO nanosheet/nanoball-flower-like structure films
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