A dual-function all-inorganic intercluster salt comprising the polycation ε-[Al 13 O 4 (OH) 24 (H 2 O) 12 ] 7+ and polyanion α-[PMo 10 V 2 O 40 ] 5− for detoxifying sulfur mustard and soman

ε-[Al 13 O 4 (OH) 24 (H 2 O) 12 ] 7+ , which shares similarity with the phosphotriesterase active site Zn II –OH–Zn II , was specially chosen to interact with the cluster α-PMo 10 V 2 O 40 5− to form a new three-dimensional intercluster, which crystallized in the monoclinic space group P 2 1 / m wit...

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Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2020-06, Vol.49 (24), p.8122-8135
Hauptverfasser:	Yu, Jialin, Gao, Qi, Zhang, Lijuan, Zhou, Yunshan, Zhong, Yuxu, Yin, Jianbo, Zhou, Yuanyuan, Tao, Fangsheng, Wang, Yong'an
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalytic oxidation Chemical warfare Crystallization Crystallography Decontamination Guinea pigs Hydrolysates Mustard gas Oxidation Pigskins Polyelectrolytes Reaction kinetics Sulfur
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