Post-harvest treatment of carbendazim in Chinese chives using TiO2 nanofiber photocatalysis with different anatase/rutile ratios
Carbendazim residues in Chinese chives were treated by photocatalysis using the following three electrospun TiO 2 nanofibers: TTiP/PVP, TTiP/PVAc, and TBOT/PVP. The as-spun fibers were calcined at 500–650 °C to achieve anatase/rutile (A/R) ratios of 100:0, 80:20, 70:30, 50:50, and 30:70. The obtaine...
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creator | Ngamsakpasert, Chanitsara Suriyawong, Achariya Supothina, Sitthisuntorn Chuaybamroong, Paradee |
description | Carbendazim residues in Chinese chives were treated by photocatalysis using the following three electrospun TiO
2
nanofibers: TTiP/PVP, TTiP/PVAc, and TBOT/PVP. The as-spun fibers were calcined at 500–650 °C to achieve anatase/rutile (A/R) ratios of 100:0, 80:20, 70:30, 50:50, and 30:70. The obtained anatase crystallite sizes were in the range of 13.9–28.1 nm, while the rutile crystallite sizes were 21.1–30.6 nm. The experiments were conducted in glass reactors. These were filled with water and each type of the fiber and irradiated from above by black light lamps for 5 min. Then, 50 g of the samples of Chinese chives was immersed for 5, 15, 30, and 60 min. Carbendazim in the chives was extracted using the matrix solid-phase dispersion (MSPD) method and analyzed using UHPLC. The ˙OH formation from each fiber type was investigated using the coumarin fluorescent probe method.
An A/R ratio of 70:30 yielded the highest ˙OH formation, as well as the greatest carbendazim degradation. Rutile plays a crucial role in inhibition of electron-hole recombination and ˙O
2
−
stabilization. The degradation efficiencies for carbendazim from TTiP/PVP, TTiP/PVAc, and TBOT/PVP fibers after a 60-min treatment were 98.6–99.5%, 91.2–97.1%, and 99.5–99.9%, respectively. The TTiP/PVP and TBOT/PVP fibers produced levels of retained carbendazim in the chives that were within EU maximum residue limits of 0.1 mg/kg. The thermal stability of the TTiP/PVAc fiber limited ˙OH formation and carbendazim degradation. |
doi_str_mv | 10.1007/s11051-020-04891-x |
format | Article |
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2
nanofibers: TTiP/PVP, TTiP/PVAc, and TBOT/PVP. The as-spun fibers were calcined at 500–650 °C to achieve anatase/rutile (A/R) ratios of 100:0, 80:20, 70:30, 50:50, and 30:70. The obtained anatase crystallite sizes were in the range of 13.9–28.1 nm, while the rutile crystallite sizes were 21.1–30.6 nm. The experiments were conducted in glass reactors. These were filled with water and each type of the fiber and irradiated from above by black light lamps for 5 min. Then, 50 g of the samples of Chinese chives was immersed for 5, 15, 30, and 60 min. Carbendazim in the chives was extracted using the matrix solid-phase dispersion (MSPD) method and analyzed using UHPLC. The ˙OH formation from each fiber type was investigated using the coumarin fluorescent probe method.
An A/R ratio of 70:30 yielded the highest ˙OH formation, as well as the greatest carbendazim degradation. Rutile plays a crucial role in inhibition of electron-hole recombination and ˙O
2
−
stabilization. The degradation efficiencies for carbendazim from TTiP/PVP, TTiP/PVAc, and TBOT/PVP fibers after a 60-min treatment were 98.6–99.5%, 91.2–97.1%, and 99.5–99.9%, respectively. The TTiP/PVP and TBOT/PVP fibers produced levels of retained carbendazim in the chives that were within EU maximum residue limits of 0.1 mg/kg. The thermal stability of the TTiP/PVAc fiber limited ˙OH formation and carbendazim degradation.</description><identifier>ISSN: 1388-0764</identifier><identifier>EISSN: 1572-896X</identifier><identifier>DOI: 10.1007/s11051-020-04891-x</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Anatase ; Black light ; Carbendazim ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Coumarin ; Crystallites ; Crystals ; Degradation ; Fibers ; Fluorescent indicators ; Fungicides ; Holes (electron deficiencies) ; Inorganic Chemistry ; Lasers ; Materials Science ; Nanofibers ; Nanoparticles ; Nanotechnology ; Optical Devices ; Optics ; Photocatalysis ; Photonics ; Physical Chemistry ; Polyvinyl acetates ; Recombination ; Research Paper ; Residues ; Rutile ; Solid phases ; Thermal stability ; Titanium dioxide</subject><ispartof>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology, 2020-07, Vol.22 (7), Article 174</ispartof><rights>Springer Nature B.V. 2020</rights><rights>Springer Nature B.V. 2020.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c271x-e9969778e30941c0e809126e8224a093b7c64c4efa0ac95ee76ffadc3328f80d3</citedby><cites>FETCH-LOGICAL-c271x-e9969778e30941c0e809126e8224a093b7c64c4efa0ac95ee76ffadc3328f80d3</cites><orcidid>0000-0001-5968-0061</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11051-020-04891-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11051-020-04891-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Ngamsakpasert, Chanitsara</creatorcontrib><creatorcontrib>Suriyawong, Achariya</creatorcontrib><creatorcontrib>Supothina, Sitthisuntorn</creatorcontrib><creatorcontrib>Chuaybamroong, Paradee</creatorcontrib><title>Post-harvest treatment of carbendazim in Chinese chives using TiO2 nanofiber photocatalysis with different anatase/rutile ratios</title><title>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology</title><addtitle>J Nanopart Res</addtitle><description>Carbendazim residues in Chinese chives were treated by photocatalysis using the following three electrospun TiO
2
nanofibers: TTiP/PVP, TTiP/PVAc, and TBOT/PVP. The as-spun fibers were calcined at 500–650 °C to achieve anatase/rutile (A/R) ratios of 100:0, 80:20, 70:30, 50:50, and 30:70. The obtained anatase crystallite sizes were in the range of 13.9–28.1 nm, while the rutile crystallite sizes were 21.1–30.6 nm. The experiments were conducted in glass reactors. These were filled with water and each type of the fiber and irradiated from above by black light lamps for 5 min. Then, 50 g of the samples of Chinese chives was immersed for 5, 15, 30, and 60 min. Carbendazim in the chives was extracted using the matrix solid-phase dispersion (MSPD) method and analyzed using UHPLC. The ˙OH formation from each fiber type was investigated using the coumarin fluorescent probe method.
An A/R ratio of 70:30 yielded the highest ˙OH formation, as well as the greatest carbendazim degradation. Rutile plays a crucial role in inhibition of electron-hole recombination and ˙O
2
−
stabilization. The degradation efficiencies for carbendazim from TTiP/PVP, TTiP/PVAc, and TBOT/PVP fibers after a 60-min treatment were 98.6–99.5%, 91.2–97.1%, and 99.5–99.9%, respectively. The TTiP/PVP and TBOT/PVP fibers produced levels of retained carbendazim in the chives that were within EU maximum residue limits of 0.1 mg/kg. The thermal stability of the TTiP/PVAc fiber limited ˙OH formation and carbendazim degradation.</description><subject>Anatase</subject><subject>Black light</subject><subject>Carbendazim</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Coumarin</subject><subject>Crystallites</subject><subject>Crystals</subject><subject>Degradation</subject><subject>Fibers</subject><subject>Fluorescent indicators</subject><subject>Fungicides</subject><subject>Holes (electron deficiencies)</subject><subject>Inorganic Chemistry</subject><subject>Lasers</subject><subject>Materials Science</subject><subject>Nanofibers</subject><subject>Nanoparticles</subject><subject>Nanotechnology</subject><subject>Optical Devices</subject><subject>Optics</subject><subject>Photocatalysis</subject><subject>Photonics</subject><subject>Physical Chemistry</subject><subject>Polyvinyl acetates</subject><subject>Recombination</subject><subject>Research Paper</subject><subject>Residues</subject><subject>Rutile</subject><subject>Solid phases</subject><subject>Thermal stability</subject><subject>Titanium dioxide</subject><issn>1388-0764</issn><issn>1572-896X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp9kE1LAzEQhhdRsFb_gKeA5-gku91NjlL8gkI9KHgLaTpxU9qkJqlWT_50oxW8ecpAnvcd5qmqUwbnDKC7SIzBiFHgQKERktHtXjVgo45TIdun_TLXQlDo2uawOkppAcBaLvmg-rwPKdNex1dMmeSIOq_QZxIsMTrO0M_1h1sR58m4dx4TEtO7wpJNcv6ZPLgpJ177YN0MI1n3IQejs16-J5fIm8s9mTtrMX53al9-El7ETXZLJFFnF9JxdWD1MuHJ7zusHq-vHsa3dDK9uRtfTqjhHdtSlLKVXSewBtkwAyhAMt6i4LzRIOtZZ9rGNGg1aCNHiF1rrZ6buubCCpjXw-ps17uO4WVTjlWLsIm-rFS8Yc2oFbyGQvEdZWJIKaJV6-hWOr4rBurbtNqZVsW0-jGttiVU70KpwP4Z41_1P6kvo6eEbg</recordid><startdate>20200701</startdate><enddate>20200701</enddate><creator>Ngamsakpasert, Chanitsara</creator><creator>Suriyawong, Achariya</creator><creator>Supothina, 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treatment of carbendazim in Chinese chives using TiO2 nanofiber photocatalysis with different anatase/rutile ratios</title><author>Ngamsakpasert, Chanitsara ; Suriyawong, Achariya ; Supothina, Sitthisuntorn ; Chuaybamroong, Paradee</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c271x-e9969778e30941c0e809126e8224a093b7c64c4efa0ac95ee76ffadc3328f80d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Anatase</topic><topic>Black light</topic><topic>Carbendazim</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Coumarin</topic><topic>Crystallites</topic><topic>Crystals</topic><topic>Degradation</topic><topic>Fibers</topic><topic>Fluorescent indicators</topic><topic>Fungicides</topic><topic>Holes (electron deficiencies)</topic><topic>Inorganic Chemistry</topic><topic>Lasers</topic><topic>Materials 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technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ngamsakpasert, Chanitsara</au><au>Suriyawong, Achariya</au><au>Supothina, Sitthisuntorn</au><au>Chuaybamroong, Paradee</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Post-harvest treatment of carbendazim in Chinese chives using TiO2 nanofiber photocatalysis with different anatase/rutile ratios</atitle><jtitle>Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology</jtitle><stitle>J Nanopart Res</stitle><date>2020-07-01</date><risdate>2020</risdate><volume>22</volume><issue>7</issue><artnum>174</artnum><issn>1388-0764</issn><eissn>1572-896X</eissn><abstract>Carbendazim residues in Chinese chives were treated by photocatalysis using the following three electrospun TiO
2
nanofibers: TTiP/PVP, TTiP/PVAc, and TBOT/PVP. The as-spun fibers were calcined at 500–650 °C to achieve anatase/rutile (A/R) ratios of 100:0, 80:20, 70:30, 50:50, and 30:70. The obtained anatase crystallite sizes were in the range of 13.9–28.1 nm, while the rutile crystallite sizes were 21.1–30.6 nm. The experiments were conducted in glass reactors. These were filled with water and each type of the fiber and irradiated from above by black light lamps for 5 min. Then, 50 g of the samples of Chinese chives was immersed for 5, 15, 30, and 60 min. Carbendazim in the chives was extracted using the matrix solid-phase dispersion (MSPD) method and analyzed using UHPLC. The ˙OH formation from each fiber type was investigated using the coumarin fluorescent probe method.
An A/R ratio of 70:30 yielded the highest ˙OH formation, as well as the greatest carbendazim degradation. Rutile plays a crucial role in inhibition of electron-hole recombination and ˙O
2
−
stabilization. The degradation efficiencies for carbendazim from TTiP/PVP, TTiP/PVAc, and TBOT/PVP fibers after a 60-min treatment were 98.6–99.5%, 91.2–97.1%, and 99.5–99.9%, respectively. The TTiP/PVP and TBOT/PVP fibers produced levels of retained carbendazim in the chives that were within EU maximum residue limits of 0.1 mg/kg. The thermal stability of the TTiP/PVAc fiber limited ˙OH formation and carbendazim degradation.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s11051-020-04891-x</doi><orcidid>https://orcid.org/0000-0001-5968-0061</orcidid></addata></record> |
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subjects | Anatase Black light Carbendazim Characterization and Evaluation of Materials Chemistry and Materials Science Coumarin Crystallites Crystals Degradation Fibers Fluorescent indicators Fungicides Holes (electron deficiencies) Inorganic Chemistry Lasers Materials Science Nanofibers Nanoparticles Nanotechnology Optical Devices Optics Photocatalysis Photonics Physical Chemistry Polyvinyl acetates Recombination Research Paper Residues Rutile Solid phases Thermal stability Titanium dioxide |
title | Post-harvest treatment of carbendazim in Chinese chives using TiO2 nanofiber photocatalysis with different anatase/rutile ratios |
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