Compatibilization of immiscible blends of polypropylene and isosorbide containing copolyester with silica nanoparticles
In the present study, compatibilization of immiscible blends of polymers was investigated based on the Pickering emulsion concept with various mixing procedures. Silica nanoparticles were incorporated into poly (1,4‐cyclohexanedimethylene isosorbide terephthalate) (PEICT)/isotactic polypropylene (iP...
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| Veröffentlicht in: | Polymer engineering and science 2020-06, Vol.60 (6), p.1365-1376 |
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| container_title | Polymer engineering and science |
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| creator | Kim, Ha Neul Park, Chang Kyu Kim, Ick Soo Kim, Seong Hun |
| description | In the present study, compatibilization of immiscible blends of polymers was investigated based on the Pickering emulsion concept with various mixing procedures. Silica nanoparticles were incorporated into poly (1,4‐cyclohexanedimethylene isosorbide terephthalate) (PEICT)/isotactic polypropylene (iPP) blends. Localization of nanoparticles was effectively modified by varying mixing procedures. Relocation of hydrophilic silica occurred in a secondary mixing procedure with the PEICT, which has relatively high affinity when primarily mixed with iPP. The final location of the silica nanoparticles was confirmed by SEM images. SEM and an optical microscope were used to follow morphological change. By simply changing the mixing procedure, the hydrophilic silica nanoparticles were able to perform the role of a morphology modifier successfully without modifying the surface characteristics. The mechanical properties and crystallization behavior were also compared depending on the surface characteristics of the silica nanoparticles and their final localization. |
| doi_str_mv | 10.1002/pen.25387 |
| format | Article |
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Silica nanoparticles were incorporated into poly (1,4‐cyclohexanedimethylene isosorbide terephthalate) (PEICT)/isotactic polypropylene (iPP) blends. Localization of nanoparticles was effectively modified by varying mixing procedures. Relocation of hydrophilic silica occurred in a secondary mixing procedure with the PEICT, which has relatively high affinity when primarily mixed with iPP. The final location of the silica nanoparticles was confirmed by SEM images. SEM and an optical microscope were used to follow morphological change. By simply changing the mixing procedure, the hydrophilic silica nanoparticles were able to perform the role of a morphology modifier successfully without modifying the surface characteristics. The mechanical properties and crystallization behavior were also compared depending on the surface characteristics of the silica nanoparticles and their final localization.</description><identifier>ISSN: 0032-3888</identifier><identifier>EISSN: 1548-2634</identifier><identifier>DOI: 10.1002/pen.25387</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>blends ; Crystallization ; Hydrophilicity ; Isosorbide dinitrate ; Localization ; Mechanical properties ; Miscibility ; Morphology ; Nanoparticles ; Optical microscopes ; poly(propylene) (PP) ; polyesters ; Polymer blends ; Polyols ; Polypropylene ; Relocation ; silicas ; Silicon dioxide ; Surface properties ; Terephthalate</subject><ispartof>Polymer engineering and science, 2020-06, Vol.60 (6), p.1365-1376</ispartof><rights>2020 Society of Plastics Engineers</rights><rights>COPYRIGHT 2020 Society of Plastics Engineers, Inc.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5107-6a66cab7320d230db24fc3837421a72f2b348887923fa66d4ab48237334d17df3</citedby><cites>FETCH-LOGICAL-c5107-6a66cab7320d230db24fc3837421a72f2b348887923fa66d4ab48237334d17df3</cites><orcidid>0000-0003-0401-6643</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpen.25387$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpen.25387$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Kim, Ha Neul</creatorcontrib><creatorcontrib>Park, Chang Kyu</creatorcontrib><creatorcontrib>Kim, Ick Soo</creatorcontrib><creatorcontrib>Kim, Seong Hun</creatorcontrib><title>Compatibilization of immiscible blends of polypropylene and isosorbide containing copolyester with silica nanoparticles</title><title>Polymer engineering and science</title><description>In the present study, compatibilization of immiscible blends of polymers was investigated based on the Pickering emulsion concept with various mixing procedures. Silica nanoparticles were incorporated into poly (1,4‐cyclohexanedimethylene isosorbide terephthalate) (PEICT)/isotactic polypropylene (iPP) blends. Localization of nanoparticles was effectively modified by varying mixing procedures. Relocation of hydrophilic silica occurred in a secondary mixing procedure with the PEICT, which has relatively high affinity when primarily mixed with iPP. The final location of the silica nanoparticles was confirmed by SEM images. SEM and an optical microscope were used to follow morphological change. By simply changing the mixing procedure, the hydrophilic silica nanoparticles were able to perform the role of a morphology modifier successfully without modifying the surface characteristics. The mechanical properties and crystallization behavior were also compared depending on the surface characteristics of the silica nanoparticles and their final localization.</description><subject>blends</subject><subject>Crystallization</subject><subject>Hydrophilicity</subject><subject>Isosorbide dinitrate</subject><subject>Localization</subject><subject>Mechanical properties</subject><subject>Miscibility</subject><subject>Morphology</subject><subject>Nanoparticles</subject><subject>Optical microscopes</subject><subject>poly(propylene) (PP)</subject><subject>polyesters</subject><subject>Polymer blends</subject><subject>Polyols</subject><subject>Polypropylene</subject><subject>Relocation</subject><subject>silicas</subject><subject>Silicon dioxide</subject><subject>Surface properties</subject><subject>Terephthalate</subject><issn>0032-3888</issn><issn>1548-2634</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>N95</sourceid><recordid>eNp1ktuKFDEQhoMoOK5e-AYBrwR7Nqfu9Fwuw6oLi4qH65DOoTdLd9ImPYzj01u9I6wDIyGpUHz_n0pRCL2mZE0JYZeTi2tW81Y-QStai7ZiDRdP0YoQziretu1z9KKUewIsrzcrtN-mcdJz6MIQfkNMESePwziGYkI3OAw72rIkpzQcppymA2Qc1tHiUFJJuQvWYZPirEMMsYfrQroyu4z3Yb7DBbyNxlHHNOk8BzO48hI983oo7tXfeIF-vL_-vv1Y3X7-cLO9uq1MTYmsGt00RneSM2IZJ7ZjwhvecikY1ZJ51nEBn5Ibxj2gVuhOtIxLzoWl0np-gd4cfaHynzsoSt2nXY7wpGKCig2p6UY-Ur0enArRpzlrs_RAXTUMoJqRFqjqDNVDN7IeUnQ-QPqEX5_hYVk3BnNW8PZEsDTV_Zp7vStF3Xz7esq--4ftdiVEV-Aoob-by1FyztrkVEp2Xk05jDofFCVqmRwFk6MeJgfYyyO7h_oO_wfVl-tPR8UfS8HEAA</recordid><startdate>202006</startdate><enddate>202006</enddate><creator>Kim, Ha Neul</creator><creator>Park, Chang Kyu</creator><creator>Kim, Ick Soo</creator><creator>Kim, Seong Hun</creator><general>John Wiley & Sons, Inc</general><general>Society of Plastics Engineers, Inc</general><general>Blackwell Publishing Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>N95</scope><scope>XI7</scope><scope>ISR</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-0401-6643</orcidid></search><sort><creationdate>202006</creationdate><title>Compatibilization of immiscible blends of polypropylene and isosorbide containing copolyester with silica nanoparticles</title><author>Kim, Ha Neul ; Park, Chang Kyu ; Kim, Ick Soo ; Kim, Seong Hun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5107-6a66cab7320d230db24fc3837421a72f2b348887923fa66d4ab48237334d17df3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>blends</topic><topic>Crystallization</topic><topic>Hydrophilicity</topic><topic>Isosorbide dinitrate</topic><topic>Localization</topic><topic>Mechanical properties</topic><topic>Miscibility</topic><topic>Morphology</topic><topic>Nanoparticles</topic><topic>Optical microscopes</topic><topic>poly(propylene) (PP)</topic><topic>polyesters</topic><topic>Polymer blends</topic><topic>Polyols</topic><topic>Polypropylene</topic><topic>Relocation</topic><topic>silicas</topic><topic>Silicon dioxide</topic><topic>Surface properties</topic><topic>Terephthalate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Ha Neul</creatorcontrib><creatorcontrib>Park, Chang Kyu</creatorcontrib><creatorcontrib>Kim, Ick Soo</creatorcontrib><creatorcontrib>Kim, Seong Hun</creatorcontrib><collection>CrossRef</collection><collection>Gale Business: Insights</collection><collection>Business Insights: Essentials</collection><collection>Gale In Context: Science</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer engineering and science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Ha Neul</au><au>Park, Chang Kyu</au><au>Kim, Ick Soo</au><au>Kim, Seong Hun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Compatibilization of immiscible blends of polypropylene and isosorbide containing copolyester with silica nanoparticles</atitle><jtitle>Polymer engineering and science</jtitle><date>2020-06</date><risdate>2020</risdate><volume>60</volume><issue>6</issue><spage>1365</spage><epage>1376</epage><pages>1365-1376</pages><issn>0032-3888</issn><eissn>1548-2634</eissn><abstract>In the present study, compatibilization of immiscible blends of polymers was investigated based on the Pickering emulsion concept with various mixing procedures. Silica nanoparticles were incorporated into poly (1,4‐cyclohexanedimethylene isosorbide terephthalate) (PEICT)/isotactic polypropylene (iPP) blends. Localization of nanoparticles was effectively modified by varying mixing procedures. Relocation of hydrophilic silica occurred in a secondary mixing procedure with the PEICT, which has relatively high affinity when primarily mixed with iPP. The final location of the silica nanoparticles was confirmed by SEM images. SEM and an optical microscope were used to follow morphological change. By simply changing the mixing procedure, the hydrophilic silica nanoparticles were able to perform the role of a morphology modifier successfully without modifying the surface characteristics. The mechanical properties and crystallization behavior were also compared depending on the surface characteristics of the silica nanoparticles and their final localization.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/pen.25387</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-0401-6643</orcidid></addata></record> |
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| identifier | ISSN: 0032-3888 |
| ispartof | Polymer engineering and science, 2020-06, Vol.60 (6), p.1365-1376 |
| issn | 0032-3888 1548-2634 |
| language | eng |
| recordid | cdi_proquest_journals_2414905197 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | blends Crystallization Hydrophilicity Isosorbide dinitrate Localization Mechanical properties Miscibility Morphology Nanoparticles Optical microscopes poly(propylene) (PP) polyesters Polymer blends Polyols Polypropylene Relocation silicas Silicon dioxide Surface properties Terephthalate |
| title | Compatibilization of immiscible blends of polypropylene and isosorbide containing copolyester with silica nanoparticles |
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